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We show that under local detailed balance the expected entropy production rate is always bounded in terms of the dynamical activity. The activity refers to the time-symmetric contribution in the action functional for path-space…

Statistical Mechanics · Physics 2017-10-25 Christian Maes

If a system is at thermodynamic equilibrium, an observer cannot tell whether a film of it is being played forward or in reverse: any transition will occur with the same frequency in the forward as in the reverse direction. However, if…

Statistical Mechanics · Physics 2020-07-01 John W. Biddle , Jeremy Gunawardena

Using extensive particle-based simulations, we investigate out-of-equilibrium pattern dynamics in an oppositely driven binary particle system in two dimensions. A surprisingly rich dynamical behavior including lane formation, jamming,…

Soft Condensed Matter · Physics 2015-06-05 Masahiro Ikeda , Hirofumi Wada , Hisao Hayakawa

Activated dynamics in a glassy system undergoing steady shear deformation is studied by numerical simulations. Our results show that the external driving force has a strong influence on the barrier crossing rate, even though the reaction…

Statistical Mechanics · Physics 2010-11-12 Patrick Ilg , Jean-Louis Barrat

At molecular scales, fluctuations play a significant role and prevent biomolecular processes from always proceeding in a preferred direction, raising the question of how limited amounts of free energy can be dissipated to obtain directed…

Statistical Mechanics · Physics 2016-10-05 Aidan I. Brown , David A. Sivak

The design of desired behaviors in mechanical metamaterials has produced remarkable advances but has generally neglected two aspects - the inevitable presence of undesired behaviors and the role of dynamics in avoiding such behaviors.…

Soft Condensed Matter · Physics 2019-10-22 Menachem Stern , Viraaj Jayaram , Arvind Murugan

Everything that is not prohibited is permissible. So, what is prohibited in the course of chemical reactions, heat transfer and other dissipative processes? Is it possible to "overshoot" the equilibrium, and if yes, then how far?…

Chemical Physics · Physics 2007-05-23 A. N. Gorban , G. S. Yablonsky

The collective motion of interacting self-driven particles describes many types of coordinated dynamics and self-organisation. Prominent examples are alignment or lane formation which can be observed alongside other ordered structures and…

Adaptation and Self-Organizing Systems · Physics 2022-02-24 Basma Khelfa , Raphael Korbmacher , Andreas Schadschneider , Antoine Tordeux

A major impediment to a more complete understanding of barrier crossing and other single-molecule processes is the inability to directly visualize the trajectories and dynamics of atoms and molecules in reactions. Rather, the kinetics are…

Chemical Physics · Physics 2018-03-29 Patrick Figliozzi , Curtis W. Peterson , Stuart A. Rice , Norbert F. Scherer

Asymmetric exclusion processes with locally reversible kinetic constraints are introduced to investigate the effect of non-conservative driving forces in athermal systems. At high density they generally exhibit rheological-like behavior,…

Statistical Mechanics · Physics 2008-07-25 Mauro Sellitto

Active systems evade the rules of equilibrium thermodynamics by constantly dissipating energy at the level of their microscopic components. This energy flux stems from the conversion of a fuel, present in the environment, into sustained…

Soft Condensed Matter · Physics 2022-03-15 Étienne Fodor , Robert L. Jack , Michael E. Cates

The thermal activation process by which a system passes from one local energy minimum to another is a recurring motif in physics, chemistry, and biology. For instance, biopolymer chains are typically modeled in terms of energy landscapes,…

Statistical Mechanics · Physics 2024-10-01 Sudeep Adhikari , K. S. D. Beach

Allosteric regulation is often viewed as thermodynamic in nature. However protein internal motions during an enzymatic reaction cycle can be slow hopping processes over numerous potential barriers. We propose that regulating molecules may…

Biological Physics · Physics 2009-11-13 Jianhua Xing

A model multilevel molecule described by two sets of rotational internal energy levels of different parity and degenerate ground states, coupled by a constant interaction, is considered, by assuming that the random collisions in a gas of…

Quantum Physics · Physics 2013-05-31 Filippo Giraldi , Francesco Petruccione

Processes occurring in real open systems are far from equilibrium state and they can lead to synergetic effects, which are caused by coordinated behavior of system units. Traditional methods of analysis often just establish such behavior,…

Computational Physics · Physics 2007-05-23 E. N. Vertyagina

Engines are open systems that can generate work cyclically, at the expense of an external disequilibrium. They are ubiquitous in nature and technology, but the course of mathematical physics over the last 300 years has tended to make their…

Statistical Mechanics · Physics 2021-09-01 Robert Alicki , David Gelbwaser-Klimovsky , Alejandro Jenkins

Regulation to a well-defined target state is a fundamental requirement for achieving reliable functionality in living systems and maintaining specific non-equilibrium states. The control of certain properties and functionalities of systems…

Soft Condensed Matter · Physics 2024-12-17 Lisa Rohde , Desmond J. Quinn , Diptabrata Paul , Frank Cichos

We determine the asymptotic behaviour of (bilateral) obstacle problems for fractional energies in rather general aperiodic settings via Gamma-convergence arguments. As further developments we consider obstacles with random sizes and shapes…

Analysis of PDEs · Mathematics 2009-09-29 Matteo Focardi

Engineering molecular systems that exhibit complex behavior requires the design of kinetic barriers. For example, an effective catalytic pathway must have a large barrier when the catalyst is absent. While programming such energy barriers…

Emerging Technologies · Computer Science 2020-01-28 Keenan Breik , Cameron Chalk , David Doty , David Haley , David Soloveichik

Previous work shows that a net directed motion arises from a system of individual particles undergoing run-and-tumble dynamics in the presence of an array of asymmetric barriers. Here, we show that when the individual particle is replaced…

Soft Condensed Matter · Physics 2013-03-01 Mew-Bing Wan , YongSeok Jho