Related papers: Enhancement of solid-state proton NMR via SPINOE w…
The Overhauser effect (OE) and the Solid effect (SE) are two Dynamic Nuclear Polarization techniques. These two-spin techniques are widely used to create nonequilibrium nuclear spin states having polarization far beyond its equilibrium…
We report measurements of enhanced tensor polarization on solid-state targets. The results here represent an increase in tensor polarization over that previously achieved in high energy and nuclear scattering experiments that focused on the…
We report on hyperpolarization of quadrupolar (I=3/2) 131Xe via spin-exchange optical pumping. Observations of the 131Xe polarization dynamics show that the effective alkali-metal/131Xe spin-exchange cross-sections are large enough to…
We propose a scalable and practical implementation of spin amplification which does not require individual addressing nor a specially tailored spin network. We have demonstrated a gain of 140 in a solid-state nuclear spin system of which…
We measured the spin noise spectroscopy (SNS) of rubidium atomic ensemble with two different atomic vapor cells (filled with the buffer gases or coated with paraffin film on the inner wall), and demonstrated the enhancement of signal to…
We propose a new, more efficient, and potentially cost effective, solid-state nuclear spin hyperpolarization method combining the Cross Effect mechanism and electron spin optical hyperpolarization in rotating solids. We first demonstrate…
We report on a study of Dynamic Nuclear Polarization and electron and nuclear spin relaxation of atomic hydrogen and deuterium in solid molecular matrices of H$_{2}$, D$_{2}$, and HD mixtures. The electron and nuclear spin relaxation times…
Recently, Pang et al reported a novel polarization transfer scheme applicable to three-spin systems, whereby a rotating-frame NMR analogue of the cross effect could transfer polarization between; e.g., two 13Cs and an 15N in a single…
We describe a new method for pulsed spin order transfer (SOT) of parahydrogen induced polarization (PHIP) that enables close to 100 % polarization in incompletely 2H-labeled molecules by exciting only the desired protons in a…
Chemical exchange saturation transfer (CEST) is widely used for enhancing the solution NMR signatures of magnetically-dilute spin pools; in particular species at low concentrations undergoing chemical exchanges with an abundant spin pool.…
Nuclear spin hyperpolarization provides a promising route to overcome the challenges imposed by the limited sensitivity of nuclear magnetic resonance. Here we demonstrate that dissolution of spin-polarized pentacene-doped naphthalene…
We exploit spin noise spectroscopy (SNS) to directly observe build-up of dynamic nuclear polarization and relaxation of a perturbed nuclear spin-system to its equilibrium state in a single-shot experiment. The SNS experiments were performed…
Quantum amplification is recognized as a key resource for precision measurements. However, most conventional paradigms employ an ensemble of independent particles that usually limit the performance of quantum amplification in gain, spectral…
An equation of state(EOS) of nuclear matter with explicit inclusion of a spin-isospin dependent force is constructed from a finite range, momentum and density dependent effective interaction. This EOS is found to be in good agreement with…
Polarization transfers are crucial building blocks in magnetic resonance experiments, i.e., they can be used to polarize insensitive nuclei and correlate nuclear spins in multidimensional NMR spectroscopy. The polarization can be…
SABRE (Signal Amplification By Reversible Exchange) is a technique for enhancement of NMR (Nuclear Magnetic Resonance) signals, which utilizes parahydrogen (pH2, the H2 molecule in its nuclear spin state) as a source of non-thermal spin…
A sensitivity increase of two orders of magnitude in proton (1H) and carbon (13C) spins via dynamic nuclear polarization (DNP) has been accomplished recently using a compact benchtop DNP polarizer operating at 1 T and 77 K. However the DNP…
Dynamic nuclear polarisation (DNP) refers to a class of techniques used to increase the signal in nuclear magnetic resonance measurements by transferring spin polarisation from ensembles of highly polarised electrons to target nuclear…
We describe a method to hyperpolarize 3He nuclear spins at high magnetic fields (4.7 Tesla) solely by a magnetized plasma. The conditions for such a magnetized plasma are fulfilled when the mean free path of the free electrons is much…
Spin engineering of advanced pulse sequences has had a transformative impact on the development of nuclear magnetic resonance (NMR) spectroscopy, to an extending degree also electron paramagnetic resonance (EPR), and the hybrid between the…