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A variety of enhanced statistical and numerical methods are now routinely used to extract comprehensible and relevant thermodynamic information from the vast amount of complex, high-dimensional data obtained from intensive molecular…

Soft Condensed Matter · Physics 2020-10-14 Francois Sicard , Vladimir Koskin , Alessia Annibale , Edina Rosta

The self-diffusion constant D is expressed in terms of transitions among the local minima of the potential (inherent structure, IS) and their correlations. The formulae are evaluated and tested against simulation in the supercooled,…

Statistical Mechanics · Physics 2009-10-31 T. Keyes , J. Chowdhary

Based on the non-Markov diffusion equation taking into account the spatial fractality and modeling for the generalized coefficient of particle diffusion…

Statistical Mechanics · Physics 2024-06-19 P. Kostrobij , M. Tokarchuk , B. Markovych , I. Ryzha

Local diffusion coefficients in disordered systems such as spin glass systems and living cells are highly heterogeneous and may change over time. Such a time-dependent and spatially heterogeneous environment results in irreproducibility of…

Statistical Mechanics · Physics 2016-12-21 Takuma Akimoto , Eiji Yamamoto

Recently there has been growing interest in nanofluids and nanodroplet engineering and applications. In this paper we derive a theory of Lennard-Jones fluids in multiphase dynamics from the information theoretic approach in analogy to the…

Statistical Mechanics · Physics 2010-02-02 Fredrick Michael

As well known, the generalized Langevin equation with a memory kernel decreasing at large times as an inverse power law of time describes the motion of an anomalously diffusing particle. Here, we focus attention on some new aspects of the…

Statistical Mechanics · Physics 2011-05-27 Noëlle Pottier

We present the results of a large scale molecular dynamics computer simulation study in which we investigate whether a supercooled Lennard-Jones liquid exhibits dynamical heterogeneities. We evaluate the non-Gaussian parameter for the self…

Disordered Systems and Neural Networks · Physics 2009-10-30 Walter Kob , Claudio Donati , Steven J. Plimpton , Peter H. Poole , Sharon C. Glotzer

Using molecular dynamics simulation, we have calculated the pressure dependence of the diffusion constant in a binary Lennard-Jones Glass. We observe four temperature regimes. The apparent activation volume drops from high values in the hot…

Disordered Systems and Neural Networks · Physics 2009-11-07 H. R. Schober

Using molecular dynamics simulations we examine the system size dependence of the fast dynamics in two model glass forming liquids, one of them a Lennard-Jones mixture for which cooperative fast relaxation has been reported. We find no…

Soft Condensed Matter · Physics 2018-10-17 D. Fragiadakis , C. M. Roland

We consider Langevin equation with dichotomously fluctuating diffusivity, where the diffusion coefficient changes dichotomously in time, in order to study fluctuations of time-averaged observables in temporary heterogeneous diffusion…

Statistical Mechanics · Physics 2016-06-15 Takuma Akimoto , Eiji Yamamoto

We present results of theoretical description and numerical calculation of the dynamics of molecular liquids based on the Reference Interaction Site Model / Mode-Coupling Theory. They include the temperature-pressure(density) dependence of…

Chemical Physics · Physics 2007-05-23 A. E. Kobryn , T. Yamaguchi , F. Hirata

We study a diffusion process with random space-time dependent coefficients. Moreover the diffusion matrix is allowed to degenerate. An invariance principle is proved provided that the diffusion coefficient is controlled by a time…

Probability · Mathematics 2016-08-16 Rémi Rhodes

We analyze the influence of boundary conditions on numerical simulations of the diffusive properties of a two dimensional granular gas. We show in particular that periodic boundary conditions introduce unphysical correlations in time which…

Statistical Mechanics · Physics 2009-10-31 C. Henrique , G. Batrouni , D. Bideau

We calculate the diffusion coefficients of persistent random walks on lattices, where the direction of a walker at a given step depends on the memory of a certain number of previous steps. In particular, we describe a simple method which…

Statistical Mechanics · Physics 2013-02-07 Thomas Gilbert , David P. Sanders

This series of papers is devoted to identifying and explaining the properties of strongly correlating liquids, i.e., liquids with more than 90% correlation between their virial W and potential energy U fluctuations in the NVT ensemble.…

Soft Condensed Matter · Physics 2012-03-27 Thomas B. Schrøder , Nicoletta Gnan , Ulf R. Pedersen , Nicholas P. Bailey , Jeppe C. Dyre

Lateral diffusion of molecules on surfaces plays a very important role in various biological processes, including lipid transport across the cell membrane, synaptic transmission and other phenomena such as exo- and endocytosis, signal…

Analysis of PDEs · Mathematics 2013-11-12 A. B. Duncan , C. M. Elliott , G. A. Pavliotis , A. M. Stuart

We report results of molecular dynamics simulations of a binary Lennard-Jones system at zero pressure in the undercooled liquid and glassy states. We first follow the evolution of diffusivity and dynamic heterogeneity with temperature and…

Disordered Systems and Neural Networks · Physics 2007-05-23 H. R. Schober

A space fractional diffusion-like equation is introduced, which embodies the nonlocality in time, represented by the memory kernel and the non-locality in space. A specific example of the nonlocal term is considered in combination with…

Statistical Mechanics · Physics 2026-01-06 Pece Trajanovski , Irina Petreska , Katarzyna Gorska , Ljupco Kocarev , Trifce Sandev

We investigate a binary Lennard-Jones mixture with molecular dynamics simulations. We consider first a system cooled linearly in time with the cooling rate gamma. By varying gamma over almost four decades we study the influence of the…

Statistical Mechanics · Physics 2015-06-25 K. Vollmayr-Lee , W. Kob , K. Binder , A. Zippelius

In this paper we study a storage process or a liquid queue in which the input process is the local time of a positively recurrent stationary diffusion in stationary state and the potential output takes place with a constant deterministic…

Probability · Mathematics 2007-05-23 M. Kozlova , P. Salminen