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We show that continuous filling or wedge-wetting transitions are possible in 3D wedge-geometries made from (angled) substrates exhibiting first-order wetting transitions and develop a comprehensive fluctuation theory yielding a complete…

Condensed Matter · Physics 2009-10-31 A. O. Parry , C. Rascon , A. J. Wood

A comprehensive theory of interfacial fluctuation effects occurring at 2D wedge (corner) filling transitions in pure (thermal disorder) and impure (random bond-disorder) systems is presented. Scaling theory and the explicit results of…

Soft Condensed Matter · Physics 2009-11-07 A. O. Parry , M. J. Greenall , A. J. Wood

Interfacial fluctuation effects occuring at wedge and cone filling transitions are investigated and shown to exhibit very different characteristics. For both geometries we show how the conditions for observing critical (continuous) filling…

Soft Condensed Matter · Physics 2009-10-31 A. O. Parry , A. J. Wood , C. Rascon

We show that the 3D wedge filling transition in the presence of short-ranged interactions can be first-order or second order depending on the strength of the line tension associated with to the wedge bottom. This fact implies the existence…

Statistical Mechanics · Physics 2009-11-11 J. M. Romero-Enrique , A. O. Parry

Fluids adsorbed in 3D wedges are shown to exhibit two types of continuous interfacial unbinding corresponding to critical and tricritical filling respectively. Analytic solution of an effective interfacial model based on the transfer-matrix…

Statistical Mechanics · Physics 2009-11-11 J. M. Romero-Enrique , A. O. Parry

We study filling phenomena in 3D wedge geometries paying particular attention to the role played by a line tension associated with the wedge bottom. Our study is based on transfer matrix analysis of an effective one dimensional model of 3D…

Soft Condensed Matter · Physics 2009-11-13 J. M. Romero-Enrique , A. O. Parry

We study 2D wedge wetting using a continuum interfacial Hamiltonian model which is solved by transfer-matrix methods. For arbitrary binding potentials, we are able to exactly calculate the wedge free-energy and interface height distribution…

Condensed Matter · Physics 2009-10-31 A. O. Parry , C. Rascon , A. J. Wood

Interfacial phenomena associated with fluid adsorption in two dimensional systems has recently been shown to exhibit hidden symmetries, or covariances, which precisely relate local adsorption properties in different confining geometries. We…

Statistical Mechanics · Physics 2009-11-10 C. Rascon , A. O. Parry

Interfacial structure and correlation functions near a two-dimensional (2D) wedge filling transition are studied using effective interfacial Hamiltonian models. An exact solution for short range binding potentials and results for Kratzer…

Statistical Mechanics · Physics 2009-11-10 J. M. Romero-Enrique , A. O. Parry , M. J. Greenall

We propose a method to describe the short-distance behavior of an interface fluctuating in the presence of the wedge-shaped substrate near the critical filling transition. Two different length scales determined by the average height of the…

Statistical Mechanics · Physics 2009-10-31 A. Bednorz , M. Napiorkowski

In this Letter we present evidences of the occurrence of a tricritical filling transition for an Ising model in a linear wedge. We perform Monte Carlo simulations in a double wedge where antisymmetric fields act at the top and bottom…

Soft Condensed Matter · Physics 2015-06-22 A. Rodriguez-Rivas , J. M. Romero-Enrique , L. F. Rull , A. Milchev

We have developed a theory for inhomogeneous systems that allows for incorporation of effects of mesoscopic fluctuations. A hierarchy of equations relating the correlation and direct correlation functions for the local excess $\phi({\bf…

Statistical Mechanics · Physics 2016-09-21 Alina Ciach , Wojciech T. Gozdz

The ensemble-switch method for computing wall excess free energies of condensed matter is extended to estimate the interface free energies between coexisting phases very accurately. By this method, system geometries with linear dimensions…

Statistical Mechanics · Physics 2014-06-04 Fabian Schmitz , Peter Virnau , Kurt Binder

We use microscopic density functional theory to study filling transitions in systems with long-ranged wall-fluid and short-ranged fluid-fluid forces occurring in a right-angle wedge. By changing the strength of the wall-fluid interaction we…

Statistical Mechanics · Physics 2016-05-04 Alexandr Malijevský , Andrew O. Parry

The computation of interfacial free energies between coexisting phases (e.g.~saturated vapor and liquid) by computer simulation methods is still a challenging problem due to the difficulty of an atomistic identification of an interface, and…

Statistical Mechanics · Physics 2015-06-19 Fabian Schmitz , Peter Virnau , Kurt Binder

We show that condensation in a capped capillary slit is a continuous interfacial critical phenomenon, related intimately to several other surface phase transitions. In three dimensions (3d), the adsorption and desorption branches correspond…

Statistical Mechanics · Physics 2007-05-23 A. O. Parry , C. Rascon , N. B. Wilding , R. Evans

The surface tension of rough interfaces between coexisting phases in 2D and 3D Ising models are discussed in view of the known results and some original calculations presented in this paper. The results are summarised in a formula, which…

Statistical Mechanics · Physics 2009-11-11 J. Kaupuzs

We present an introduction to modern theories of interfacial fluctuations and the associated interfacial parameters: surface tension and surface stiffness, as well as their interpretation within the capillary wave model. Transfer matrix…

Condensed Matter · Physics 2014-10-13 Vladimir Privman

Critical wetting is an elusive phenomenon for solid-fluid interfaces. Using interfacial models we show that the diverging length scales, which characterize complete wetting at an apex, precisely mimic critical wetting with the apex angle…

Statistical Mechanics · Physics 2009-11-07 A. O. Parry , M. J. Greenall , J. M. Romero-Enrique

A model describing the three-dimensional folding of the triangular lattice on the face-centered cubic lattice is generalized allowing the presence of defects corresponding to cuts in the two-dimensional network. The model can be expressed…

Statistical Mechanics · Physics 2012-05-25 Emilio N. M. Cirillo , Alessandro Pelizzola , Giuseppe Gonnella
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