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The underlying connection between the degrees of freedom of a system and its nonextensive thermodynamic behavior is addressed. The problem is handled by starting from a thermodynamical system with fractal structure and its analytical…

Statistical Mechanics · Physics 2021-09-17 A. Deppman , J. A. S. Lima

In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…

Mathematical Physics · Physics 2015-06-19 Elliott H. Lieb , Jakob Yngvason

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

The problems of conditional entropy's definition and the formula to compute conditional entropy are analyzed from various perspectives, and the corrected computing formula is presented. Examples are given to prove the conclusion that…

Information Theory · Computer Science 2007-08-24 Wang Yong

We discuss that the thermodynamics of composite systems with non-additive entropies and additive energies can be equivalently derived considering additive entropies and non-additive energies. The general discussion is illustrated by a…

Statistical Mechanics · Physics 2007-05-23 Ramandeep S. Johal , Antoni Planes , Eduard Vives

In its continuous version, the entropy functional measuring the information content of a given probability density may be plagued by a "measure" problem that results from improper weighting of phase space. This issue is addressed…

Statistical Mechanics · Physics 2011-06-08 P. Maynar , E. Trizac

We consider a generic system composed of a fixed number of particles distributed over a finite number of energy levels. We make only general assumptions about system's properties and the entropy. System's constraints other than fixed number…

Probability · Mathematics 2020-03-12 Tomasz M. Łapiński

In stochastic thermodynamics, the entropy production of a thermodynamic system is defined by the irreversibility measured by the logarithm of the ratio of the path probabilities in the forward and reverse processes. We derive the relation…

Statistical Mechanics · Physics 2018-03-14 Hyun-Myung Chun , Jae Dong Noh

A complete model of baryon production in an expanding, primordially symmetric hot Universe is constructed in the framework of general-relativistic kinetic theory. In this model specific model for a baryon is calculated and graphs of the…

General Relativity and Quantum Cosmology · Physics 2010-12-30 Yu. G. Ignatyev , K. Alsmadi

The physical impossibility of heat transfer under isothermal conditions implies that the classical expression for the entropy of the ideal gas may not be compatible with the internal energy of the gas itself. A corrected expression of the…

Statistical Mechanics · Physics 2023-09-01 A. Paglietti

We derive a functional for the entropy contributed by any microscopic degrees of freedom as arising from their measurable pair correlations. Applicable both in and out of equilibrium, this functional yields the maximum entropy which a…

Statistical Mechanics · Physics 2023-02-17 Benjamin Sorkin , Joshua Ricouvier , Haim Diamant , Gil Ariel

The limit of small entropy production is reached in relaxing systems long after preparation, and in stationary driven systems in the limit of small driving power. Surprisingly, for extended systems this limit is not in general the…

Condensed Matter · Physics 2009-10-31 Leticia F. Cugliandolo , Jorge Kurchan

In systems with detailed balance, the stationary distribution and the equilibrium distribution are identical, creating a clear connection between energetic and entropic quantities. Many driven systems violate detailed balance and still pose…

Statistical Mechanics · Physics 2025-01-22 Markus Hofer , Jan Korbel , Rudolf Hanel , Stefan Thurner

Entropy generation in a chemical reaction is analyzed without using the general formalism of non-equilibrium thermodynamics at a level adequate for advanced undergraduates. In a first approach to the problem, the phenomenological kinetic…

General Physics · Physics 2015-06-11 E. N. Miranda

A pure quantum state can fully describe thermal equilibrium as long as one focuses on local observables. Thermodynamic entropy can also be recovered as the entanglement entropy of small subsystems. When the size of the subsystem increases,…

Statistical Mechanics · Physics 2018-05-31 Yuya O. Nakagawa , Masataka Watanabe , Hiroyuki Fujita , Sho Sugiura

We introduce an exactly solvable lattice model that reveals a universal finite-size scaling law for configurational entropy driven purely by geometry. Using exact enumeration via Burnside's lemma, we compute the entropy for diverse 1D, 2D,…

Statistical Mechanics · Physics 2025-07-29 Youshen Wu , Xin Guan , Shengli Zhang , Lei Zhang

The thermodynamic uncertainty relation expresses a universal trade-off between precision and entropy production, which applies in its original formulation to current observables in steady-state systems. We generalize this relation to…

Statistical Mechanics · Physics 2018-12-06 Timur Koyuk , Udo Seifert , Patrick Pietzonka

The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…

Statistical Mechanics · Physics 2016-03-23 Dragos-Victor Anghel

We construct the generalized entropy optimized by a given arbitrary statistical distribution with a finite linear expectation value of a random quantity of interest. This offers, via the maximum entropy principle, a unified basis for a…

Statistical Mechanics · Physics 2009-11-07 Sumiyoshi Abe

General hyperbolic systems of balance laws with inhomogeneity in space and time in all constitutive functions are studied in the context of relative entropy. A framework is developed in this setting that contributes to a measure-valued weak…

Analysis of PDEs · Mathematics 2022-06-02 Cleopatra Christoforou