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We propose an extension of the second-order Barker-Henderson perturbation theory for polydisperse hard-sphere multi-Morse mixture. To verify the accuracy of the theory, we compare its predictions for the limiting case of monodisperse…

Soft Condensed Matter · Physics 2015-04-17 T. V. Hvozd , Yu. V. Kalyuzhnyi

Multi-configurational wave functions are known to describe electronic structure across a Born-Oppenheimer surface qualitatively correct. However, for quantitative reaction energies, dynamical correlation originating from the many…

Chemical Physics · Physics 2020-04-16 Christopher J. Stein , Markus Reiher

We study various temporal correlation functions of a tagged particle in one-dimensional systems of interacting point particles evolving with Hamiltonian dynamics. Initial conditions of the particles are chosen from the canonical thermal…

Statistical Mechanics · Physics 2015-06-25 Anjan Roy , Abhishek Dhar , Onuttom Narayan , Sanjib Sabhapandit

We present a theory for the steady-state dynamics of a two-dimensional system of spherically symmetric active Brownian particles. The derivation of the theory consists of two steps. First, we integrate out the self-propulsions and obtain a…

Soft Condensed Matter · Physics 2019-05-01 Grzegorz Szamel

We report a Monte Carlo simulation study of the properties of highly asymmetric binary hard sphere mixtures. This system is treated within an effective fluid approximation in which the large particles interact through a depletion potential…

Statistical Mechanics · Physics 2009-11-11 Julio Largo , Nigel B. Wilding

Generalized mode-coupling theory (GMCT) is a first-principles-based and systematically correctable framework to predict the complex relaxation dynamics of glass-forming materials. The formal theory amounts to a hierarchy of infinitely many…

Statistical Mechanics · Physics 2020-11-26 Rutger A. Biezemans , Simone Ciarella , Onur Çaylak , Björn Baumeier , Liesbeth M. C. Janssen

The mode coupling theory (MCT) of glasses, while offering an incomplete description of glass transition physics, represents the only established route to first-principles prediction of rheological behavior in nonergodic materials such as…

Soft Condensed Matter · Physics 2009-09-29 J. M. Brader , Th. Voigtmann , M. Fuchs , R. G. Larson , M. E. Cates

The fundamental measure approach to classical density functional theory has been shown to be a powerful tool to predict various thermodynamic properties of hard-sphere systems. We employ this approach to determine not only one-particle…

Soft Condensed Matter · Physics 2015-11-02 Andreas Härtel , Matthias Kohl , Michael Schmiedeberg

We study by molecular dynamics computer simulation a binary soft-sphere mixture that shows a pronounced decoupling of the species' long-time dynamics. Anomalous, power-law-like diffusion of small particles arises, that can be understood as…

Statistical Mechanics · Physics 2013-05-29 Th. Voigtmann , J. Horbach

A high order morphing continuum theory (MCT) is introduced to model highly compressible turbulence. The theory is formulated under the rigorous framework of rational continuum mechanics. A set of linear constitutive equations and balance…

Fluid Dynamics · Physics 2017-11-22 James Chen

We derive an extension of the mode coupling theory for the liquid-glass transition to a class of models of confined fluids, where the fluid particles evolve in a disordered array of interaction sites. We find that the corresponding…

Disordered Systems and Neural Networks · Physics 2007-05-23 V. Krakoviack

Complementary Neutron Spin Echo and X-ray experiments and Molecular Dynamics simulations have been performed on difluorotetrachloroethane (CFCl2-CFCl2) glassy crystal. Static, single-molecule reorientational dynamics and collective dynamics…

Soft Condensed Matter · Physics 2009-11-11 F. Affouard , E. Cochin , F. Danède , R. Decressain , M. Descamps , W. Haeussler

The mode-coupling theory for ideal glass transitions in simple systems is generalized to a theory for the glassy dynamics of molecular liquids using the density fluctuations of the sites of the molecule's constituent atoms as the basic…

Soft Condensed Matter · Physics 2009-11-07 S. -H. Chong , W. Gotze

We introduce a new class of exchange-correlation potentials for a static and time-dependent Density Functional Theory of strongly correlated systems in 3D. The potentials are obtained via Dynamical Mean Field Theory and, for strong enough…

Strongly Correlated Electrons · Physics 2015-05-18 Daniel Karlsson , Antonio Privitera , Claudio Verdozzi

We study heat conduction in a one-dimensional chain of particles with longitudinal as well as transverse motions. The particles are connected by two-dimensional harmonic springs together with bending angle interactions. The problem is…

Statistical Mechanics · Physics 2009-11-10 Jian-Sheng Wang , Baowen Li

A molecular dynamics simulation is performed for a supercooled liquid of rigid diatomic molecules. The time-dependent self and collective density correlators of the molecular centers of mass are determined and compared with the predictions…

Statistical Mechanics · Physics 2009-10-30 Stefan Kammerer , Walter Kob , Rolf Schilling

We solved the mode-coupling equations for the Kob-Andersen binary mixture using the structure factors calculated from Brownian dynamics simulations of the same system. We found, as was previously observed, that the mode-coupling…

Soft Condensed Matter · Physics 2009-11-11 Elijah Flenner , Grzegorz Szamel

We argue that the critical dynamical fluctuations predicted by the mode-coupling theory (MCT) of glasses provide a natural mechanism to explain the breakdown of the Stokes-Einstein relation. This breakdown, observed numerically and…

Statistical Mechanics · Physics 2015-06-25 Giulio Biroli , Jean-Philippe Bouchaud

Coupled mode theory (CMT) is a powerful framework for decomposing interactions between electromagnetic waves and scattering bodies into resonances and their couplings with power-carrying channels. It has widespread use in few-resonance,…

Optics · Physics 2020-10-22 Hanwen Zhang , Owen D. Miller

The one-dimensional Hubbard model is investigated by means of two different cluster schemes suited to introduce short-range spatial correlations beyond the single-site Dynamical Mean-Field Theory, namely the Cluster-Dynamical Mean-Field…

Strongly Correlated Electrons · Physics 2007-08-07 M. Capone , M. Civelli , S. S. Kancharla , C. Castellani , G. Kotliar