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This paper employs the general time-space fractional diffusion equation to derive correlation time function for analyzing nuclear magnetic resonance (NMR) relaxation. Both the anomalous rotational and translational diffusion are treated.…

Chemical Physics · Physics 2018-12-31 Guoxing Lin

In-situ NMR spin-lattice relaxation measurements were performed on several vapor deposited ices. The measurements, which span more than 6 orders of magnitude in relaxation times, show a complex spin-lattice relaxation pattern that is…

Materials Science · Physics 2018-05-31 E. Lisitsin-Baranovsky , S. Delage , O. Sucre , O. Ofer , P. Ayotte , G. Alexandrowicz

We consider nuclear spin-lattice relaxation rate resulted from a fractional diffusion equation for anomalous rotational wobbling in a cone. The mechanism of relaxation is assumed to be due to dipole-dipole interaction of nuclear spins and…

Statistical Mechanics · Physics 2011-06-30 A. E. Sitnitsky

We present a first step toward a microscopic theory for the glass transition in systems with trivial static correlations. As an example we have chosen N infinitely thin hard rods with length L, fixed with their centers on a periodic lattice…

Soft Condensed Matter · Physics 2009-11-07 Rolf Schilling , Grzegorz Szamel

Application of fractional calculus to the description of anomalous diffusion and relaxation processes in complex media provided one of the most impressive impulses to the development of statistical physics during the last decade. In…

Soft Condensed Matter · Physics 2008-11-13 A. E. Sitnitsky

We consider nuclear spin-lattice relaxation rate resulted from a diffusion equation for rotational wobbling in a cone. We show that the widespread point of view that there are no analytical expressions for correlation functions for wobbling…

Soft Condensed Matter · Physics 2015-05-30 A. E. Sitnitsky

This paper proposes an effective diffusion equation method to analyze nuclear magnetic resonance (NMR) relaxation. NMR relaxation is a spin system recovery process, where the evolution of the spin system is affected by the random field due…

Chemical Physics · Physics 2021-03-31 Guoxing Lin

A general expression is derived for the dipolar NMR spin-lattice relaxation rate $1/T_1$ of a system exhibiting Brownian dynamics in a discrete and finite configuration space. It is shown that this approach can be particularly useful to…

Chemical Physics · Physics 2015-07-07 P. Wzietek

The theory of spin diffusion is extended to the case of spin lattice relaxation and spin diffusion in an inhomogeneous field in spin systems with non-equidistant energy spectrum. Two coupled equations describing the mutual relaxation and…

Materials Science · Physics 2007-05-23 Gregory B. Furman , Shaul D. Goren

A comprehensive theoretical description is given for the spin relaxation and diffusion in solids. The formulation is made in a general statistical-mechanical way. The method of the nonequilibrium statistical operator (NSO) developed by D.…

Statistical Mechanics · Physics 2009-11-11 A. L. Kuzemsky

We study dynamical heterogeneity and glassy dynamics in a kinetically constrained lattice gas model which has both translational and rotational degrees of freedom. We find that the rotational diffusion constant tracks the structural…

Soft Condensed Matter · Physics 2015-06-25 Albert C. Pan

The relation between relaxation and diffusion is investigated in a Hamiltonian system of globally coupled rotators. Diffusion is anomalous if and only if the system is going towards equilibrium. The anomaly in diffusion is not anomalous…

Chaotic Dynamics · Physics 2007-05-23 Yamaguchi Y. Yoshiyuki

We investigate the translational and rotational relaxation dynamics of a crowded two-dimensional system of monodisperse Penrose kites, in which crystallization, quasi-crystallization, and nematic ordering are suppressed, from low to high…

Soft Condensed Matter · Physics 2020-01-15 Yan-Wei Li , Zi-Qi Li , Zhang-Lin Hou , Thomas G. Mason , Kun Zhao , Zhao-Yan Sun , Massimo Pica Ciamarra

We present $^{75}$As nuclear magnetic resonance spin-lattice and spin-spin relaxation rate data in Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$ and Ba(Fe$_{1-x}$Cu$_x$)$_2$As$_2$ as a function of temperature, doping and magnetic field. The relaxation…

Finite-temperature local spin dynamics within the random spin-1/2 antiferromagnetic Heisenberg chain is studied numerically. The aim is to explain measured NMR spin-lattice relaxation times in BaCu_{2}(Si_{0.5}Ge_{0.5})_{2}O_{7}, which is…

Strongly Correlated Electrons · Physics 2013-10-04 J. Herbrych , J. Kokalj , P. Prelovšek

Based on the canonical formalism, the dilatation symmetry is implemented to the Fokker-Planck equation for the Wigner distribution function that describes atomic motion in an optical lattice. This reveals the symmetry principle underlying…

Statistical Mechanics · Physics 2016-08-31 Sumiyoshi Abe

We demonstrate an unexpected decay-recovery behaviour in the time-dependent $^{1}\mathrm{H}$ NMR relaxation times of water confined within a hydrating porous material. Our observations are rationalised by considering the combined effects of…

Mesoscale and Nanoscale Physics · Physics 2023-03-27 Neil Robinson , Razyq Nasharuddin , Einar O. Fridjonsson , Michael L. Johns

In a preceding paper, Mukhopadhyay and I studied the diffusive motion of a tagged molecule in a heterogeneous glass-forming liquid at temperatures just above a glass transition. Among other features of this system, we postulated a relation…

Statistical Mechanics · Physics 2009-11-13 J. S. Langer

In graphene, out-of-plane (flexural) vibrations and static ripples imposed by the substrate relax the electron spin, intrinsically protected by mirror symmetry. We calculate the relaxation times in different scenarios, accounting for all…

Mesoscale and Nanoscale Physics · Physics 2017-05-08 I. M. Vicent , H. Ochoa , F. Guinea

We present an analytical and numerical study of a nonlinear diffusion model which describes density relaxation of loosely packed particles under gravity and weak random (thermal) vibration, and compare the results with Monte Carlo…

Soft Condensed Matter · Physics 2009-11-10 Jeferson J. Arenzon , Yan Levin , Mauro Sellitto
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