Related papers: Synthesis of superconducting pyrochlore RbOs2O6
We report the discovery of a new pyrochlore oxide superconductor RbOs2O6. The compound crystallizes in the same beta-pyrochlore structure as the recently discovered superconductor KOs2O6, where Os atoms form a corner-sharing tetrahedral…
The discovery of a new beta-pyrochlore oxide superconductor CsOs2O6 with Tc = 3.3 K is reported. It is the third superconductor in the family of beta-pyrochlore oxides, following KOs2O6 with Tc = 9.6 K and RbOs2O6 with Tc = 6.3 K. The Tc of…
We report the basic thermodynamic properties of the new geometrically frustrated beta-pyrochlore bulk superconductor RbOs2O6 with a critical temperature Tc = 6.4 K. Specific heat measurements are performed in magnetic fields up to 12 T. The…
We report the results of 87Rb NMR measurements on RbOs2O6, a new member of the family of the superconducting pyrochlore-type oxides with a critical temperature Tc = 6.4 K. In the normal state, the nuclear spin-lattice relaxation time T1…
Rattling-induced superconductivity in the beta-pyrochlore oxide RbOs2O6 is investigated under high pressures up to 6 GPa. Resistivity measurements in a high-quality single crystal show that the superconducting transition temperature Tc…
Superconductivity in the potassium osmium oxide KOs2O6 crystallizing in the beta-pyrochlore structure is studied by means of electrical resistivity, magnetic susceptibility and specific heat. It is the second superconductor in the family of…
Pressure dependence of superconducting transition temperature $T_{\rm c}$ has been determined through the DC magnetic measurements under pressure up to $P$=10 GPa for $\beta$-pyrochlore oxides AOs$_2$O$_6$ with A=Cs ($T_{\rm c}$=3.3 K), Rb…
Another phase transition that is probably of first order is found in the beta-pyrochlore oxide superconductor KOs2O6 with a superconducting transition temperature Tc of 9.6 K. It takes place at Tp=7.5 K in the superconducting state in a…
{\ss}-pyrochore KOs2O6, which shows superconductivity below ~ 9.7K, has been converted into KxOs2O6 (x < 2/3 - 1/2) electrochemically to show spin glass-like behavior below ~ 6.1K. Room temperature sample surface potential versus charge…
Single crystals of RbOs2O6 have been grown from Rb2O and Os in sealed quartz ampoules. The crystal structure has been identified at room temperature as cubic with the lattice constant a = 10.1242(12) A. The anisotropy of the tetrahedral and…
Two beta-pyrochlore oxide superconductors, CsOs2O6 and RbOs2O6, are studied thermodynamically by measuring specific heat on polycrystalline samples. It is found that a Sommerfeld coefficient ? is nearly equal, 20 mJ/K2 mol Os, in the two…
Polycrystalline sample of the new layered superconductor Bi4O4S3 is successfully synthesized by solid-state reaction method by using Bi, S and Bi2O3 powders with one step reaction. The superconducting transition temperature (Tconset=4.5 K),…
We develop a general procedure for the analysis of bulk thermodynamic data of a superconductor for samples containing a metallic non-superconducting second phase. The method is based on the condensation energy and it allows the extraction…
We report magnetization measurements under high hydrostatic pressure in the newly discovered pyrochlore superconductor RbOs_2O_6 (T_c\simeq6.3K at p=0). A pronounced and {\it positive} pressure effect (PE) on T_c with dT_c/dp…
The superconducting properties of two beta-pyrochlore oxides, CsOs2O6 and RbOs2O6, are studied by thermodynamic and transport measurements using high-quality single crystals. It is shown that the character of superconductivity changes…
Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…
The Tb-123 phase has been synthesized in single-phase form with the composition TbSr2Cu2.7Mo0.3O7 by solid-state reaction route and its phase purity is confirmed by neutron powder diffraction experiments. As-synthesized sample does not show…
We report the first pyrochlore oxide superconductor Cd2Re2O7. Resistivity,magnetic susceptibility,and specific heat measurements on single crystals evidence a bulk superconductivity at 1 K. Another phase transition found at 200 K suggests…
Here we report the preparation and superconductivity of the 133-type Cr-based quasi-one-dimensional (Q1D) RbCr3As3 single crystals. The samples were prepared by the deintercalation of Rb+ ions from the 233-type Rb2Cr3As3 crystals which were…
High pressure effects on the superconducting transitions of beta-pyrochlore superconductors AOs2O6 (A = Cs, Rb, K) are studied by measuring resistivity under high pressures up to 10 GPa. The superconducting transition temperature Tc first…