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We have carried out extensive equilibrium molecular dynamics (MD) simulations to study the structure and the interfacial properties in the liquid-vapor (LV) phase coexistence of partially miscible binary Lennard-Jones (LJ) mixtures. By…

Soft Condensed Matter · Physics 2009-11-10 Enrique Díaz-Herrera , José A. Moreno-Razo , Guillermo Ramírez-Santiago

By means of extensive equilibrium molecular dynamics simulations we have investigated, the behavior of the interfacial tension $\gamma$ of two immiscible symmetrical Lennard-Jones fluids. This quantity is studied as function of reduced…

Statistical Mechanics · Physics 2016-08-15 Enrique Diaz-Herrera , José Alejandre , Guillermo Ramírez-Santiago , F. Forstmann

Recently the supercooled Wahnstrom binary Lennard-Jones mixture was partially crystallized into ${\rm MgZn_2}$ phase crystals in lengthy Molecular Dynamics simulations. We present Molecular Dynamics simulations of a modified Kob-Andersen…

Soft Condensed Matter · Physics 2012-10-01 Søren Toxvaerd , Ulf R. Pedersen , Thomas B. Schrøder , Jeppe C. Dyre

Evaporation and condensation at a liquid/vapor interface are ubiquitous interphase mass and energy transfer phenomena that are still not well understood. We have carried out large scale molecular dynamics simulations of Lennard-Jones (LJ)…

Soft Condensed Matter · Physics 2012-01-12 Shengfeng Cheng , Jeremy B. Lechman , Steven J. Plimpton , Gary S. Grest

Multicanonical ensemble sampling simulations have been performed to calculate the phase diagram of a Lennard-Jones fluid embedded in a fractal random matrix generated through diffusion limited cluster aggregation. The study of the system at…

Statistical Mechanics · Physics 2015-06-25 V. De Grandis , P. Gallo , M. Rovere

It is established that liquid metals exhibit surface layering at the liquid-vapor interface, while dielectric simple systems, like those interacting through Lennard-Jones potentials, show a monotonic decay from the liquid density to that of…

Disordered Systems and Neural Networks · Physics 2009-11-11 Luis E. Gonzalez , David J. Gonzalez

Within the coexistence region between liquid and vapor the equilibrium pressure of a simulated fluid exhibits characteristic jumps and plateaus when plotted as a function of density at constant temperature. These features exclusively…

Statistical Mechanics · Physics 2015-09-09 S. Prestipino , C. Caccamo , D. Costa , G. Malescio , G. Munaò

A Lennard--Jones model of a binary dense liquid (A,B) with a symmetrical miscibility gap is investigated by means of computer simulation methods. Semigrand--canonical Monte Carlo simulations yield the phase diagram in the $T$--$x$ plane…

Statistical Mechanics · Physics 2007-05-23 Subir K. Das , Jürgen Horbach , Kurt Binder

Thermal motions in the 2D Lennard-Jones liquid near solidification are studied at equilibrium and under shear flow conditions. At the temperatures of the study, the liquid is significantly aggregated. On times of few to few tens of…

Mesoscale and Nanoscale Physics · Physics 2017-03-03 Alexander Z. Patashinski , Rafal Orlik , Mark A. Ratner

We report a Monte Carlo finite-size scaling study of the demixing transition of a symmetrical Lennard-Jones binary fluid mixture. For equal concentration of species, and for a choice of the unlike-to-like interaction ratio delta=0.7, this…

Statistical Mechanics · Physics 2009-11-10 Nigel B. Wilding

We use molecular dynamics (MD) to simulate an unstable homogeneous mixture of binary fluids (AB), confined in a slit pore of width $D$. The pore walls are assumed to be flat and structureless, and attract one component of the mixture (A)…

Disordered Systems and Neural Networks · Physics 2009-11-11 S. K. Das , S. Puri Jawaharlal , J. Horbach , Kurt Binder

We study the relaxation dynamics of a binary Lennard-Jones liquid in the presence of an amorphous wall generated from equilibrium particle configurations. In qualitative agreement with the results presented in Nature Phys. {\bf 8}, 164…

Statistical Mechanics · Physics 2014-06-16 Glen M Hocky , Ludovic Berthier , Walter Kob , David R. Reichman

The dynamic and static critical behavior of five binary Lennard-Jones liquid mixtures, close to their continuous demixing points (belonging to the so-called model H' dynamic universality class), are studied computationally by combining…

Statistical Mechanics · Physics 2018-03-09 Sutapa Roy , S. Dietrich , Felix Höfling

Linearly-sloped or `ramp' potentials belong to a class of core-softened models which possess a liquid-liquid critical point (LLCP) in addition to the usual liquid-gas critical point. Furthermore they exhibit thermodynamic anomalies in the…

Statistical Mechanics · Physics 2009-11-11 Helen M. Gibson , Nigel B. Wilding

We study the dynamics of particles in a multi-component 2d Lennard-Jones (LJ) fluid in the limiting case where {\it all the particles are different} (APD). The equilibrium properties of this APD system were studied in our earlier work…

Soft Condensed Matter · Physics 2016-06-22 Lenin S. Shagolsem , Yitzhak Rabin

We use simulation-based supervised machine learning and classical density functional theory to investigate bulk and interfacial phenomena associated with phase coexistence in binary mixtures. For a prototypical symmetrical Lennard-Jones…

Soft Condensed Matter · Physics 2025-10-23 Silas Robitschko , Florian Sammüller , Matthias Schmidt , Robert Evans

We study the excess free energy due to phase coexistence of fluids by Monte Carlo simulations using successive umbrella sampling in finite LxLxL boxes with periodic boundary conditions. Both the vapor-liquid phase coexistence of a simple…

Soft Condensed Matter · Physics 2015-05-19 B. J. Block , S. K. Das , M. Oettel , P. Virnau , K. Binder

Molecular dynamics simulations of miscible and partially miscible binary Lennard--Jones mixtures are used to study the dynamics and thermodynamics of vapor condensation onto a non-volatile liquid drop in the canonical ensemble. When the…

Soft Condensed Matter · Physics 2015-06-17 Levent Inci , Richard. K. Bowles

Results of a systematic investigation of the vapour-liquid equilibria of 38 individual two-centre Lennard-Jones plus axial pointdipole model fluids (2CLJD) are reported over a range of reduced dipolar momentum 0 $\le \mu^{*2} \le$ 20 and of…

Computational Physics · Physics 2009-04-23 Jürgen Stoll , Jadran Vrabec , Hans Hasse

The paper concerns the construction of a compressible liquid-vapor relaxation model which is able to capture the metastable states of the non isothermal van der Waals model as well as saturation states. Starting from the Gibbs formalism, we…

Analysis of PDEs · Mathematics 2019-11-01 Hala Ghazi , Francois James , Hélène Mathis
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