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A lattice gas model is used to study the equilibrium properties and desorption kinetics of CO on Ru(0001). With interactions obtained from density functional theory (DFT) the phase diagram and temperature programmed desorption (TPD) spectra…

Statistical Mechanics · Physics 2007-05-23 J. -S. McEwen , A. Eichler

We investigate the atomic hydrogen adsorption on Mg(0001) by using density-functional theory within the generalized gradient approximation and a supercell approach. The coverage dependence of the adsorption structures and energetics is…

Materials Science · Physics 2009-04-29 Yanfang Li , Ping Zhang , Bo Sun , Yu Yang , Yinghui Wei

The adsorption and dissociation of isolated water molecule on Zr(0001) surface are theoretically investigated for the first time by using density-functional theory calculations. Two kinds of adsorption configurations with almost the same…

Materials Science · Physics 2015-05-27 Shuang-Xi Wang , Ping Zhang , Peng Zhang , Jian Zhao , Shu-Shen Li

Extensive density-functional calculations are performed for chemisorption of atoms in the three first periods (H, B, C, N, O, F, Al, Si, P, S, and Cl) on the polar TiC(111) surface. Calculations are also performed for O on TiC(001), for…

Materials Science · Physics 2007-05-23 Carlo Ruberto , Bengt I. Lundqvist

The electronic structure and optical absorption spectrum of V^{0} and V^{-} center in MgO are investigated using first-principles calculations based on density functional theory. It is demonstrated that the configuration with distortion is…

Materials Science · Physics 2017-03-16 Jie Zhang , Xian Long Wang , Kai Shuai Yang , Ya Cheng , Chuan Guo Zhang , Zhi Zeng , Xian Ming Zhou , Hai Qing Lin

We have studied the adsorption of bisphenol-A-polycarbonate (BPA-PC) on the alpha-Al2O3(0001) surface using density-functional theory (DFT) with van der Waals (vdW) corrections. The BPA-PC polymer can be divided into its chemical fragments…

Materials Science · Physics 2012-05-30 Janne Blomqvist , Petri Salo

We use the one-dimensional object-oriented particle-in-cell Monte Carlo collision code oopd1 to explore the properties and the origins of both the electric field and electron power absorption within the plasma bulk for a capacitively…

Plasma Physics · Physics 2021-02-08 A. Proto , J. T. Gudmundsson

Stable oxygen sites on a PdO film over a Pd(100) thin structures with a (sqrt{5} times sqrt{5}) R27^circ surface-unit cell are determined using the first-principles electronic structure calculations with the generalized gradient…

Materials Science · Physics 2015-05-14 K. Kusakabe , K. Harada , Y. Ikuno , H. Nagara

The adsorption of hydrogen on the polar Zn-ended ZnO(0001) surface has been investigated by density functional {\it ab-initio} calculations. An on top H(1x1) ordered overlayer with genuine H-Zn chemical bonds is shown to be energetically…

Materials Science · Physics 2015-05-13 N. Sanchez , S. Gallego , J. Cerdá , M. C. Muñoz

We investigated the bond, electronic and magnetic behavior of adsorption Yttrium atoms on Lithium (110) surface using a combination of Bond-order-length-strength(BOLS) correlation and density-functional theory(DFT). We found that adsorption…

Materials Science · Physics 2018-12-26 Maolin Bo , Li Lei , Chuang Yao , Zhongkai Huang , Cheng Peng , Chang Q. Sun

We have investigated Rb adsorption on the Si(100) surface for 0.5 and 1 monolayer coverages using the total energy method with norm-conserving pseudopotentials. For 2$\times$1 reconstruction at 1 ML coverage symmetrized dimers are found to…

Strongly Correlated Electrons · Physics 2007-05-23 E. Mete , R. Shaltaf , Ş. Ellialtıoğlu

Using density-functional theory we investigate several properties of Al(111), Al(100), Al(110), and stepped Al(111) surfaces. We report results of formation energies of surfaces, steps, adatoms, and vacancies. For the adsorption and…

mtrl-th · Physics 2008-02-03 Roland Stumpf , Matthias Scheffler

Here, we report orbital-free density-functional theory (OF DFT) molecular dynamics simulations of the displacement cascade in aluminum. The electronic effect is our main concern. The displacement threshold energies are calculated using OF…

Materials Science · Physics 2017-09-26 Ruizhi Qiu

The structural and magnetic properties of Fe octaethylporphyrin (OEP) molecules on Cu(001) have been investigated by means of density functional theory (DFT) methods and X-ray absorption spectroscopy. The molecules have been adsorbed on the…

The structures and energetics of organic molecules adsorbed onto clean and H-passivated Si(001)-(2$\times$1) surfaces have been calculated using density functional theory. For benzene adsorbed on the clean Si surface the tight-bridge…

Materials Science · Physics 2009-11-13 Karen Johnston , Risto M. Nieminen

The adsorption and dissociation of O$_{2}$ molecules at the Be(0001) surface is studied by using density-functional theory within the generalized gradient approximation and a supercell approach. The physi- and chemisorbed molecular…

Materials Science · Physics 2013-05-29 Ping Zhang , Bo Sun , Yu Yang

The adsorption of the chiral molecule lactate on the intrinsically chiral noble metal surfaces Pt(321), Au(321) and Ag(321) is studied by Density Functional Theory calculations. We use the oPBE-vdW functional which includes van der Waals…

Materials Science · Physics 2015-06-17 J. -H. Franke , D. S. Kosov

We present the results of a density functional theory (DFT) investigation of the surfaces of rutile-like vanadium dioxide, VO2(R). We calculate the surface energies of low Miller index planes, and find that the most stable surface…

Chemical Physics · Physics 2015-06-11 Thomas A. Mellan , Ricardo Grau-Crespo

Equilibrium atomic configurations and electron energy structure of ethanol adsorbed on the Si (111) surface are studied by the first-principles density functional theory. Geometry optimization is performed by the total energy minimization…

Computational Physics · Physics 2008-02-11 A. V. Gavrilenko , C. E. Bonner , V. I. Gavrilenko

We study the adsorption and ring-opening of lactide on the naturally chiral metal surface Pt(321)$^S$. Lactide is a precursor for polylactic acid ring-opening polymerization and Pt is a well known catalyst surface. We study here the…

Materials Science · Physics 2015-06-23 Joern-Holger Franke , Daniel S. Kosov