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Related papers: Long Range Bond-Bond Correlations in Dense Polymer…

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The presence of long-ranged correlations in a fluid undergoing uniform shear flow is investigated. An exact relation between the density autocorrelation function and the density-mometum correlation function implies that the former must…

Statistical Mechanics · Physics 2009-11-07 James F. Lutsko , J. W. Dufty

Using molecular dynamics simulation of a standard bead-spring model we investigate the density crossover scaling of strictly two-dimensional self-avoiding polymer chains focusing on properties related to the contact exponent set by the…

Soft Condensed Matter · Physics 2015-06-03 N. Schulmann , H. Meyer , J. P. Wittmer , A. Johner , J. Baschnagel

Polymers are among the most important materials in the modern society being found almost in every activity of our daily life. Understanding their chemical and physical properties lead to improvements of their usage. The correlation…

Soft Condensed Matter · Physics 2021-02-02 B. V. Costa

This study reports a general scenario for the out-of-equilibrium features of collapsing polymeric architectures. We use molecular dynamics simulations to characterize the coarsening kinetics, in bad solvent, for several macromolecular…

Soft Condensed Matter · Physics 2019-12-10 Mariarita Paciolla , Daniel J. Arismendi-Arrieta , Angel J. Moreno

We perform simulations for long hard-sphere polymer chains using a recently developed binary-tree based Monte Carlo method. Systems in two to five dimensions with free and periodic boundary conditions and up to $10^7$ repeat units are…

Soft Condensed Matter · Physics 2023-12-01 Stefan Schnabel , Wolfhard Janke

We present a unified scaling theory for the dynamics of monomers for dilute solutions of semiflexible polymers under good solvent conditions in the free draining limit. Our theory encompasses the well-known regimes of mean square…

Soft Condensed Matter · Physics 2015-06-17 Aiqun Huang , Ramesh Adhikari , Aniket Bhattacharya , Kurt Binder

The behavior of mesoscopic particles dissolved in a dilute solution of long, flexible, and nonadsorbing polymer chains is studied by field-theoretic methods. For spherical and cylindrical particles the solvation free energy for immersing a…

Soft Condensed Matter · Physics 2009-10-31 A. Hanke , E. Eisenriegler , S. Dietrich

The massive field theory approach in fixed space dimensions $d=3$ is applied to investigate a dilute solution of long-flexible polymer chains in a good solvent between two parallel repulsive walls, two inert walls and for the mixed case of…

Soft Condensed Matter · Physics 2009-10-08 D. Romeis , Z. Usatenko

The paper presents a short overview of the theoretical, numerical and experimental works on the critical behavior of a dilute polymer solution of long-flexible polymer chains confined in semi-infinite space restricted by a surface or in a…

Soft Condensed Matter · Physics 2018-01-08 Zoryana Usatenko , Krzysztof S. Danel

We calculate the two, three, four, and five-body (state independent) effective potentials between the centers of mass (CM) of self avoiding walk polymers by Monte-Carlo simulations. For full overlap, these coarse-grained n-body interactions…

Soft Condensed Matter · Physics 2009-11-07 P. G. Bolhuis , A. A. Louis , J. P. Hansen

We study polymer-polymer phase separation in a common good solvent by means of Monte Carlo simulations of the bond-fluctuation model. Below a critical, chain-length dependent concentration, no phase separation occurs. For higher…

Soft Condensed Matter · Physics 2009-11-11 Lei Guo , Erik Luijten

The predictions of the polymer mode coupling theory for the finite size corrections to the transport coefficients of entangled polymeric systems are tested in comparisons with various experimental data. It is found that quantitative…

Condensed Matter · Physics 2009-10-30 Matthias Fuchs , Kenneth S. Schweizer

We present an exactly solvable model of a Gaussian (flexible) polymer chain in a quenched random medium. This is the case when the random medium obeys very long range quadratic correlations. The model is solved in $d$ spatial dimensions…

Disordered Systems and Neural Networks · Physics 2009-10-31 Yohannes Shiferaw , Yadin Y. Goldschmidt

We consider a two-dimensional Coulomb gas of positive and negative pointlike unit charges interacting via a logarithmic potential. The density (rather than the charge) correlation functions are studied. In the bulk, the form-factor theory…

Statistical Mechanics · Physics 2007-05-23 L. Šamaj , B. Jancovici

We present and analyze correlation functions of a main-chain polymer nematic in a continuum worm-like chain description for two types of constraints formalized by the tensorial and vectorial conservation laws, both originating in the…

Soft Condensed Matter · Physics 2017-05-11 Daniel Svensek , Rudolf Podgornik

We use Monte Carlo simulations to study polymer melts consisting of fully flexible and moderately stiff chains in the bond fluctuation model at a volume fraction $0.5$. In order to reduce the local density fluctuations, we test a…

Soft Condensed Matter · Physics 2015-06-24 Hsiao-Ping Hsu

We present a quantitative picture of the separation of star polymers in a solution where part of the volume is influenced by a porous medium. To this end, we study the impact of long-range-correlated quenched disorder on the entropy and…

Soft Condensed Matter · Physics 2009-11-11 V. Blavats'ka , C. von Ferber , Yu. Holovatch

We consider polymers in which M randomly selected pairs of monomers are restricted to be in contact. Analytical arguments and numerical simulations show that an ideal (Gaussian) chain of N monomers remains expanded as long as M<<N; its mean…

Condensed Matter · Physics 2009-10-28 Yacov Kantor , Mehran Kardar

The self-consistent field (SCF) theory of dense polymer liquids assumes that short-range correlations are almost independent of how monomers are connected into polymers. Some limits of this idea are explored in the context of a perturbation…

Soft Condensed Matter · Physics 2015-05-13 David C. Morse , Jun Kyung Chung

We investigate the localization of a hydrophobic - polar (HP) - regular copolymer at a selective solvent-solvent interface with emphasis on the impact of block length $M$ on the copolymer behavior. The considerations are based on simple…

Soft Condensed Matter · Physics 2007-05-23 Andrea Corsi , Andrey Milchev , Vakhtang G. Rostiashvili , Thomas A. Vilgis