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We extend the Intrinsic Atomic Orbital (IAO) method for localisation of molecular orbitals to calculate well-localised generalised Wannier functions in crystals using the Pipek--Mezey locality metric. We furthermore present a one-shot…

Materials Science · Physics 2024-07-02 Andrew Zhu , David P. Tew

We consider the applicability of phase space Wannier functions" to electronic structure calculations. These generalized Wannier functions are analogous to localized plane waves and constitute a complete, orthonormal set which is…

Other Condensed Matter · Physics 2010-07-22 D. J. Sullivan , J. J. Rehr , J. W. Wilkins , K. G. Wilson

A recently proposed ab initio Hartree-Fock approach aimed at directly obtaining the Wannier functions of a crystalline insulator is applied to polymers. The systems considered are the LiH chain and trans-polyacetylene. In addition to being…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Hermann Stoll

We have constructed maximally-localized Wannier functions for prototype structures of solid molecular hydrogen under pressure, starting from LDA and tight-binding Bloch wave functions. Each occupied Wannier function can be associated with…

Materials Science · Physics 2009-10-31 Ivo Souza , Richard M. Martin , Nicola Marzari , Xinyuan Zhao , David Vanderbilt

The spatial decay properties of Wannier functions and related quantities have been investigated using analytical and numerical methods. We find that the form of the decay is a power law times an exponential, with a particular power-law…

Materials Science · Physics 2009-11-07 Lixin He , David Vanderbilt

Wannier functions of the one dimensional Schroedinger equation with elliptic one gap potentials are explicitly constructed. Properties of these functions are analytically and numerically investigated. In particular we derive an expression…

Soft Condensed Matter · Physics 2009-11-10 E D Belokolos , V Z Enolskii , M Salerno

An exact analytical expression is derived for Bloch states in three dimensions, based on the only assumption that the electronic wavefunction can be expanded in terms of Gaussian type orbitals. The resulting expression features…

Materials Science · Physics 2025-08-08 Emanuele Maggio

In the present letter, we report the extension of our Wannier-function-based ab initio Hartree-Fock approach---meant originally for three-dimensional crystalline insulators---to deal with quasi-one-dimensional periodic systems such as…

Condensed Matter · Physics 2009-10-31 Alok Shukla , Michael Dolg , Hermann Stoll

In this work, we use Wannier functions to analyze topological phase transitions in one dimensional photonic crystals. We first review the construction of exponentially localized Wannier functions in one dimension, and show how to…

Optics · Physics 2022-06-07 Vaibhav Gupta , Barry Bradlyn

The topology of two-dimensional materials traditionally manifests itself through the quantization of the Hall conductance, which is revealed in transport measurements. Recently, it was predicted that topology can also give rise to a…

We identify a mapping between two-dimensional (2D) electron transport in a minimally twisted graphene bilayer and a 1D quantum walk, where one spatial dimension plays the role of time. In this mapping a magnetic field B perpendicular to the…

Mesoscale and Nanoscale Physics · Physics 2022-11-02 T. Vakhtel , D. O. Oriekhov , C. W. J. Beenakker

Non-trivial Chern classes pose an obstruction to the existence of exponentially decaying Wannier functions which provide natural bases for spectral subspaces. For non-trivial Bloch bundles, we obtain decay rates of Wannier functions in…

Mathematical Physics · Physics 2025-05-06 Simon Becker , Zhongkai Tao , Mengxuan Yang

The electronic ground state of a periodic crystalline solid is usually described in terms of extended Bloch orbitals; localized Wannier functions can alternatively be used. These two representations are connected by families of unitary…

Materials Science · Physics 2009-10-31 Nicola Marzari , David Vanderbilt

We review the formalisms of the self-consistent GW approximation to many-body perturbation theory and of the generation of optimally-localized Wannier functions from groups of energy bands. We show that the quasiparticle Bloch wave…

Materials Science · Physics 2009-11-13 D. R. Hamann , David Vanderbilt

In this paper we consider Wannier functions of quasi-periodic g-gap ($g\geq 1$) potentials and investigate their main properties. In particular, we discuss the problem of averaging underlying the definition of Wannier functions for both…

Mathematical Physics · Physics 2009-11-10 E. D. Belokolos , V. Z. Enolskii , M. Salerno

In the Hermitian regime, the Wannier-Stark ladder characterizes the eigenstates of an electron in a periodic potential with an applied static electric field. In this work, we extend this concept to the complex regime for a periodic…

Quantum Physics · Physics 2024-12-20 H. P. Zhang , Z. Song

Motivated by recent developments in quantum simulation of synthetic dimensions, e.g. in optical lattices of ultracold atoms, we discuss here $d$-dimensional periodic, gapped quantum systems for $d \le 4$, with focus on the topology of the…

Mathematical Physics · Physics 2023-02-06 Domenico Monaco , Thaddeus Roussigné

Wannier functions provide a localized representation of spectral subspaces of periodic Hamiltonians, and play an important role for interpreting and accelerating Hartree-Fock and Kohn-Sham density functional theory calculations in quantum…

Computational Physics · Physics 2018-01-29 Anil Damle , Antoine Levitt , Lin Lin

The Bloch wavefunction leads either to mathematically impossible consequences or suggests that the ground state energy is a function of size and shape when the geometry of large crystals is considered in detail. It is incompatible with the…

Materials Science · Physics 2008-06-20 T. R. S. Prasanna

We present a first-principles calculation of the electronic properties of crystalline silicon and gallium arsenide in a uniform electric field. Polarized Wannier-like functions which are confined in a finite region are obtained by…

Materials Science · Physics 2007-05-23 Pablo Fernández , Andrea Dal Corso , Alfonso Baldereschi