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This chapter takes a microscopic view of quantum tunneling of magnetization (QTM) in single-molecule magnets (SMMs), focusing on the interplay between exchange and anisotropy. Careful consideration is given to the relationship between…

Mesoscale and Nanoscale Physics · Physics 2013-03-04 Junjie Liu , Enrique del Barco , Stephen Hill

We study the magnetic properties of small Mn ring shaped clusters on a Pt(111) surface in the framework of density functional theory. We find that the Mn atoms possess large magnetic moments, of the order of 4uB/atom, and have dominating…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 M. S. Ribeiro , G. B. Corrêa , A. Bergman , L. Nordström , O. Eriksson , A. B. Klautau

A multi-high-frequency electron paramagnetic resonance method is used to probe the magnetic excitations of a dimer of single-molecule magnets. The measured spectra display well resolved quantum transitions involving coherent superposition…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 S. Hill , R. S. Edwards , N. Aliaga-Alcalde , G. Christou

The implementation of a spin qubit in a quantum ring occupied by one or a few electrons is proposed. Quantum bit involves the Zeeman sublevels of the highest occupied orbital. Such a qubit can be initialized, addressed, manipulated, read…

Mesoscale and Nanoscale Physics · Physics 2011-03-07 Elzbieta Zipper , Marcin Kurpas , Janusz Sadowski , Maciej M. Maska

Antiferromagnets have been shown to harbor strong magnon squeezing in equilibrium, making them a potential resource for quantum correlations and entanglement. Recent experiments have also found them to host coherently coupled magnonic…

The ground state of a molecular diamond-lattice compound (ET)Ag$_4$(CN)$_5$ is investigated by the magnetization and nuclear magnetic resonance spectroscopy. We found that the system exhibits antiferromagnetic long-range ordering with weak…

Machine learning advances chemistry and materials science by enabling large-scale exploration of chemical space based on quantum chemical calculations. While these models supply fast and accurate predictions of atomistic chemical…

Chemical Physics · Physics 2019-06-25 K. T. Schütt , M. Gastegger , A. Tkatchenko , K. -R. Müller , R. J. Maurer

Magnetic phase transitions between ordered phases are often understood on the basis of semi-classical spin models. Deviations from the classical description due to the quantum nature of the atomic spins as well as quantum fluctuations are…

Strongly Correlated Electrons · Physics 2026-05-19 Tobias Dannegger , Imre Hagymási , Levente Rózsa , Ulrich Nowak

Starting from a phenomenological Hamiltonian originally written in terms of angular momentum operators we derive a new quantum angle-based Hamiltonian that allows for a discussion on the quantum spin tunneling. The study of the…

Quantum Physics · Physics 2007-05-23 D. Galetti

As quantum processing units grow in size and precision we enter the stage where quantum algorithms can be tested on actual quantum devices. To implement a given quantum circuit on a given quantum device, one has to express the circuit in…

Quantum Physics · Physics 2025-06-23 Yaqing X. Wang , Tommaso Calarco , Felix Motzoi , Matthias M. Müller

We show that molecular spin qudits provide an ideal platform to simulate the quantum dynamics of photon fields strongly interacting with matter. The basic unit of the proposed molecular quantum simulator can be realized by a simple dimer of…

A promising platform for quantum information processing is that of silicon impurities, where the quantum states are manipulated by magnetic resonance. Such systems, in abstraction, can be considered as a nucleus of arbitrary spin coupled to…

Quantum Physics · Physics 2013-05-07 M. H. Mohammady

The heavy fermion superconductor CeCoIn_5 can be tuned between superconducting and antiferromagnetic ground states by hole doping with Cd. Nuclear magnetic resonance (NMR) data indicate that these two orders coexist microscopically with an…

Strongly Correlated Electrons · Physics 2007-10-02 R. R. Urbano , B. -L. Young , N. J. Curro , J. D. Thompson , L. D. Pham , Z. Fisk

An effective spin-orbit Hamiltonian is derived for a spin-1/2 trimerized kagome antiferromagnet in the second-order of perturbation theory in the ratio of two coupling constants. Low-energy singlet states of the obtained model are mapped to…

Strongly Correlated Electrons · Physics 2007-05-23 M. E. Zhitomirsky

Since the concepts for the implementation of data storage and logic gates used in conventional electronics cannot be simply downscaled to the level of single molecule devices, new architectural paradigms are needed, where quantum…

Mesoscale and Nanoscale Physics · Physics 2015-12-16 Robert Stadler

The interpretation of the magnetic phase diagrams of strongly correlated electron systems remains controversial. In particular, the physics of quantum phase transitions, which occur at zero temperature, is still enigmatic. Heavy-fermion…

Strongly Correlated Electrons · Physics 2012-11-08 W. Knafo , S. Raymond , P. Lejay , J. Flouquet

Antiferromagnetic materials hold promising prospects in novel types of spintronics applications. Assessing the stability of antiferromagnetic nanostructures against thermal excitations is a crucial aspect of designing devices with a high…

Mesoscale and Nanoscale Physics · Physics 2019-08-28 Levente Rózsa , Severin Selzer , Tobias Birk , Unai Atxitia , Ulrich Nowak

The highly controllable ultracold atoms in a one-dimensional (1D) trap provide a new platform for the ultimate simulation of quantum magnetism. In this regard, the Neel-antiferromagnetism and the itinerant ferromagnetism are of central…

Quantum Gases · Physics 2016-06-08 Lijun Yang , Xiwen Guan , Xiaoling Cui

Semiconductors are the backbone of modern technology, garnering decades of investment in high quality materials and devices. Electron spin systems in semiconductors, including atomic defects and quantum dots, have been demonstrated in the…

An electron inside liquid helium forms a bubble of 17 \AA in radius. In an external magnetic field, the two-level system of a spin 1/2 electron is ideal for the implementation of a qubit for quantum computing. The electron spin is well…

Other Condensed Matter · Physics 2007-05-23 Weijun Yao