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Solid-phase photo-processes involving icy dust grains greatly affect the chemical evolution of the interstellar medium by leading to the formation of complex organic molecules and by inducing photodesorption. So far, the focus of laboratory…

We have measured the intricate temperature dependence of the Co L2,3 x-ray absorption spectra (2p-3d excitations) of CoO. To allow for accurate total electron yield measurements, the material has been grown in thin film form on a metallic…

Strongly Correlated Electrons · Physics 2008-06-24 M. W. Haverkort , A. Tanaka , Z. Hu , H. H. Hsieh , H. -J. Lin , C. T. Chen , L. H. Tjeng

We present optical absorption spectra of mixed films of pentacene (PEN) and perfluoropentacene (PFP) grown on SiO2. We investigated the influence of intermolecular coupling between PEN and PFP on the optical spectra by analyzing samples…

Materials Science · Physics 2011-06-22 K. Broch , U. Heinemeyer , A. Hinderhofer , F. Anger , R. Scholz , A. Gerlach , F. Schreiber

With infrared spectroscopy we investigated the spin-reorientation transition from an orthorhombic antiferromagnetic (o-AF) to a tetragonal AF (t-AF) phase and the reentrance of the o-AF phase in the superconducting state of underdoped Ba$…

The spectra from Fe-peak elements may be used to determine the temperature and density of various astrophysical objects. Determination of these quantities is underpinned by the accuracy and the comprehensiveness of the underlying atomic…

Instrumentation and Methods for Astrophysics · Physics 2018-12-19 Luis Fernández-Menchero , Ryan T. Smyth , Catherine A. Ramsbottom , Connor P. Ballance

We present a comprehensive study of polar and magnetic excitations in BiFeO3 ceramics and a thin film epitaxially grown on an orthorhombic (110) TbScO3 substrate. Infrared reflectivity spectroscopy was performed at temperatures from 5 to…

Materials Science · Physics 2015-05-22 S. Skiadopoulou , V. Goian , C. Kadlec , F. Kadlec , X. F. Bai , I. C. Infante , B. Dkhil , C. Adamo , D. G. Schlom , S. Kamba

IR spectroscopy such as Fourier transform infrared spectroscopy (FTIR) are widely used for the investigation of structure and the quantitative determination of substances in the fields of chemistry, physics, biology, medicine, and…

Density functional theory (DFT) including van der Waals weak interaction in conjunction with the so called rotational invariant DFT+U, where $U$ is the Hubbard interaction of the iron site, is used to show that the fluorinated spin…

Materials Science · Physics 2023-09-06 R. Pasquier , K. Rassoul , M. Alouani

In this work we demonstrate vibrational spectroscopy of polyatomic ions that are trapped and sympathetically cooled by laser-cooled atomic ions. We use the protonated dipeptide tryptophane-alanine (HTyrAla+) as a model system, cooled by…

Chemical Physics · Physics 2017-09-13 Ch. Wellers , A. Borodin , S. Vasilyev , D. Offenberg , S. Schiller

Fourier-transform Infrared (FT-IR) Spectroscopy measurements have been performed on the three-dimensional dilute antiferromagnet Fe(x)Zn(1-x)F2 with x=0.99 ~ 0.58 in far infrared (FIR) region. The FIR spectra are analyzed taking into…

Disordered Systems and Neural Networks · Physics 2009-11-07 J. Satooka , K. Katsumata , D. P. Belanger

We report a Fe K\beta x-ray emission spectroscopy study of local magnetic moments in the rare-earth doped iron pnictide Ca_{1-x}RE_xFe_2As_2 (RE=La, Pr, and Nd). In all samples studied the size of the Fe local moment is found to decrease…

Superconductivity · Physics 2013-01-28 H. Gretarsson , S. R. Saha , T. Drye , J. Paglione , Jungho Kim , D. Casa , T. Gog , W. Wu , S. R. Julian , Young-June Kim

We identify a first-order, isosymmetric transition between a ferrielectric (FiE) and ferroelectric (FE) state in $A$-site ordered LaScO$_{3}$/BiScO$_{3}$ and LaInO$_{3}$/BiInO$_{3}$ superlattices. Such a previously unreported ferroic…

Materials Science · Physics 2013-09-11 Gaoyang Gou , James M. Rondinelli

Interfaces between heavy metals (HMs) and antiferromagnetic insulators (AFIs) have recently become highly investigated and debated systems in the effort to create spintronic devices able to function at terahertz frequencies. Such…

The rotational and hyperfine spectrum of the $X^1\Sigma^+ \rightarrow B^3\Pi_1$ transition in TlF molecules was measured using laser-induced fluorescence from both a thermal and a cryogenic molecular beam. Rotational and hyperfine constants…

In astrochemical exploration, infrared (IR) spectroscopy is vital for understanding the composition and structure of ice in various space environments. This article explores the impact of incident angles on IR spectroscopy, focusing on…

Instrumentation and Methods for Astrophysics · Physics 2025-02-25 Cristóbal González Díaz , Hector Carrascosa , Guillermo M. Muñoz Caro

We analyzed archival spectra acquired with the Hubble Space Telescope for a study of interstellar C2. Absorption from the electronic transitions, D ^1Sigma^+_u -- X ^1Sigma^+_g (0,0) as well as F ^1Pi_u -- X ^1Sigma^+_g (0,0) and (1,0), was…

Astrophysics of Galaxies · Physics 2015-06-12 Ryan C. Hupe , Y. Sheffer , S. R. Federman

Recently, Mitsuhashi et al., have observed superconductivity with transition temperature up to 18 K in potassium doped picene (C22H14), a polycyclic aromatic hydrocarbon compound [Nature 464 (2010) 76]. Theoretical analysis indicate the…

Optical absorption and transverse Kerr effect spectra, resistivity and magnetoresistance of La$_{1-x}$Sr$_{x}$CoO$_3$ ($x=0.15, 0.25, 0.35$) films have been studied. The temperature dependencies of the optical and magneto-optical properties…

Pump-probe spectroscopy is central for exploring ultrafast dynamics of fundamental excitations, collective modes and energy transfer processes. Typically carried out using conventional diffraction-limited optics, pump-probe experiments…

The spin crossover properties and the domains of existence of the different phases for the [Fe(PM-BIA)2(NCS)2] complex are obtained from combining DFT and classical molecular dynamics (MD). The potential energy surfaces expressed in the…

Materials Science · Physics 2015-06-12 A. Marbeuf , P. Négrier , S. F. Matar , L. Kabalan , J. F. Létard , P. Guionneau
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