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Local-spin-density functional calculations may be affected by severe errors when applied to the study of magnetic and strongly-correlated materials. Some of these faults can be traced back to the presence of the spurious self-interaction in…

Materials Science · Physics 2009-11-10 Alessio Filippetti , Nicola Spaldin

By combining the Self-Interaction Correction (SIC) with pseudopotential perturbation theory, the role of self-interaction errors inherent to the Local Density Approximation (LDA) to Density Functional Theory is estimated in the…

mtrl-th · Physics 2009-10-28 Jorge M. Pacheco , Walter Ekardt , Wolf-Dieter Schoene

We present a fully variational locally scaled self-interaction corrected (SIC) energy functional using complex optimal orbitals. This represents an important milestone for fully variational SIC energy functionals, which have been shown to…

We calculate the electronic structure of several atoms and small molecules by direct minimization of the Self-Interaction Corrected Local Density Approximation (SIC-LDA) functional. To do this we first derive an expression for the gradient…

Condensed Matter · Physics 2009-10-28 S. Goedecker , C. J. Umrigar

Standard spin-density functionals for the exchange-correlation energy of a many-electron ground state make serious self-interaction errors which can be corrected by the Perdew-Zunger self-interaction correction (SIC). We propose a…

Materials Science · Physics 2014-01-28 Mark R Pederson , Adrienn Ruzsinszky , John P. Perdew

Recently proposed local self-interaction correction (LSIC) method [Zope, R. R. et al., J. Chem. Phys. 151, 214108 (2019)] is a one-electron self-interaction-correction (SIC) method that uses an iso-orbital indicator to apply the SIC at each…

Chemical Physics · Physics 2023-02-22 Yoh Yamamoto , Tunna Baruah , Po-Hao Chang , Selim Romero , Rajendra R. Zope

A recently proposed local self-interaction correction (LSIC) method [Zope \textit{et al.} J. Chem. Phys., 2019,{\bf 151}, 214108] when applied to the simplest local density approximation provides significant improvement over standard…

Chemical Physics · Physics 2021-02-24 Selim Romero , Yoh Yamamoto , Tunna Baruah , Rajendra R. Zope

We present applications of the recently introduced ``Generalized SIC-Slater'' scheme which provides a simple Self-Interaction Correction approximation in the framework of the Optimized Effective Potential. We focus on the computation of…

Quantum Physics · Physics 2015-05-13 J. Messud , Z. Wang , P. M. Dinh , P. -G. Reinhard , E. Suraud

We present an atomic orbital based approximate scheme for self-interaction correction (SIC) to the local density approximation of density functional theory. The method, based on the idea of Filippetti and Spaldin [Phys. Rev. B 67, 125109…

Strongly Correlated Electrons · Physics 2013-05-29 C. D. Pemmaraju , T. Archer , D. Sanchez-Portal , S. Sanvito

The Perdew-Zunger self-interaction correction(PZ-SIC) improves the performance of density functional approximations(DFAs) for the properties that involve significant self-interaction error(SIE), as in stretched bond situations, but…

We examine the role of self-interaction errors (SIE) removal on the evaluation of magnetic exchange coupling constants. In particular we analyze the effect of scaling down the self-interaction-correction (SIC) for three {\em non-empirical}…

We discuss an extension of time-dependent density-functional theory by a self-interaction correction (SIC). A strictly variational formulation is given taking care of the necessary constraints. A manageable and transparent propagation…

Other Condensed Matter · Physics 2009-11-13 J. Messud , P. M. Dinh , P. -G. Reinhard , E. Suraud

Local field correction effects on intra-layer inelastic scattering rate of interacting electrons are theoretically investigated in a coupled-quantum-wells structure, at finite temperature. At first, temperature dependent dynamic dielectric…

Mesoscale and Nanoscale Physics · Physics 2018-07-04 Vahdat Rafee , Alireza Razeghizadeh , Abdolrasoul Gharaati

Semilocal density-functional approximations (DFAs), including the state-of-the-art SCAN functional, are plagued by the self-interaction error (SIE). While this error is explicitly defined only for one-electron systems, it has inspired the…

Materials Science · Physics 2024-01-23 Sheng Bi , Christian Carbogno , Igor Ying Zhang , Matthias Scheffler

Semi-local approximations to the density functional for the exchange-correlation energy of a many-electron system necessarily fail for lobed one-electron densities, including not only the familiar stretched densities but also the less…

Accurate prediction of spin-state energy difference is crucial for understanding the spin crossover (SCO) phenomena and is very challenging for the density functional approximations, especially for the local and semi-local approximations,…

Chemical Physics · Physics 2023-02-22 Selim Romero , Tunna Baruah , Rajendra R. Zope

We extend some of the well established self-interaction correction (SIC) schemes of density-functional theory to the case of systems with noncollinear magnetism. Our proposed SIC schemes are tested on a set of molecules and metallic…

Chemical Physics · Physics 2023-10-31 Nicolas Tancogne-Dejean , Martin Lüders , Carsten A. Ullrich

We propose a simplification of the Optimized Effective Potential (OEP) applied to the Self Interaction Correction (SIC) scheme of Density Functional Theory (DFT). The new scheme fulfills several key formal properties and turns out to be…

Other Condensed Matter · Physics 2009-11-13 J. Messud , P. M. Dinh , P. -G. Reinhard , E. Suraud

A systematic comparison of three approximate self-interaction corrections (SICs), Perdew-Zunger SIC, Lundin-Eriksson SIC and extended Fermi-Amaldi SIC, is performed for a model Hamiltonian whose exact many-body solution and exact…

Materials Science · Physics 2008-07-18 Daniel Vieira , K. Capelle

Self-interaction (SI) error, which results when exchange-correlation contributions to the total energy are approximated, limits the reliability of many density functional approximations. The Perdew-Zunger SI correction (PZSIC), when applied…

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