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Related papers: Density Matrix Perturbation Theory

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Density matrix perturbation theory (DMPT) is known as a promising alternative to the Rayleigh-Schr\"odinger perturbation theory, in which the sum-over-state (SOS) is replaced by algorithms with perturbed density matrices as the input…

Chemical Physics · Physics 2020-12-02 Lionel A. Truflandier , Rivo M. Dianzinga , David R. Bowler

The perturbation theory with a variational basis is constructed and analyzed.The generalized Gaussian effective potential is introduced and evaluated up to the second order for selfinteracting scalar fields in one and two spatial…

High Energy Physics - Theory · Physics 2014-11-18 Paolo Cea , Luigi Tedesco

A recently developed linear algebraic method for the computation of perturbation expansion coefficients to large order is applied to the problem of a hydrogenic atom in a magnetic field. We take as the zeroth order approximation the $D…

chem-ph · Physics 2009-10-22 Timothy C. Germann , Dudley R. Herschbach , Bruce M. Boghosian

The perturbative approach was adopted to develop a temperature-dependent version of non-relativistic quantum mechanics in the limit of low-enough temperatures. A generalized, self-consistent Hamiltonian was therefore constructed for an…

Quantum Physics · Physics 2021-03-08 Ashkan Shekaari , Mahmoud Jafari

A new approach is presented to compute entropy for massless scalar quantum fields. By perturbing a skewed correlation matrix composed of field operator correlation functions, the mutual information is obtained for disjoint spherical regions…

High Energy Physics - Theory · Physics 2025-01-15 Joseph Bramante , Andrew Buchanan

The real-space density-functional perturbation theory (DFPT) for the computations of the response properties with respect to the atomic displacement and homogeneous electric field perturbation has been recently developed and implemented…

Computational Physics · Physics 2020-10-28 Honghui Shang , Wanzhen Liang , Yunquan Zhang , Jinlong Yang

Determining ground state energies of quantum systems by hybrid classical/quantum methods has emerged as a promising candidate application for near-term quantum computational resources. Short of large-scale fault-tolerant quantum computers,…

Quantum Physics · Physics 2016-10-25 Nicholas C. Rubin

Perturbation theory (PT) might be one of the most powerful and fruitful tools for both physicists and chemists, which evoked an explosion of applications with the blooming of atomic and subatomic physics. Even though PT is well-used today,…

Quantum Physics · Physics 2023-05-16 Junxu Li , Barbara A. Jones , Sabre Kais

We develop a perturbation theory of quantum (and classical) master equations with slowly varying parameters, applicable to systems which are externally controlled on a time scale much longer than their characteristic relaxation time. We…

Quantum Physics · Physics 2017-08-09 Vasco Cavina , Andrea Mari , Vittorio Giovannetti

We exhibit an explicit formula for the spectral density of a (large) random matrix which is a diagonal matrix whose spectral density converges, perturbated by the addition of a symmetric matrix with Gaussian entries and a given (small)…

Probability · Mathematics 2011-04-28 Florent Benaych-Georges , Nathanaël Enriquez

We analyze solutions to loop-truncated Schwinger-Dyson equations in massless N=2 and N=4 Wess-Zumino matrix quantum mechanics at finite temperature, where conventional perturbation theory breaks down due to IR divergences. We find a rather…

High Energy Physics - Theory · Physics 2013-04-09 Ying-Hsuan Lin , Shu-Heng Shao , Yifan Wang , Xi Yin

Based on the special properties of Liouville eigenoperators a perturbation theory for the partition sum is given. It is applicable for any temperature and includes the case of degenerate Hamiltonians. To demonstrate the reliability of the…

Strongly Correlated Electrons · Physics 2007-05-23 R. Schumann

We propose a convex variational approach to compute localized density matrices for both zero temperature and finite temperature cases, by adding an entry-wise $\ell_1$ regularization to the free energy of the quantum system. Based on the…

Numerical Analysis · Mathematics 2016-05-04 Rongjie Lai , Jianfeng Lu

Perturbation theory is developed to analyze the impact of noise on data and has been an essential part of numerical analysis. Recently, it has played an important role in designing and analyzing matrix algorithms. One of the most useful…

Probability · Mathematics 2023-11-21 Abhinav Bhardwaj , Van Vu

In a recent paper we have suggested that the finite temperature density matrix can be computed efficiently by a combination of polynomial expansion and iterative inversion techniques. We present here significant improvements over this…

Materials Science · Physics 2010-10-19 Michele Ceriotti , Thomas D. Kühne , Michele Parrinello

We analyze the response of a complex quantum-mechanical system (e. g., a quantum dot) to a time-dependent perturbation. Assuming the dot energy spectrum and the perturbation to be described by the Gaussian Orthogonal Ensemble of random…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 D. M. Basko , M. A. Skvortsov , V. E. Kravtsov

The properties of coherence and polarization of light has been the subject of intense investigations and form the basis of many technological applications. These concepts which historically have been treated independently can now be…

Quantum Physics · Physics 2021-01-07 Bertúlio de Lima Bernardo

We introduce a perturbative approximation to the combined density functional theory and multireference configuration interaction (DFT/MRCI) method. The method, termed DFT/MRCI(2), results from the application of quasi-degenerate…

Chemical Physics · Physics 2022-11-09 Simon P. Neville , Michael S. Schuurman

We present an ab-initio approach for grand canonical ensembles in thermal equilibrium with local or nonlocal external potentials based on the one-reduced density matrix. We show that equilibrium properties of a grand canonical ensemble are…

Other Condensed Matter · Physics 2015-08-03 Tim Baldsiefen , Attila Cangi , E. K. U. Gross

The quantum density matrix generalises the classical concept of probability distribution to quantum theory. It gives the complete description of a quantum state as well as the observable quantities that can be extracted from it. Its…

Quantum Physics · Physics 2023-08-31 Apoorva D. Patel