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First principles density functional theory calculations within the GGA+U approximation were performed for LiMn$_{1-x}$M$_x$O$_{2}$, a candidate cathode material for lithium-ion batteries, with ($x=0.25$, M=Ni, Fe, Co, Mg), to investigate…

Materials Science · Physics 2008-07-01 N. N. Shukla , S. Shukla , R. Prasad , R. Benedek

Small single crystals of Rb$_3$Ni$_2$(NO$_3$)$_7$ were obtained by crystallization from anhydrous nitric acid solution of rubidium nitrate and nickel nitrate hexahydrate. The basic elements of the crystal structure of this new compound are…

Ab initio electronic structure calculations of two-dimensional layered structures are typically performed using codes that were developed for three-dimensional structures, which are periodic in all three directions. The introduction of a…

Strongly Correlated Electrons · Physics 2016-06-22 Paolo E. Trevisanutto , Giovanni Vignale

A GW approximation (GWA) method named U+GWA is proposed, where we can start GWA with more localized wave functions obtained by the local spin-density approximation (LSDA)+U method. Then GWA and U+GWA are applied to MnO, NiO, and V$_2$O$_3$…

Strongly Correlated Electrons · Physics 2008-10-18 S. Kobayashi , Y. Nohara , S. Yamamoto , T. Fujiwara

GeCu2O4 exhibits a tetragonal spinel structure due to the strong Jahn-Teller distortion associated with Cu2+ ions. We show that its magnetic structure can be described as slabs composed of a pair of layers with orthogonally oriented spin…

Materials Science · Physics 2016-12-14 T. Zou , Y. -Q. Cai , C. R. dela Cruz , V. O. Garlea , S. D. Mahanti , J. -G. Cheng , X. Ke

Ultrafast quantum dynamics relaxation of a photoexcited state in a strongly correlated spin crossover system LaCoO3 under a sudden perturbation is considered with the density matrix generalized master equation. The magnetization and…

Strongly Correlated Electrons · Physics 2022-11-03 Yu. S. Orlov , S. V. Nikolaev , S. G. Ovchinnikov

Low temperature magnetic and structural behavior of the extended Kagome system YBaCo4O7 has been studied by single crystal neutron diffraction and high-resolution powder X-ray diffraction. Long-range magnetic ordering associated with a…

Materials Science · Physics 2015-05-19 D. D. Khalyavin , P. Manuel , B. Ouladdiaf , A. Huq , H. Zheng , J. F. Mitchell , L. C. Chapon

Despite several attempts, the intimate electronic structure of two-dimensional electron systems buried at the interface between LaAlO3 and SrTiO3 still remains to be experimentally revealed. Here, we investigate the transport properties of…

The Gutzwiller technique has long been known as a method to include correlations in electronic structure calculations. Here we implement an ab-initio Gutzwiller+LDA calculation, and apply it to a classic problem, the ferromagnetism of bulk…

Strongly Correlated Electrons · Physics 2013-07-23 Giovanni Borghi , Michele Fabrizio , Erio Tosatti

The variational cluster approximation is applied to the calculation of thermodynamical quantities and single-particle spectra of LaCoO3. Trial self-energies and the numerical value of the Luttinger-Ward functional are obtained by exact…

Strongly Correlated Electrons · Physics 2015-05-14 R. Eder

The relation between crystal symmetries, electron correlations, and electronic structure steers the formation of a large array of unconventional phases of matter, including magneto-electric loop currents and chiral magnetism. Detection of…

The electronic and magnetic properties of the delafossite CuFeO2 are investigated by means of electronic structure calculations. They are performed using density functional theory in the generalized gradient approximation as well as the new…

Strongly Correlated Electrons · Physics 2008-08-24 Volker Eyert , Raymond Fresard , Antoine Maignan

The electronic structures, charge and spin dynamics of the cobalt pnictide compounds ACo2As2 (A=Ba, Sr, Ca) in the paramagnetic state are investigated by using density functional theory combined with dynamical mean-field theory. In contrast…

Strongly Correlated Electrons · Physics 2018-09-25 Huican Mao , Zhiping Yin

Based on ab initio calculations we determine the features and relative stability of different models proposed to describe the $(2 \times 2)$-FeO(111) reconstruction. Our results suggest that both wurtzite and spinel-like environments are…

Strongly Correlated Electrons · Physics 2016-09-21 Ivan Bernal-Villamil , Silvia Gallego

We here study electronic structure and magnetic properties of bcc Co$_{x}$Fe$_{1-x}$, Cr$_{x}$Fe$_{1-x}$ and Mn$_{x}$Fe$_{1-x}$ in their ferromagnetic phases using Augmented Space Recursion technique coupled with tight-binding linearized…

Materials Science · Physics 2019-08-17 Subhradip Ghosh , Chhanda Basu Chaudhuri , Biplab Sanyal , Abhijit Mookerjee

The structural properties and the band structures of the charge-transfer insulating oxides SrO, MgO and SrTiO3 are computed both within density functional theory in the local density approximation (LDA) and in the Hedin's GW scheme for…

Condensed Matter · Physics 2009-10-31 G. Cappellini , S. Bouette-Russo , B. Amadon , C. Noguera , F. Finocchi

Electronic state and the Verwey transition in magnetite (Fe_3O_4) are studied using a spinless three-band Hubbard model for 3d electrons on the B sites with the Hartree-Fock approximation and the exact diagonalisation method.…

Strongly Correlated Electrons · Physics 2009-11-13 Hisashi Uzu , Arata Tanaka

Among the numerous 2D system that can be prepared via exfoliation, iron phosphorus trisulfide (FePS3) attracts a lot of attention recently due to its broad-range photoresponse, its unusual Ising-type magnetic order and possible applications…

Materials Science · Physics 2023-01-16 Mohammad Amirabbasi , Peter Kratzer

The relative thermodynamic stability of surface reconstructions including vacancies, adatoms and additional layers on both CaO and MnO$_{2}$ terminations is calculated to predict the surface phase diagram of…

Materials Science · Physics 2015-04-22 Diomedes Saldana-Greco , Chan-Woo Lee , Doyle Yuan , Andrew M. Rappe

Re-based double perovskites (DPs) exhibit a complex interplay of structural and metal-insulator transitions. Here we systematically study the ground state electronic and structural properties for a family of Re-based DPs $A_2B$ReO$_6$…

Strongly Correlated Electrons · Physics 2018-01-10 Alex Taekyung Lee , Chris A. Marianetti
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