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Monte Carlo simulations using a hybrid quantum and classical mechanical potential were performed for crystal and amorphous-like HCl-water(n) clusters The subsystem composed by HCl and one water molecule was treated within Density Functional…

Chemical Physics · Physics 2009-10-30 Dario A. Estrin , Jorge Kohanoff , Daniel H. Laria , Ruben O. Weht

Using Molecular Dynamics (MD) and Monte Carlo (MC) simulations interfacial properties of crystal-fluid interfaces are investigated for the hard sphere system and the one-component metallic system Ni (the latter modeled by a potential of the…

Materials Science · Physics 2015-05-13 T. Zykova-Timan , R. E. Rozas , J. Horbach , K. Binder

We consider a computational model for complex-fluid-solid interaction based on a diffuse-interface model for the complex fluid and a hyperelastic-material model for the solid. The diffuse-interface complex-fluid model is described by the…

Numerical Analysis · Mathematics 2015-10-09 E. H. van Brummelen , M. Shokrpour-Roudbari , G. J. van Zwieten

We investigate the value of the correlation function of an inhomogeneous hard-sphere fluid at contact. This quantity plays a critical role in Statistical Associating Fluid Theory (SAFT), which is the basis of a number of recently developed…

Soft Condensed Matter · Physics 2013-09-10 Jeff Schulte , Patrick Kreitzberg , Chris Haglund , David Roundy

We present Monte Carlo simulations of liquid-crystalline material confined to a nanoscopic slit-pore. The simulations are carried out under isothermal conditions in a specialized isostress ensemble in which N fluid molecules are exposed to…

Soft Condensed Matter · Physics 2010-04-30 Manuel Greschek , Martin Schoen

Bounded potentials are good models to represent the effective two-body interaction in some colloidal systems, such as dilute solutions of polymer chains in good solvents. The simplest bounded potential is that of penetrable spheres, which…

Statistical Mechanics · Physics 2007-05-23 Alexandr Malijevsky , Andres Santos

The fundamental measure approach to classical density functional theory has been shown to be a powerful tool to predict various thermodynamic properties of hard-sphere systems. We employ this approach to determine not only one-particle…

Soft Condensed Matter · Physics 2015-11-02 Andreas Härtel , Matthias Kohl , Michael Schmiedeberg

A model for the pair distribution function of nonequilibrium hard-core fluids is proposed based on a model for the effect of velocity correlations on the structure. Good agreement is found with molecular dynamics simulations of granular…

Statistical Mechanics · Physics 2009-10-31 James F. Lutsko

We study numerically the dynamo transition of an incompressible electrically conducting fluid filling the gap between two concentric spheres. In a first series of simulations, the fluid is driven by the rotation of a smooth inner sphere…

Fluid Dynamics · Physics 2012-11-13 K. Finke , A. Tilgner

We study structural and thermophysical properties of a one-dimensional classical fluid made of penetrable spheres interacting via an attractive square-well potential. Penetrability of the spheres is enforced by reducing from infinite to…

Soft Condensed Matter · Physics 2009-09-24 Riccardo Fantoni , Achille Giacometti , Alexandr Malijevský , Andrés Santos

In a recent paper [Phys. Rev. E \textbf{76}, 031202 (2007)], Schmidt has proposed a Fundamental Measure Density Functional Theory for one-dimensional nonadditive hard-rod fluid mixtures and has compared its predictions for the bulk…

Soft Condensed Matter · Physics 2007-12-19 Andres Santos

Using Monte Carlo simulations, we investigate the electrical conductivity of networks of hard rods as a function of the volume fraction for two tunneling conductance models. For a simple, orientationally independent tunneling model, we…

Soft Condensed Matter · Physics 2018-12-26 Arshia Atashpendar , Sarthak Arora , Alexander D. Rahm , Tanja Schilling

Positional ordering of a two-dimensional fluid of hard disks is examined in such narrow tubes where only the nearest-neighbor interactions take place. Using the exact transfer-matrix method the transverse and longitudinal pressure…

Statistical Mechanics · Physics 2015-05-30 S. Varga , G. Balló , P. Gurin

We investigate interfacial properties between two highly incompatible polymers of different stiffness. The extensive Monte Carlo simulations of the binary polymer melt yield detailed interfacial profiles and the interfacial tension via an…

Statistical Mechanics · Physics 2009-10-30 Marcus Mueller , Andreas Werner

The task of accurately locating fluid phase boundaries by means of computer simulation is hampered by problems associated with sampling both coexisting phases in a single simulation run. We explain the physical background to these problems…

Statistical Mechanics · Physics 2009-11-07 N. B. Wilding

By using the Rosenfeld density functional we determine the number density profiles of both components of binary hard-sphere fluids close to a planar hard wall as well as the corresponding excess coverage and surface tension. The comparison…

Soft Condensed Matter · Physics 2009-10-31 R. Roth , S. Dietrich

We examine the dynamics of hard spheres and discs at high packing fractions in two and three dimensions, modeling the simplest systems exhibiting a glass transition. As it is well known, cooperativity and dynamic heterogeneity arise as…

Soft Condensed Matter · Physics 2007-05-23 Burkhard Doliwa , Andreas Heuer

Computer simulations of hard spheres and disks are used to estimate the most probable cavity size, $\xi_{\rm cavity}$, and a ``rattle'' size, $\xi_{\rm rattle}$, over which a particle can translate holding all other particles fixed. Both of…

Soft Condensed Matter · Physics 2007-05-23 Sanat K. Kumar , Shekhar Garde , Jack F. Douglas , Francis W. Starr

The phase behavior of the Baxter adhesive hard sphere fluid has been determined using specialized Monte Carlo simulations. We give a detailed account of the techniques used and present data for the fluid-fluid coexistence curve as well as…

Soft Condensed Matter · Physics 2009-11-10 M. A. Miller , D. Frenkel

The crystal-melt interfaces of a binary hard-sphere fluid mixture in coexistence with a single-component hard-sphere crystal is investigated using molecular-dynamics simulation. In the system under study, the fluid phase consists of a…

Chemical Physics · Physics 2009-11-07 Rachel Sibug-Aga , Brian B. Laird