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We present an O(N) algorithm to study the vibrational properties of amorphous silicon within the framework of tight-binding approach. The dynamical matrix elements have been evaluated numerically in the harmonic approximation exploiting the…

Disordered Systems and Neural Networks · Physics 2009-11-07 Parthapratim Biswas

The structural features of the interface between the cystalline and amorphous phases of Si solid are studied in simulations based on a combination of empirical interatomic potentials and a nonorthogonal tight-binding model. The…

Materials Science · Physics 2009-10-31 N. Bernstein , M. J. Aziz , E. Kaxiras

We show that harmonic vibrations in amorphous silicon can be decomposed to transverse and longitudinal components in all frequency range even in the absence of the well defined wave vector ${\bf q}$. For this purpose we define the…

Disordered Systems and Neural Networks · Physics 2016-01-20 Y. M. Beltukov , C. Fusco , A. Tanguy , D. A. Parshin

We present a novel approach for parameter-free modeling of the structural, dynamical and electronic properties of non-crystalline materials based on ab-initio Molecular Dynamics, improved signal processing technique and computer…

Materials Science · Physics 2009-11-13 I. M. Kupchak , F. Gaspari , A. I. Shkrebtii , J. Perz

We report a new approach to simulate amorphous networks of covalently bonded materials that leads to excellent radial distribution functions and realistic atomic arrangements. We apply it to generate the first ab initio structures of…

Materials Science · Physics 2007-05-23 Fernando Alvarez , Ariel A. Valladares

The vibrational properties of model amorphous materials are studied by combining complete analysis of the vibration modes, dynamical structure factor and energy diffusivity with exact diagonalization of the dynamical matrix and the Kernel…

Disordered Systems and Neural Networks · Physics 2016-02-18 Y. M. Beltukov , C. Fusco , D. A. Parshin , A. Tanguy

We present a tight-binding potential based on the moment expansion of the density of states, which includes up to the fifth moment. The potential is fitted to bcc and hcp Zr and it is applied to the computation of vibrational properties of…

Materials Science · Physics 2009-10-31 Marcel Porta , Teresa Castan

Amorphous silicon (a-Si) models are analyzed for structural, electronic and vibrational characteristics. Several models of various sizes have been computationally fabricated for this analysis. It is shown that a recently developed…

Disordered Systems and Neural Networks · Physics 2018-11-29 Dale Igram , Bishal Bhattarai , Parthapratim Biswas , D. A. Drabold

The molecular dynamics method is applied to simulate the recrystallization of an amorphous/crystalline silicon interface. The atomic structure of the amorphous material is constructed with the method of Wooten, Winer, and Weaire. The…

Computational Physics · Physics 2011-07-07 Christophe Krzeminski , Quentin Brulin , V. Cuny , Emmanuel Lecat , Evelyne Lampin , Fabrizio Cleri

Molecular hydrogen in silicon has been studied by path-integral molecular dynamics simulations in the canonical ensemble. Finite-temperature properties of these point defects were analyzed in the range from 300 to 900 K. Interatomic…

Materials Science · Physics 2009-07-31 Carlos P. Herrero , Rafael Ramirez

We have used tight-binding molecular-dynamics simulations to investigate the role of point defects (vacancies and interstitials) on structural relaxation in amorphous silicon. Our calculations give unambiguous evidence that point defects…

Materials Science · Physics 2007-05-23 Cristiano L. Dias , Laurent J. Lewis , S. Roorda

On the basis of density functional calculations and using Bader's atom in molecule theory, this article presents quantitative microscopic analyses on the bonding properties of amorphous silicon (a-Si) which could reflect in the observable…

Materials Science · Physics 2019-04-11 Zahra Nourbakhsh , Hadi Akbarzadeh

The vibrational properties of a high-quality realistic model of amorphous silicon are examined. The longitudinal and transverse dynamical structure factors are calculated, and fitted to a damped harmonic oscillator (DHO) function. The width…

Materials Science · Physics 2009-11-13 J. K. Christie , S. N. Taraskin , S. R. Elliott

We report on microscopic tight-binding modeling of surface states in Bi$_2$Se$_3$ three-dimensional topological insulator, based on a sp$^3$ Slater-Koster Hamiltonian, with parameters calculated from density functional theory. The effect of…

Mesoscale and Nanoscale Physics · Physics 2014-11-04 A. Pertsova , C. M. Canali

A tight-binding parametrization for silicon, optimized to correctly reproduce effective masses as well as the reciprocal space positions of the conduction-band minima, is presented. The reliability of the proposed parametrization is…

Materials Science · Physics 2009-11-11 A. S. Martins , Timothy B. Boykin , Gerhard Klimeck , Belita Koiller

We develop an empirical potential for silicon which represents a considerable improvement over existing models in describing local bonding for bulk defects and disordered phases. The model consists of two- and three-body interactions with…

Materials Science · Physics 2016-08-31 Joao F. Justo , Martin Z. Bazant , Efthimios Kaxiras , V. V. Bulatov , Sidney Yip

Solid state physics deals with systems composed of atoms with strongly bound electrons. The tunneling probability of each electron is determined by interactions that typically extend to neighboring sites, as their corresponding wave…

Materials Science · Physics 2019-11-27 F. Ramírez-Ramírez , E. Flores-Olmedo , G. Báez , E. Sadurní , R. ~A. Méndez-Sánchez

Several static and dynamic properties of liquid silicon near melting have been determined from an orbital free {\em ab-initio} molecular dynamics simulation. The calculated static structure is in good agreement with the available X-ray and…

Materials Science · Physics 2015-06-25 A. Delisle , D. J. Gonzalez , M. J. Stott

An application of the tight binding approximation is presented for the description of electronic structure and interatomic force in magnetic iron, both pure and containing hydrogen impurities. We assess the simple canonical d-band…

Materials Science · Physics 2015-05-19 A. T. Paxton , C. Elsaesser

In 1985, Beeman, Tsu and Thorpe established an almost linear relation between the Raman transverse-optic (TO) peak width and the spread in mean bond angle in a-Si. This relation is often used to estimate the latter quantity in experiments.…

Condensed Matter · Physics 2007-05-23 R. L. C. Vink , G. T. Barkema , W. F. van der Weg
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