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In this paper we present a theoretical study of the third-order nonlinear optical properties of poly(diphenyl)polyacetylene (PDPA) pertaining to the third-harmonic-generation (THG) process. We study the aforesaid process in PDPA's using…

Materials Science · Physics 2010-01-14 Alok Shukla

Photo-physical and nonlinear-optical properties of a new amphiphilic conjugated polymer: hydroxylated pyridyl para-phenylene (Py-PhPPP) both in CH2Cl2 solution and in thin films have been investigated. By using Z-scan technique with…

Materials Science · Physics 2007-05-23 W. Ji , Hendry Izaac Elim , Jun He , F. Fitrilawati , C. Baskar , S. Valiyaveettil , W. Knoll

In a recently performed experiment Korovyanko et al [Phys. Rev. B 67, 035114 (2003)] have measured the photo-induced absorption (PA) spectrum of phenyl-disubstituted polyacetylenes (PDPA) from 1$B_{u}$ and 2$A_{g}$ excited states. In…

Materials Science · Physics 2010-01-14 Priya Sony , Alok Shukla

Phenyl-disubstituted polyacetylene (PDPA) is an organic semiconductor which has been studied during the last years for its efficient photo-luminescence. In contrast, the molecular geometry, providing the basis for the electronic and optical…

Materials Science · Physics 2010-08-02 Priya Sony , Alok Shukla , Claudia Ambrosch-Draxl

In this paper we present results of large-scale correlated calculations of triplet photoinduced absorption (PA) spectrum of oligomers of poly-(para)phenylenevinylene (PPV) containing up to five phenyl rings. In particular, the high-energy…

Condensed Matter · Physics 2010-01-14 Alok Shukla

We report a large third order nonlinear optical response of palladium diselenide (PdSe2) films, a two dimensional (2D) noble metal dichalcogenide material. Both open aperture (OA) and closed aperture (CA) Z scan measurements are performed…

Optics · Physics 2020-05-05 Linnan Jia , Jiayang Wu , Tieshan Yang , Baohua Jia , David J. Moss

In quasi-1D $\pi$-conjugated polymers such as \emph{trans}-polyacetylene and polyenes, electron correlation effects determine the "reversed" excited state ordering in which the lowest two-photon $2A_{g}$ state lies below the lowest…

Mesoscale and Nanoscale Physics · Physics 2018-07-10 Tista Basak , Tushima Basak , Alok Shukla

Non-degenerate two-photon absorption (TPA) is investigated in a nanophotonic silicon waveguide in a configuration such that the dispersion of the nonlinear absorption and refraction cannot be neglected. It is shown that a signal wave can…

We present a theoretical study of three-photon electromagnetically induced absorption for a ladder-type three-level atomic system. A probe beam was tuned to the lower line and two counter-propagating, linearly polarized coupling beams were…

Atomic Physics · Physics 2015-08-03 Heung-Ryoul Noh , Han Seb Moon

As a novel layered noble metal dichalcogenide material, palladium diselenide (PdSe2) has attracted wide interest due to its excellent optical and electronic properties. In this work, a strong third-order nonlinear optical response of 2D…

Optics · Physics 2021-07-01 David Moss

In this paper we present a computational study of linear optical absorption in phenacene class of polyaromatic hydrocarbons. For the purpose, we have employed a correlated-electron methodology based upon configuration-interaction (CI)…

Materials Science · Physics 2018-10-17 Deepak Kumar Rai , Alok Shukla

This study delves into the enhancement of two-photon absorption (2PA) properties in diazaacene-bithiophene derivatives through a synergistic approach combining theoretical analysis and experimental validation. By investigating the…

We have expressed the nonlinear optical absorption of a semiconductor in terms of its linear spectrum. We determined that the two-photon absorption coefficient in a strong DC-electric field of a direct gap semiconductor can be expressed as…

Optics · Physics 2009-11-13 Hernando Garcia , Ramki Kalyanaraman

Advanced photonic materials showing two-photon absorption (2PA) have been widely explored to develop three-dimensional imaging, micro and nanofabrication, all-optical switching, lithography on a nanoscale and many other enabling…

We have studied the adsorption of bisphenol-A-polycarbonate (BPA-PC) on the alpha-Al2O3(0001) surface using density-functional theory (DFT) with van der Waals (vdW) corrections. The BPA-PC polymer can be divided into its chemical fragments…

Materials Science · Physics 2012-05-30 Janne Blomqvist , Petri Salo

We study the dynamics of a single Frenkel exciton in a disordered molecular chain. The coherent-potential approximation (CPA) is applied to the situation when the single-molecule excitation energies as well as the transition dipole moments,…

Disordered Systems and Neural Networks · Physics 2011-05-11 D. B. Balagurov , G. C. La Rocca , V. M. Agranovich

The second order optical response of centrosymmetric materials manifests itself mostly at their surface, being strongly suppressed in their bulk. However, the overall surface response is also suppressed in nanoparticles with a…

Optics · Physics 2021-09-22 Raksha Singla , W. Luis Mochán

In this paper, we report theoretical calculations of the photo-induced absorption (PA) spectrum of naphthalene and anthracene, with the aim of understanding those excited states, which are invisible in the linear optical absorption. The…

Materials Science · Physics 2009-08-05 Priya Sony , Alok Shukla

A great deal of theoretical and experimental efforts have been devoted in the last decades to the study of long-wavelength photodetection mechanisms in field-effect transistors hosting two-dimensional (2D) electron systems. A particularly…

Mesoscale and Nanoscale Physics · Physics 2019-02-13 Alessandro Principi , Denis Bandurin , Habib Rostami , Marco Polini

In this paper we present large-scale correlated calculations of linear optical absorption spectrum of oligo-acenes containing up to seven benzene rings. For the calculations we used the Pariser-Parr-Pople (P-P-P) Hamiltonian, along with the…

Materials Science · Physics 2009-11-13 Priay Sony , Alok Shukla
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