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In this work, we use molecular dynamics simulations to study the enhancement of surface over bulk diffusion (surface enhanced diffusion) in (PbO)x(SiO2)1-x glasses. This work is motivated to better understand surface diffusion in glasses…

Explicit molecular dynamics simulations were applied to a pair of amorphous silica nanoparticles of diameter 3.2 nm immersed in a background electrolyte. Mean forces acting between the pair of silica nanoparticles were extracted at four…

Chemical Physics · Physics 2007-09-11 S. Jenkins , S. R. Kirk , M. Persson , J. Carlen , Z. Abbas

The structure of surfaces and interfaces of silica (SiO2) is investigated by large scale molecular dynamics computer simulations. In the case of a free silica surface, the results of a classical molecular dynamics simulation are compared to…

Disordered Systems and Neural Networks · Physics 2007-05-23 Juergen Horbach , Torsten Stuehn , Claus Mischler , Walter Kob , Kurt Binder

We use computer simulations to study the microscopic dynamics of an athermal assembly of soft particles near the fluid-to-solid, jamming transition. Borrowing tools developed to study dynamic heterogeneity near glass transitions, we…

Materials Science · Physics 2010-06-24 Claus Heussinger , Ludovic Berthier , Jean-Louis Barrat

We analyze the displacements of the particles of a glass-forming molecular liquid perpendicular to a confining solid surface, using extensive molecular dynamics simulations with atomistic models. In the vicinity of an attractive surface,…

Soft Condensed Matter · Physics 2024-10-15 Alireza F. Behbahani , Vagelis Harmandaris

Dynamics of spreading of small droplets on surfaces has been studied by the molecular dynamics method. Simulations have been performed for mixtures of solvent and dimer, and solvent and tetramer droplets. For solvent particles and dimers,…

Condensed Matter · Physics 2009-10-22 J. A. Nieminen , T. Ala- Nissila

Experiments have shown that self-propelled particles can slide along the surface of a circular obstacle without becoming trapped over long times. Using simulations and theory, we study the impact of boundary conditions on the diffusive…

Biological Physics · Physics 2019-01-30 Theresa Jakuszeit , Ottavio A. Croze , Samuel Bell

A molecular dynamics simulation of SPC/E water confined in a Silica pore is presented. The pore has been constructed to reproduce the average properties of a pore of Vycor glass. Due to the confinement and to the presence of a strong…

Statistical Mechanics · Physics 2007-05-23 P. Gallo , M. Rovere

In this work we study the diffusion mechanisms in lithium disilicate melt using molecular dynamics simulation, which has an edge over other simulation methods because it can track down actual atomic rearrangements in materials once a…

Materials Science · Physics 2014-05-30 Luis G. V. Gonçalves , José P. Rino

In this paper we use density-functional theory calculations to analyze both the stability and diffusion of Cu adatoms near and on the H-passivated Si(001) surface. Two different Cu sources are considered: depositing Cu from vacuum, and…

Materials Science · Physics 2024-02-08 A. Rodriguez-Prieto , D. R. Bowler

A full understanding of glasses requires an accurate atomistic picture of the complex activated processes that constitute the low-temperature dynamics of these materials. To this end, we generate over five thousand activated events in…

Condensed Matter · Physics 2009-10-31 Normand Mousseau , G. T. Barkema , Simon W. de Leeuw

We investigate the structure and dynamics of sodium disilicate by means of molecular dynamics computer simulation. We show that the structure is described by a partially destroyed tetrahedral SiO_4 network and a spherical super structure…

Statistical Mechanics · Physics 2017-02-08 Jurgen Horbach , Walter Kob

A Molecular Dynamics simulation of the microscopic structure of water confined in a silica pore is presented. A single cavity in the silica glass has been modeled as to reproduce the main features of the pores of real Vycor glass. A layer…

Soft Condensed Matter · Physics 2009-11-07 P. Gallo , M. A. Ricci , M. Rovere

Explicit molecular dynamics simulations were applied to a pair of amorphous silica nanoparticles in aqueous solution, of diameter 4.4 nm with four different background electrolyte concentrations, to extract the mean force acting between the…

Chemical Physics · Physics 2009-11-13 S. Jenkins , S. R. Kirk , M. Persson , J. Carlen , Z. Abbas

Crystallization from an amorphous atomic structure is usually seen as a spontaneous process in pursuit of a lower energy state, but for alloy systems it is often hard to elucidate because of the intrinsic structural and compositional…

Materials Science · Physics 2020-04-10 Y. Huang , L. Xie , D. S. He , J. Q. He

Diffusion across surfaces generally involves motion on a vibrating but otherwise stationary substrate. Here, using molecular dynamics, we show that a layered material such as graphene opens up a new mechanism for surface diffusion whereby…

Chemical Physics · Physics 2016-11-30 Ming Ma , Gabriele Tocci , Angelos Michaelides , Gabriel Aeppli

The present investigation examines the relationship between structural order, diffusivity anomalies, and density anomalies in liquid silica by means of molecular dynamics simulations. We use previously defined orientational and…

Soft Condensed Matter · Physics 2009-11-07 M. S. Shell , P. G. Debenedetti , A. Z. Panagiotopoulos

We present the first molecular dynamics study to probe the mechanisms of anomalous diffusion in cationic surfactant micelles in the presence of explicit salt and solvent-mediated interactions. Simulations show that when the counter ion…

Soft Condensed Matter · Physics 2017-08-02 Subas Dhakal , Radhakrishna Sureshkumar

We use ab initio simulations to study the static and dynamic properties of a sodium borosilicate liquid with composition 3Na_2O-B_2O_3-6SiO_2, i.e. a system that is the basis of many glass-forming materials. In particular we focus on the…

Disordered Systems and Neural Networks · Physics 2018-02-28 Laurent Pedesseau , Simona Ispas , Walter Kob

Indentation has been widely used for investigating the mechanical behavior of glasses. However, how the various microscopic properties (such as atomic structure and mechanics) of glass evolve from the immediate contact with the indenter to…

Disordered Systems and Neural Networks · Physics 2023-05-09 Linfeng Ding , Ranran Lu , Lianjun Wang , Qiuju Zheng , John C. Mauro , Zhen Zhang