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We investigate the bulk magnetic, electron paramagnetic resonance, and magneto-optical properties of {Ni4Mo12}, a magnetic molecule with antiferromagnetically coupled tetrahedral {Ni4Mo12} in a diamagnetic molybdenum matrix. The…

Recent magnetic measurements on tetra-nickel molecular magnets [Ni(hmp)(ROH)Cl]$_4$, where R=CH$_3$, CH$_2$CH$_3$, or (CH$_2$)$_2$C(CH$_3$)$_3$ and hmp$^-$ is the monoanion of 2-hydroxymethylpyridine, revealed a strong exchange bias prior…

Materials Science · Physics 2009-11-10 Kyungwha Park , En-Che Yang , David N. Hendrickson

The effect of the anisotropy in the exchange interaction on the phase diagrams and magnetization behavior of the Heisenberg thin film has been investigated with effective field formulation in a two spin cluster using the decoupling…

Statistical Mechanics · Physics 2015-06-17 Ümit Akıncı

Mapping the magnetic exchange interactions from model Hamiltonian to density functional theory is a crucial step in multi-scale modeling calculations. Considering the usual magnetic force theorem but with arbitrary rotational angles of the…

Materials Science · Physics 2010-11-23 Samir Lounis , Peter H. Dederichs

Spins in molecular magnets can experience both anisotropic exchange interactions and on-site magnetic anisotropy. In this paper we study the effect of exchange anisotropy on the molecular magnetic anisotropy both with and without on-site…

Materials Science · Physics 2018-12-12 Sumit Haldar , Rajamani Raghunathan , Jean-Pascal Sutter , S. Ramasesha

Magnetic materials are typically described in terms of the Heisenberg model, which provides an accurate account of thermodynamic properties when combined with first principles calculations. This approach is usually based on an energy…

Materials Science · Physics 2020-12-04 Daniele Torelli , Thomas Olsen

The thermodynamics of a site-diluted ferromagnetic Heisenberg model for spin $S=1/2$ with interaction anisotropy in spin space is investigated. The study is aimed at presenting the magnetocaloric properties of such a model, including the…

Statistical Mechanics · Physics 2013-04-09 Karol Szałowski , Tadeusz Balcerzak , Andrej Bobák

The tetrameric Ni(II) spin cluster Ni4Mo12 has been studied by INS. The data were analyzed extensively in terms of a very general spin Hamiltonian, which includes antiferromagnetic Heisenberg interactions, biquadratic 2-spin and 3-spin…

Mesoscale and Nanoscale Physics · Physics 2010-06-11 J. Nehrkorn , M. Höck , M. Brüger , H. Mutka , J. Schnack , O. Waldmann

We analyse a specific two dimensional mixed spin Heisenberg model with exchange anisotropy, by means of high temperature expansions and Monte Carlo simulations. The goal is to describe the magnetic properties of the compound…

Statistical Mechanics · Physics 2016-08-31 C. Meyers , Y. Meurdesoif , Y. Leroyer , O. Kahn

The effect of the anisotropy in the exchange interaction on the critical temperature and the order parameter of the anisotropic Heisenberg model on a core-shell structured nanotube geometry has been investigated. As a formulation, effective…

Statistical Mechanics · Physics 2014-08-01 Ümit Akıncı

We investigate various types of quantum entanglement in the octanuclear heterometallic $3d/4f$ complexes denoted as Ni$^{2+}_4$Gd$^{3+}_4$ under an external magnetic field, using the exact diagonalization approach. These molecular magnets,…

Materials Science · Physics 2025-09-15 Hamid Arian Zad , Michal Jaščur , Azam Zoshki , Ralph Kenna , Nerses Ananikian

The low-lying magnetic excitations in the dimer of single-molecule magnets (Mn4)2 are studied by inelastic neutron scattering as a function of hydrostatic pressure. The anisotropy parameters D and B04, which describe each Mn4 subunit, are…

We investigate the thermally activated magnetization switching of small ferromagnetic particles driven by an external magnetic field. For low uniaxial anisotropy the spins can be expected to rotate coherently, while for sufficient large…

Statistical Mechanics · Physics 2009-10-31 D. Hinzke , U. Nowak

We examine the anisotropic properties of the exchange stiffness constant, $\mathcal{A}$, for rare-earth permanent magnet, Nd$_2$Fe$_{14}$B, by connecting analyses with two different scales of length, i.e., Monte Carlo (MC) method with an…

Materials Science · Physics 2018-08-22 Yuta Toga , Masamichi Nishino , Seiji Miyashita , Takashi Miyake , Akimasa Sakuma

We study the behavior of the magnetization and the magnetic susceptibility of molecular magnets with complex bridging structure. Our computations are based on a post-Hartree-Fock method accounting for the intricate network of interatomic…

Strongly Correlated Electrons · Physics 2020-03-30 M. Georgiev , H. Chamati

Motivated by the recent suggestion of anisotropic effective exchange interactions between Mn spins in Ga$_{1-x}$Mn$_x$As (arising as a result of spin-orbit coupling), we study their effects in diluted Heisenberg spin systems. We perform…

Disordered Systems and Neural Networks · Physics 2007-05-23 Chenggang Zhou , Malcolm P. Kennett , Xin Wan , Mona Berciu , R. N. Bhatt

Although low-dimensional $S = 1$ antiferromagnets remain of great interest, difficulty in obtaining high-quality single crystals of the newest materials hinders experimental research in this area. Polycrystalline samples are more readily…

We present a model of equal spin $s_1$ dimer single molecule magnets. The spins within each dimer interact via the Heisenberg and the most general set of four quadratic anisotropic spin interactions with respective strengths $J$ and…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Dmitri V. Efremov , Richard A. Klemm

The dynamic magnetic properties of Ni nanoparticles diluted in an amorphous SiO2 matrix prepared from a modified sol-gel method have been studied by the frequency f dependence of the ac magnetic susceptibility \c{hi}(T). For samples with…

Materials Science · Physics 2011-03-22 G. F. Goya , F. C. Fonseca , R. F. Jardim , R. Muccillo , N. L. V. Carreño , E. Longo , E. R. Leite

In the Heisenberg antiferromagnet $Gd_2Ti_2O_7$, the exchange interactions are geometrically frustrated by the pyrochlore lattice structure. This ESR study reveals a strong temperature dependent anisotropy with respect to a [111] body…

Strongly Correlated Electrons · Physics 2016-08-16 A. K. Hassan , L. P. Lévy , C. Darie , P. Strobel
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