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The Integral Fluctuation Theorem for entropy production (IFT) is among the few equalities that are known to be valid for physical systems arbitrarily driven far from equilibrium. Microscopically, it can be understood as an inherent symmetry…

Statistical Mechanics · Physics 2023-06-21 Francesco Coghi , Lorenzo Buffoni , Stefano Gherardini

The fluctuation-dissipation theorem (FDT) is a central result in statistical physics, both for classical and quantum systems. It establishes a relationship between the linear response of a system under a time-dependent perturbation and time…

Quantum Physics · Physics 2018-05-28 Mohammad Mehboudi , Anna Sanpera , Juan M. R. Parrondo

Heat, work and entropy production: the statistical distribution of such quantities are constrained by the fluctuation theorems (FT), which reveal crucial properties about the nature of non-equilibrium dynamics. In this paper we report…

Quantum Physics · Physics 2021-10-15 K. Khan , J. Sales Araújo , W. F. Magalhães , G. H. Aguilar , B. de Lima Bernardo

Heat fluctuations over a time \tau in a non-equilibrium stationary state and in a transient state are studied for a simple system with deterministic and stochastic components: a Brownian particle dragged through a fluid by a harmonic…

Statistical Mechanics · Physics 2007-05-23 R. van Zon , E. G. D. Cohen

The fluctuation theorem characterizes the distribution of the dissipation in nonequilibrium systems and proves that the average dissipation will be positive. For a large system with no external source of fluctuation, fluctuations in…

Statistical Mechanics · Physics 2018-12-18 Guillaume Michel , Debra J. Searles

Quantum extensions of the Gallavotti-Cohen fluctuation theorem (FT) for the entropy production have been discussed by several authors. There is a practical gap between microscopic forms of FT and mesoscopic (i.e. not purely Hamiltonian)…

Statistical Mechanics · Physics 2009-11-13 Wojciech De Roeck

Fluctuation theorems have elevated the second law of thermodynamics to a statistical realm by establishing a connection between time-forward and time-reversal probabilities, providing invaluable insight into nonequilibrium dynamics. While…

Quantum Physics · Physics 2025-06-05 Hui Li , Jie Xie , Hyukjoon Kwon , Yixin Zhao , M. S. Kim , Lijian Zhang

Mesoscopic systems provide us a unique experimental stage to address non-equilibrium quantum statistical physics. By using a simple tunneling model, we describe the electron exchange process via a quantum coherent conductor between two…

We present a derivation of the integral fluctuation theorem (IFT) for isolated quantum systems based on some natural assumptions on transition probabilities. Under these assumptions of "stiffness" and "smoothness" the IFT immediately…

Statistical Mechanics · Physics 2022-08-26 Robin Heveling , Jiaozi Wang , Jochen Gemmer

Fluctuation theorems impose constraints on the probability of observing negative entropy production in small systems driven out of equilibrium. The range of validity of fluctuation theorems has been extensively tested for transitions…

Statistical Mechanics · Physics 2015-04-21 Léo Granger , Jumna Mehlis , Édgar Roldán , Sergio Ciliberto , Holger Kantz

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small nonequilibrium systems. While work and heat are equally important forms of energy exchange, fluctuation relations have not been experimentally…

Statistical Mechanics · Physics 2022-02-24 Markus Rademacher , Michael Konopik , Maxime Debiossac , David Grass , Eric Lutz , Nikolai Kiesel

The heat theorem (i.e. the second law of thermodynamics or the existence of entropy) is a manifestation of a general property of hamiltonian mechanics and of the ergodic Hypothesis. In nonequilibrium thermodynamics of stationary states the…

Statistical Mechanics · Physics 2008-11-01 Giovanni Gallavotti

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park

Recently van Zon and Cohen [1-3] proposed an extension of the Fluctuation Theorems (FTs) of Evans and Searles [4]. For dissipative nonequilibrium systems, Cohen and van Zon studied the fluctuations of the heat absorbed, over a period of…

Statistical Mechanics · Physics 2007-05-23 Denis J. Evans

The Gallavotti - Cohen Fluctuation Theorem (FT) implies an infinite set of identities between correlation functions that can be seen as a generalization of Green Kubo formula to the nonlinear regime. As an application, we discuss a…

Statistical Mechanics · Physics 2015-05-14 Marcello Porta

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

By taking full advantage of the dynamic property imposed by the detailed balance condition, we derive a new refined unified fluctuation theorem (FT) for general stochastic thermodynamic systems. This FT involves the joint probability…

Statistical Mechanics · Physics 2015-07-27 Zongping Gong , H. T. Quan

The Heat theorem reveals the second law of equilibrium Thermodynamics (i.e.existence of Entropy) as a manifestation of a general property of Hamiltonian Mechanics and of the Ergodic Hypothesis, valid for 1 as well as $10^{23}$ degrees of…

Statistical Mechanics · Physics 2008-02-01 Giovanni Gallavotti

This book provides a modern review of Fluctuation Relations and Fluctuation Theorems in nonequilibrium statistical mechanics. It focuses on the pioneering perspectives of Gallavotti and Cohen, according to which a fluctuation theorem…

Mathematical Physics · Physics 2026-02-13 Noé Cuneo , Vojkan Jakšić , Claude-Alain Pillet , Armen Shirikyan

We derive the fluctuation theorem for a stochastic and periodically driven system coupled to two reservoirs with the aid of a master equation. We write down the cumulant generating functions for both the current and entropy production in…

Statistical Mechanics · Physics 2020-11-26 Kazutaka Takahashi , Yuki Hino , Keisuke Fujii , Hisao Hayakawa