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We investigate electronic and optical properties of the V-based ladder compounds NaV2O5, the iso-structural CaV2O5, as well as MgV2O5, which differs from NaV2O5 and CaV2O5 in the c axis stacking. We calculate ab initio the A_g phonon modes…

Other Condensed Matter · Physics 2009-11-10 J. Spitaler , E. Ya. Sherman , C. Ambrosch-Draxl , H. - G. Evertz

In order to investigate the origin of the phase transition observed in NaV$_2$O$_5$, as well as its electronic structure, we have measured Raman intensities as a function of the laser wavelength above and below the phase transition…

Strongly Correlated Electrons · Physics 2015-06-25 M. J. Konstantinovic , Z. V. Popovic , T. Ruf , M. Cardona , A. N. Vasil'ev , M. Isobe , Y. Ueda

We report a comprehensive micro-Raman scattering study of electrochemically-gated graphene field-effect transistors. The geometrical capacitance of the electrochemical top-gates is accurately determined from dual-gated Raman measurements,…

Mesoscale and Nanoscale Physics · Physics 2016-08-08 Guillaume Froehlicher , Stéphane Berciaud

We investigate the electronic and magnetic properties as well as lattice dynamics and spin-phonon coupling of $\beta$-Na$_{0.33}$V$_2$O$_5$ using temperature-dependent Raman scattering, dc-magnetization and dc-resistivity, x-ray…

Materials Science · Physics 2022-11-23 Rishabh Shukla , Clemens Ulrich , R. S. Dhaka

Raman scattering on phonon--plasmon coupled modes in high magnetic fields is considered theoretically. The calculations of the dielectric function were performed in the long-wave approximation for the semiclassical and ultra-quantum…

Materials Science · Physics 2007-05-23 L. A. Falkovsky

UV Raman scattering studies show longitudinal optical (LO) mode up to 4th order in wurtzite GaN nanowire system. Frohlich interaction of electron with the long range electrostatic field of ionic bonded GaN gives rise to enhancement in LO…

We report the first systematic measurements of the Raman scattering by electrons in elemental metals of Al, Mo, Nb, Os, Pb, Re, Ta, Ti, V, W and metallic compound La$B_6$. Experimental spectra are modelled on the base of the band…

Strongly Correlated Electrons · Physics 2012-08-09 Yu. S. Ponosov , S. V. Streltsov

In the ac polarized Raman spectra of NaV2O5 we have found anomalous phonon broadening, and an energy shift of the low-frequency mode as a function of the temperature. These effects are related to the breaking of translational symmetry,…

Strongly Correlated Electrons · Physics 2009-10-31 M. J. Konstantinovic , M. Isobe , Y. Ueda

We show that the asymmetric crystal environment of the V site in the ladder compound NaV$_{2}$O$_{5}$ leads to a strong coupling of vanadium 3d electrons to phonons. This coupling causes fluctuations of the charge on the V ions, and favors…

Strongly Correlated Electrons · Physics 2009-10-31 E. Ya. Sherman , M. Fischer , P. Lemmens , P. H. M. van Loosdrecht , G. Güntherodt

We investigate the temperature dependent optical properties of NaV2O5, in the energy range 4meV-4eV. The symmetry of the system is discussed on the basis of infrared phonon spectra. By analyzing the optically allowed phonons at temperatures…

Strongly Correlated Electrons · Physics 2009-10-31 A. Damascelli , C. Presura , D. van der Marel , J. Jegoudez , A. Revcolevschi

The phonon dynamics of LiV2O5 single crystals is studied using infrared and Raman spectroscopy techniques. The infrared-active phonon frequencies and dielectric constants are obtained by oscillator fitting procedure of the reflectivity data…

Strongly Correlated Electrons · Physics 2009-10-31 Z. V. Popovic , R. Gajic , M. J. Konstantinovic , R. Provoost , V. V. Moshchalkov , A. N. Vasil'ev , M. Isobe , Y. Ueda

Polarized Raman spectra of the calcium vanadium oxide bronze beta-Ca0.33V2O5 are measured in the temperature range between 300 K and 20 K. The charge ordering phase transition at about 150 K is characterized by the appearance of the new…

Strongly Correlated Electrons · Physics 2009-11-10 Z. V. Popovic , M. J. Konstantinovic , V. V. Moshchalkov , M. Isobe , Y. Ueda

We have performed polarized Raman scattering measurements on the newly discovered superconductor Nd(O,F)BiS$_2$ ($T_c = 4$ K). We observe 2 Raman active modes, with frequencies in accordance with first-principles calculations. One A$_{1g}$…

Superconductivity · Physics 2014-09-04 S. F. Wu , P. Richard , X. B. Wang , C. S. Lian , S. M. Nie , J. T. Wang , N. L. Wang , H. Ding

We report results of Raman scattering experiments on twin-free BaFe$_{2}$As$_{2}$ with the main focus placed on understanding the influence of electronic and spin degrees of freedom on the lattice dynamics. In particular, we scrutinize the…

Strongly Correlated Electrons · Physics 2018-08-15 A. Baum , Ying Li , M. Tomić , N. Lazarević , D. Jost , F. Löffler , B. Muschler , T. Böhm , J. -H. Chu , I. R. Fisher , R. Valentí , I. I. Mazin , R. Hackl

We present a Raman study of ZrAs_{2} single crystals, a nodal line semimetal with symmetry-enforced Dirac-like band crossings. We identified the symmetry of phonon modes by polarized light measurements and comparison with calculated phonon…

Materials Science · Physics 2024-05-16 R. Bacewicz , C. Jastrzębski , K. Zberecki , A. S. Wadge , D. Jastrzębski , A. Wiśniewski

Electronic Raman scattering and optical phonon self-energies are studied on single crystals of $LuB_{12}$ with different isotopic composition in the temperature region 10-650K and at pressures up to 10 GPa. The shape and energy position of…

Materials Science · Physics 2016-08-09 Yu. S. Ponosov , A. A. Makhnev , S. V. Streltsov , V. B. Filipov , N. Yu. Shitsevalova

Inelastic light (Raman) scattering has been used to study electronic excitations and phonon anomalies in detwinned, slightly overdoped YBa$_2$Cu$_3$O$_{6.95}$ and moderately overdoped Y$_{0.85}$Ca$_{0.15}$Ba$_2$Cu$_3$O$_{6.95}$ single…

Superconductivity · Physics 2015-05-13 M. Bakr , A. P. Schnyder , L. Klam , D. Manske , C. T. Lin , B. Keimer , M. Cardona , C. Ulrich

We report the measurements of the pseudodielectric function, far-infrared reflectivity and Raman scattering spectra in Sr_{14}Cu_{24}O_{41} single crystal. We study the lattice and the spin dynamics of the Cu$_2$O$_3$ spin ladders and…

Strongly Correlated Electrons · Physics 2009-10-31 Z. V. Popović , M. J. Konstantinović , V. A. Ivanov , O. P. Khuong , R. Gajić , A. Vietkin , V. V. Moshchalkov

The semimetal NbIrTe4 has been proposed to be a Type-II Weyl semimetal with 8 pairs of opposite Chirality Weyl nodes which are very close to the Fermi energy. This topological electronic structure is made possible because of the broken…

We studied electronic excitations in NaV2O5 by Raman. Three main topics are discussed. The first is related to a broad continuum of excitations found in the 200-1500 cm-1 range and peaked around 680 cm-1. The resonant Raman profile of this…

Strongly Correlated Electrons · Physics 2015-06-25 A. Gozar , G. Blumberg
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