Related papers: Modification of the Charge ordering in Pr$_{1/2}$S…
Nanoparticles of Nd1=2Sr1=2MnO3 of average particle sizes 12 nm and 25 nm are prepared by sol-gel technique. Transport, magnetotransport, magnetization and I-V characteristics studies have been performed on the nanoparticles. Although the…
Nd_0.5 Ca_0.5 MnO_3 (NCMO) nanoparticles (average diameter ~ 20 and 40 nm) are synthesized by polymeric precursor sol-gel method and characterized by X- ray diffraction, transmission electron microscopy (TEM), selective area electron…
Nanoparticles (size 20, 40 and 60 nm) of Pr_0.5Sr_0.5MnO_3 are prepared by sol-gel technique and their magnetic properties are studied using ferromagnetic resonance and magnetization measurements. A comparison with the properties of the…
Observation of charge ordering in single crystalline and bulk polycrystalline systems of various rare-earth based manganites is well documented. However, there is hardly any manifestation of the same when the grain size is reduced to…
Nd_0.67Sr_0.33MnO_3 nanoparticles with the grain size of about 30 nm are prepared by sol-gel method.These nanopowders are annealed at four different temperatures viz. 800 oC, 900 oC, 1000 oC and 1100 oC to study the effect of particle size…
We investigated the temperature ($T=$ 15 $\sim $ 290 K) and the magnetic field ($H=$ 0 $\sim $ 17 T) dependent optical conductivity spectra of a charge/orbital ordered manganite, Nd$_{1/2}$Sr$_{1/2}$MnO$_3$. With variation of $T$ and $H$,…
Magnetic nanoparticles of La0.67Sr0.33MnO3 (LSMO) manganite with mean particle sizes of 13, 16, 18 and 21 nm were prepared by the sol-gel method. The crystal structure and mean particle size of the synthesized powders were estimated by…
We have performed unpolarized and polarized neutron diffraction experiments on monodisperse 8 nm and 13 nm antiferromagnetic MnO nanoparticles. For the 8 nm sample, the antiferromagnetic transition temperature $T_N$ (114 K) is suppressed…
In this report we show that in the perovskite manganite La_{1-x}Ca_{x}MnO_3 for a fixed x \approx 0.33, the magnetic transition changes over from first order to second order on reducing the particle size to nearly few tens of a nanometer.…
Nanoparticles (dia ~ 5 - 7 nm) of Bi_0.5 X_0.5(X=Ca,Sr)MnO_3 are prepared by polymer assisted sol-gel method and characterized by various physico-chemical techniques. X-ray diffraction gives evidence for single phasic nature of the…
We have prepared crystalline nanowires (diameter ~ 50 nm, length ~ a few microns) of the charge ordering manganite Pr_0.5Ca_0.5Mn_O3 using a low reaction temperature hydrothermal method and characterized them using X-ray diffraction,…
The fascinating phenomenon of destabilization of charge/orbital order in Nd0.5Sr0.5MnO3 with the reduction of grain size is critically investigated. Based on our magnetic and transport experiments followed by a theoretical analysis, we…
A detailed investigation of the electronic - and magneto - transport properties of Nd0.8Sr0.2MnO3 with the variation of grain size (down to 42 nm) is presented here. Interestingly, we observe that the ferromagnetic insulating state is…
We investigated optical properties of Pr_{0.5}Sr_{0.5}MnO_3, which has the A-type antiferromagnetic ordering at a low temperature. We found that T- dependence of spectral weight transfer shows a clear correlation with the magnetic phase…
Electron microdiffraction study of phase transition in La2/3Ca1/3MnO3 revealed temperature dependent (h+1/2,0,l) diffraction spots. Their intensity peaks at Tc. Quantitative electron diffraction intensity analysis shows that they come from…
In this paper we report an investigation on the ferromagnetic state and the nature of ferromagnetic transition of nanoparticles of $\mathrm{La_{0.67}Ca_{0.33}MnO_3}$ using magnetic measurements and neutron diffraction. The investigation was…
In transition metal oxides, quantum confinement arising from a large surface to volume ratio often gives rise to novel physico-chemical properties at nanoscale. Their size dependent properties have potential applications in diverse areas,…
The low-doped magnetic perovskite La_{7/8}Sr_{1/8}MnO_3 undergoes within the paramagnetic-semiconducting phase a first-order structural transition due to antiferrodistorsive ordering of Jahn-Teller deformed MnO_6 octahedra. This allows to…
The role of particle size distribution inherently present in magnetic nanoparticles (NPs) is examined in considerable detail in relation to the measured magnetic properties of oleic acid-coated maghemite ({\gamma}-Fe$_2$O$_3$) NPs.…
Transmission electron microscopy observations reveal the presence of complex superstructures and remarkable phase separation in association with Na-ordering phenomenon in y-Na0.5CoO2. Resistivity and magnetization measurements indicate that…