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Another phase transition that is probably of first order is found in the beta-pyrochlore oxide superconductor KOs2O6 with a superconducting transition temperature Tc of 9.6 K. It takes place at Tp=7.5 K in the superconducting state in a…

Superconductivity · Physics 2015-06-25 Z Hiroi , S Yonezawa , J Yamaura

Resistivity and specific heat have been measured on a single crystalline sample of the beta-pyrochlore oxide superconductor, KOs2O6. It is found that a second peak in specific heat, which may evidence an unknown phase transition, appears…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Shigeki Yonezawa , Jun-Ichi Yamaura , Takaki Muramatsu , Yuji Muraoka

The discovery of a new beta-pyrochlore oxide superconductor CsOs2O6 with Tc = 3.3 K is reported. It is the third superconductor in the family of beta-pyrochlore oxides, following KOs2O6 with Tc = 9.6 K and RbOs2O6 with Tc = 6.3 K. The Tc of…

Superconductivity · Physics 2009-11-10 Shigeki Yonezawa , Yuji Muraoka , Zenji Hiroi

Pressure dependence of superconducting transition temperature $T_{\rm c}$ has been determined through the DC magnetic measurements under pressure up to $P$=10 GPa for $\beta$-pyrochlore oxides AOs$_2$O$_6$ with A=Cs ($T_{\rm c}$=3.3 K), Rb…

Superconductivity · Physics 2009-11-13 K. Miyoshi , Y. Takaichi , Y. Takamatsu , M. Miura , J. Takeuchi

We report the discovery of a new pyrochlore oxide superconductor RbOs2O6. The compound crystallizes in the same beta-pyrochlore structure as the recently discovered superconductor KOs2O6, where Os atoms form a corner-sharing tetrahedral…

Superconductivity · Physics 2009-11-10 S. Yonezawa , Y. Muraoka , Y. Matsushita , Z. Hiroi

To elucidate the nature of the superconducting ground state of the geometrically frustrated pyrochlore KOs2O6 (Tc=9.6K), the thermal conductivity was measured down to low temperatures (~Tc/100). We found that the quasiparticle mean free…

Superconductivity · Physics 2009-11-11 Y. Kasahara , Y. Shimono , T. Shibauchi , Y. Matsuda , S. Yonezawa , Y. Muraoka , Z. Hiroi

Single crystals of KOs2O6 have been grown in a sealed quartz ampoule. Detailed single crystal X-ray diffraction studies at room temperature show Bragg peaks that violate Fd-3m symmetry. With a comparative structure refinement the structure…

Superconductivity · Physics 2009-11-11 G. Schuck , S. M. Kazakov , K. Rogacki , N. D. Zhigadlo , J. Karpinski

High pressure effects on the superconducting transitions of beta-pyrochlore superconductors AOs2O6 (A = Cs, Rb, K) are studied by measuring resistivity under high pressures up to 10 GPa. The superconducting transition temperature Tc first…

Superconductivity · Physics 2009-11-11 T. Muramatsu , N. Takeshita , C. Terakura , H. Takagi , Y. Tokura , S. Yonezawa , Y. Muraoka , Z. Hiroi

Rattling-induced superconductivity in the {\beta}-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition…

We report the superconducting properties of the pyrochlore oxide Cd2Re2O7. The bulk superconducting transition temperature Tc is about 1.0 K, and the upper critical field Hc2 determined by the measurement of specific heat under magnetic…

Superconductivity · Physics 2009-11-07 Z. Hiroi , M. Hanawa

We make the first report that a metallic pyrochlore oxide \Cd2Re2O7, exhibits type II superconductivity at 1.1 K. The pyrochlore oxide is known to be a geometrical frustrated system, which includes the tetrahedral network of magnetic ions.…

Strongly Correlated Electrons · Physics 2016-08-16 H. Sakai , K. Yoshimura , H. Ohno , H. Kato , S. Kambe , R. E. Walstedt , T. D. Matsuda , Y. Haga , Y. Ōnuki

We report the first pyrochlore oxide superconductor Cd2Re2O7. Resistivity,magnetic susceptibility,and specific heat measurements on single crystals evidence a bulk superconductivity at 1 K. Another phase transition found at 200 K suggests…

Superconductivity · Physics 2019-08-17 M. Hanawa , Y. Muraoka , T. Tayama , T. Sakakibara , J. Yamaura , Z. Hiroi

Two beta-pyrochlore oxide superconductors, CsOs2O6 and RbOs2O6, are studied thermodynamically by measuring specific heat on polycrystalline samples. It is found that a Sommerfeld coefficient ? is nearly equal, 20 mJ/K2 mol Os, in the two…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Shigeki Yonezawa , Takaki Muramatsu , Jun-Ichi Yamaura , Yuji Muraoka

{\ss}-pyrochore KOs2O6, which shows superconductivity below ~ 9.7K, has been converted into KxOs2O6 (x < 2/3 - 1/2) electrochemically to show spin glass-like behavior below ~ 6.1K. Room temperature sample surface potential versus charge…

Superconductivity · Physics 2015-05-27 C. C. Lee , W. L. Lee , J. -Y. Lin , C. C. Tsuei , J. G. Lin , F. C. Chou

Rattling-induced superconductivity in the beta-pyrochlore oxide RbOs2O6 is investigated under high pressures up to 6 GPa. Resistivity measurements in a high-quality single crystal show that the superconducting transition temperature Tc…

Superconductivity · Physics 2011-10-04 Nao Takeshita , Hiroki Ogusu , Jun-ichi Yamaura , Yoshihiko Okamoto , Zenji Hiroi

We report the basic thermodynamic properties of the new geometrically frustrated beta-pyrochlore bulk superconductor RbOs2O6 with a critical temperature Tc = 6.4 K. Specific heat measurements are performed in magnetic fields up to 12 T. The…

Superconductivity · Physics 2009-11-10 M. Brühwiler , S. M. Kazakov , N. D. Zhigadlo , J. Karpinski , B. Batlogg

The entire temperature dependence of the upper critical field $H_{\rm c2}$ in the $\beta$-pyrochlore KOs$_2$O$_6$ is obtained from high-field resistivity and magnetic measurements. Both techniques identically give $H_{\rm c2}(T \simeq 0…

Chemical trends of fundamental superconducting parameters and normal-state properties are described for a family of pyrochlore oxide superconductors. Particularly, the change of Tc from 1.0 K for alpha-pyrochlore Cd2Re2O7 to 3.3 K (A = Cs),…

Superconductivity · Physics 2009-11-11 Zenji Hiroi , Jun-Ichi Yamaura , Shigeki Yonezawa , Hisatomo Harima

Electronic, magnetic, and dynamical properties of the new superconducting $\beta$-pyrochlore KOs$_2$O$_6$ and related RbOs$_2$O$_6$ and CsOs$_2$O$_6$ compounds are calculated and compared with experiment and contrasted with structurally…

Superconductivity · Physics 2009-11-10 J. Kunes , T. Jeong , W. E. Pickett

We report the observation of superconductivity in high-quality Cd$_2$Re$_2$O$_7$ single crystals with room-temperature pyrochlore structure. Resistivity and ac susceptibility measurements establish an onset transition temperature…

Superconductivity · Physics 2009-11-07 R. Jin , J. He , S. McCall , C. S. Alexander , F. Drymiotis , D. Mandrus
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