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We present a first-principles investigation of spin-phonon relaxation in a molecular crystal of Co(II) single-ion magnets. Our study combines electronic structure calculations with machine-learning force fields and unravels the nature of…

Materials Science · Physics 2020-05-27 Alessandro Lunghi , Stefano Sanvito

Using density functional theory with the generalized gradient approximation and ultra-soft pseudo-potentials, we have calculated structural relaxations of the Cu(532) surface which contains steps and kinks. We find the relaxation pattern to…

Materials Science · Physics 2009-11-11 Faisal Mehmood , Abdelkader Kara , Talat S. Rahman

We propose a probe based on nuclear relaxation and Knight shift measurements for the Kondo scenario for the "0.7 feature" in semiconductor quantum point contact (QPC) devices. We show that the presence of a bound electron in the QPC would…

Mesoscale and Nanoscale Physics · Physics 2008-06-05 V. Tripathi , N. R. Cooper

Superparamagnetic colloids present interesting assembly dynamics and propulsion in time-varying magnetic fields due to their magnetic relaxation. However, little is known about the mechanisms governing this magnetic relaxation, which is…

We present the results obtained on the magnetisation relaxation properties of an XX quantum chain in a transverse magnetic field. We first consider an initial thermal kink-like state where half of the chain is initially thermalized at a…

Statistical Mechanics · Physics 2009-11-11 Thierry Platini , Dragi Karevski

In this study, molecular dynamics simulations were conducted to investigate the relaxation of the internal energy in nano-sized particles and its impact on the nucleation of atomic clusters. Quantum-mechanical potentials were utilized to…

Atomic and Molecular Clusters · Physics 2024-07-30 Mitchell Bredice , Michael G. Rozman , Jonathan Smucker , Eric Farmer , Robin Côté , Vasili Kharchenko

We present a novel approach to spin manipulation in atomic-scale nanostructures. Our ab initio calculations clearly demonstrate that it is possible to tune magnetic properties of sub-nanometer structures by adjusting the geometry of the…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 O. O. Brovko , P. A. Ignatiev , V. S. Stepanyuk , P. Bruno

In this work we study the relaxation of the system of strongly correlated electrons, at charge neutrality, when the chemical potential undergoes a local change. This setup is a model for for the X-ray absorbtion edge study in the…

High Energy Physics - Theory · Physics 2020-07-15 Alexander Krikun

We present a simple and accurate computational method, which facilitates ab-initio path-integral molecular dynamics simulations, where the quantum mechanical nature of the nuclei is explicitly taken into account, at essentially no…

Chemical Physics · Physics 2016-04-21 Chris John , Thomas Spura , Scott Habershon , Thomas D. Kühne

Four discrete MnIII/MnII tetra-nuclear complexes with double-cuboidal core were synthesized. dc magnetic measurements show that both Mn2+ - Mn3+ and Mn3+ - Mn3+ magnetic interactions are ferromagnetic in three samples leading to an S = 9…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. Lecren , O. Roubeau , C. Coulon , Yang-Guang Li , X. Le Goff , W. Wernsdorfer , H. Miyasaka , R. Clerac

We explore the quantum dynamics of nuclear spin relaxation in cold collisions of $^1\Sigma^+$ molecules with structureless atoms in an external magnetic field. To this end, we develop a rigorous coupled-channel methodology, which accounts…

Chemical Physics · Physics 2023-06-29 Rebekah Hermsmeier , Xiaodong Xing , Timur V. Tscherbul

In this thesis, the ground state properties of nuclear matter, namely the energy per particle and the response to weak probes, are computed, studying the effects of three nucleon interactions. Both the variational approach, based on the…

Nuclear Theory · Physics 2012-10-03 Alessandro Lovato

Recently a generalization of the ``\textit{modern theory of orbital magnetization}'' to include non-local Hamiltonians (e.g. hybrid functionals of the generalized Kohn-Sham theory) was provided for magnetic response properties. Results…

Materials Science · Physics 2025-07-22 Jacques K. Desmarais

We propose a new quantum Monte Carlo algorithm which realizes a relaxation intrinsic to the original quantum system. The Monte Carlo dynamics satisfies the dynamic scaling relation $\tau\sim \xi^z$ and is independent of the Trotter number.…

Statistical Mechanics · Physics 2009-11-10 Tota Nakamura , Yoshiyuki Ito

We derive and implement a new way of solving coupled cluster equations with lower computational scaling. Our method is based on decomposition of both amplitudes and two electron integrals, using a combination of tensor hypercontraction and…

Chemical Physics · Physics 2020-05-14 Roman Schutski , Jinmo Zhao , Thomas M. Henderson , Gustavo E. Scuseria

We present analytical derivation of the closed-form expression for the dipole magnetic shielding constant of a Dirac one-electron atom being in an arbitrary discrete energy eigenstate. The external magnetic field, by which the atomic state…

Atomic Physics · Physics 2016-08-05 Patrycja Stefańska

The effective response depends sensitively on composite microstructure due to large fluctuations in the local electric field. For metallic clusters embedded in a dielectric host, the local field distributions are extremely inhomogeneous in…

Soft Condensed Matter · Physics 2007-05-23 Ying Gu , K. W. Yu , Hong Sun

The anomalous low energy behaviour observed in metals with strong electron correlation, such as in the heavy fermion materials, is believed to arise from the scattering of the itinerant electrons with low energy spin fluctuations. In…

Strongly Correlated Electrons · Physics 2015-03-17 Khan Edwards , Alex C Hewson

An approach for explicit consideration of cluster effects in nuclear systems and accurate ab initio calculations of cluster characteristics of nuclei is devised. The essential block of the approach is a construction of a basis which…

Nuclear Theory · Physics 2018-12-26 D. M. Rodkin , Yu. M. Tchuvil'sky

Nano-plasmas produced, e.g. in clusters after short-pulse laser irradiation, can show collective excitations as derived from the time evolution of fluctuations in thermodynamic equilibrium. Molecular dynamical simulations are performed for…

Plasma Physics · Physics 2018-01-17 H. Reinholz , G. Röpke , I. Broda , I. Morozov , R. Bystryi , Y. Lavrinenko