Related papers: Decomposition of solid solutions in the Nd-Ba-Cu-O…
We studied thermochemical characteristics of the Sm1+xBa2-xCu3Oy single crystals by solution calorimetry. Dependences of formation enthalpies from samarium content were constructed. It was established that solid solutions on the bases of…
The specific heat of Nd(Y)Ba2Cu3Ox single crystals without substitution of Nd for Ba has been measured for various oxygen contents. In comparison with YBa2Cu3Ox, the maximum attainable transition temperature of the crystals is about 4 K…
LaBaCaCu3O7 (La:1113) and NdBaCaCu3O7 (Nd:1113) compounds are synthesized by solid state reaction route. Both compounds crystallize in tetragonal structure. Four probe resistivity measurements showed that superconducting transition…
We report the decomposition of La2-xSrxCuO4 into La2O3 and Cu nanoparticles in ultra-high vacuum, observed by in-situ heating experiments in a transmission electron microscope (TEM). The analysis of electron diffraction data reveals that…
Extensive X-ray and neutron scattering experiments and additional transmission electron microscopy results reveal the partial decomposition of Nd2-xCexCuO4 (NCCO) in a low-oxygen-fugacity environment such as that typically realized during…
Bulk superconductor samples of YBa2Cu3-xCoxO7-{\delta} with x = 0, 0.01, 0.03, 0.05 are synthesized by solid-state reaction route. Both x-ray diffraction and electron microscopy have been employed to study the phase identification,…
We have investigated the influence of Ca ions substitution on the structural and superconducting properties of (Nd1-xCax)(Ba1.6La0.4)Cu3Oz system. Magnetization, X-ray diffraction and neutron diffraction studies have been carried out on a…
Substitutions of the zirconium and tin ions along with the indium-niobium and iron-niobium complexes for titanium in the barium modified NBT solid solutions impact the formation of phases in the process of the solid state synthesis and the…
Samples of YBa2-xSrxCu3O7-d (x = 0.0, 0.50, 1.0) series were synthesized by solid-state reaction and first annealed in flowing O2 gas. All samples crystallized in orthorhombic structure, where orthorhombic distortion was found to decrease…
In the Cu Cr system, the formation of supersaturated solid solutions can be obtained by severe plastic deformation. Energy dispersive synchrotron diffraction measurements on as deformed Cu Cr samples as a function of the applied strain…
The systems Nb$_2$O$_5$-Ta$_2$O$_5$ and Nb$_2$O$_5$-V$_2$O$_5$ were investigated using thermal analysis, X-ray powder diffraction and thermodynamic simulations. Solid solution formation is possible for both systems; furthermore, both…
The decomposition kinetics of a solid-solution into separate phases are analyzed with an equation of motion initially developed to account for dissipative processes in quantum systems. This equation and the steepest-entropy-ascent quantum…
Nitrogen oxides are textbook class of molecular compounds, with extensive industrial applications. Nitrogen and oxygen are also among the most abundant elements in the universe. We explore the N-O system at 0 K and up to 500 GPa though ab…
We studied Tc of YBa2Cu3Ox (Y123), Y0.89Ca0.11Ba2Cu3Ox (YCa123) and NdBa2Cu3Ox (Nd123) single crystals with various oxygen contents x. Compared to Tc(x) of Y123 the Tc(x) curves of YCa123 are shifted to lower oxygen contents and the maximum…
Carbon monoxide (CO) and nitrous oxide (N2O) both undergo profound structural and chemical transformations when compressed. While their individual high-P/T phase diagrams have been mapped in considerable detail, comparatively little…
The oxygenation process at constant temperature of YBa$_2$Cu$_3$O$_{7-\delta}$ (YBCO) was systematically investigated in the temperature range from 300 $^o$C to 800 $^o$C. With this purpose, fully deoxygenated powder samples was exposed to…
Transport and Cu-NQR studies have been carried out for the T*-type high temperature superconducting Cu oxide Nd1.6-xCexSr0.4CuO4 with single layered CuO2 planes formed by CuO5 pyramids. No anomaly related to the static or quasi static…
Formation of phases during the solid state synthesis of the barium-modified NBT solid solutions, with substitutions of zirconium and tin ions for titanium are investigated. The synthesis is a multi-step process which is accompanied by the…
Transport measurements on thin films of NdNiO$_3$ reveal a crossover to a regime of pronounced nonlinear conduction below the well-known metal-insulator transition temperature. The evolution of the transport properties at temperatures well…
The La-2125 type La2-xDyxCa2xBa2Cu4+2xOz (0.1 < x < 0.5; LDBO) compounds have been synthesized and studied for their structural and superconducting properties by room temperature neutron diffraction, high field dc magnetization, four-probe…