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The ab initio $GW$ method is considered as the most accurate approach for calculating the band gaps of semiconductors and insulators. Yet its application to transition metal oxides (TMOs) has been hindered by the failure of traditional…

Materials Science · Physics 2017-02-08 Georgy Samsonidze , Cheol-Hwan Park , Boris Kozinsky

We present theoretical calculations of quasiparticle energies in closed-shell molecules using the GW method. We compare three different approaches: a full-frequency $G_0W_0$ (FF-$G_0W_0$) method with density functional theory (DFT-PBE) used…

Materials Science · Physics 2015-06-22 Johannes Lischner , Sahar Sharifzadeh , Jack Deslippe , Jeffrey B. Neaton , Steven G. Louie

We describe an all-electron $G_0W_0$ implementation for periodic systems with $k$-point sampling implemented in a crystalline Gaussian basis. Our full-frequency $G_0W_0$ method relies on efficient Gaussian density fitting integrals and…

Materials Science · Physics 2021-04-08 Tianyu Zhu , Garnet Kin-Lic Chan

The accurate ab-initio simulation of periodic solids with strong correlations is one of the grand challenges of condensed matter. While mature methods exist for weakly correlated solids, the ab-initio description of strongly correlated…

Strongly Correlated Electrons · Physics 2020-08-12 Sergei Iskakov , Chia-Nan Yeh , Emanuel Gull , Dominika Zgid

The $GW$ approximation is a widely used method for computing electron addition and removal energies of molecules and solids. The computational effort of conventional $GW$ algorithms increases as $O(N^4)$ with the system size $N$, hindering…

Chemical Physics · Physics 2024-09-12 Mia Schambeck , Dorothea Golze , Jan Wilhelm

With the aim of identifying universal trends, we compare fully self-consistent electronic spectra and total energies obtained from the GW approximation with those from an extended GWGamma scheme that includes a nontrivial vertex function…

Materials Science · Physics 2007-05-23 Arno Schindlmayr , Thomas J. Pollehn , R. W. Godby

We use a recently developed self-consistent $GW$ approximation to present systematic \emph{ab initio} calculations of the conduction band spin splitting in III-V and II-V zincblende semiconductors. The spin orbit interaction is taken into…

Other Condensed Matter · Physics 2007-11-10 A. N. Chantis , Mark van Schilfgaarde , Takao Kotani

Ab initio many-body perturbation theory within the $GW$ approximation is a Green's function formalism widely used in the calculation of quasiparticle excitation energies of solids. In what has become an increasingly standard approach,…

The electronic structure of the A-type antiferromagnetic insulator LaMnO3 is investigated by the GW approximation. The band gap and spectrum are in a good agreement with experimental observation. The on-site/off-site dynamical screened…

Strongly Correlated Electrons · Physics 2007-05-23 Y. Nohara , A. Yamasaki , S. Kobayashi , T. Fujiwara

We have undertaken a study of diluted magnetic semiconductors $Ga_{1-x}Mn_{x}N$ and $Ga_{1-x}Cr_{x}N$ with $x=0.0625, 0.125$, using the all electron linearized augmented plane wave method (LAPW) for different configurations of Mn as well as…

Materials Science · Physics 2009-11-11 Nandan Tandon , G P Das , Anjali Kshirsagar

A theory for the ab initio calculation of all-electron NMR chemical shifts in insulators using pseudopotentials is presented. It is formulated for both finite and infinitely periodic systems and is based on an extension to the Projector…

Materials Science · Physics 2016-08-31 Chris J. Pickard , Francesco Mauri

The GW approximation for the electronic self-energy is an important tool for the quantitative prediction of excited states in solids, but its mathematical exploration is hampered by the fact that it must, in general, be evaluated…

Materials Science · Physics 2013-02-27 Arno Schindlmayr

Transition-metal-based Heusler semiconductors are promising materials for a variety of applications ranging from spintronics to thermoelectricity. Employing the $GW$ approximation within the framework of the FLAPW method, we study the…

Materials Science · Physics 2016-06-01 M. Tas , E. Sasioglu , I. Galanakis , C. Friedrich , S. Blugel

For materials which are incorrectly predicted by density functional theory to be metallic, an iterative procedure must be adopted in order to perform GW calculations. In this paper we test two iterative schemes based on the quasi-particle…

Materials Science · Physics 2007-05-23 V. A. Popa , G. Brocks , P. J. Kelly

Material specific electronic band structure of the electron-doped high-Tc cuprate Nd(1.85)Ce(0.15)CuO(4) (NCCO) is calculated within the pseudo gap regime, using the recently developed generalized LDA+DMFT+Sigma_k scheme. LDA/DFT (density…

Strongly Correlated Electrons · Physics 2008-12-27 E. E. Kokorina , E. Z. Kuchinskii , I. A. Nekrasov , Z. V. Pchelkina , M. V. Sadovskii , A. Sekiyama , S. Suga , M. Tsunekawa

Self consistent GW approach (scGW) has been applied to calculate the ground state properties (equilibrium Wigner-Seitz radius $S_{WZ}$ and bulk modulus $B$) of 3d transition metals Sc, Ti, V, Fe, Co, Ni, and Cu. The approach systematically…

Strongly Correlated Electrons · Physics 2017-10-31 Andrey L. Kutepov

By recasting the non-linear frequency-dependent $GW$ quasiparticle equation into a linear eigenvalue problem, we explain the appearance of multiple solutions and unphysical discontinuities in various physical quantities computed within the…

Chemical Physics · Physics 2022-06-16 Enzo Monino , Pierre-François Loos

We present a plane wave implementation of the G0W0 approximation within the projector augmented wave method code GPAW. The computed band gaps of ten bulk semiconductors and insulators deviate on average by 0.2 eV (~ 5 %) from the…

Materials Science · Physics 2014-01-10 Falco Hüser , Thomas Olsen , Kristian S. Thygesen

Using a novel self-consistent implementation of Hedin's GW perturbation theory we calculate space and energy dependent self-energy for a number of materials. We find it to be local in real space and rapidly convergent on second-- to third--…

Strongly Correlated Electrons · Physics 2012-04-11 N. E. Zein , S. Y. Savrasov , G. Kotliar

The theory of Self-Consistent Green's Function (SCGF) is reformulated in an explicit Nambu-covariant fashion for applications to many-body systems at non-zero temperature in symmetry-broken phases. This is achieved by extending the…

Nuclear Theory · Physics 2025-07-09 M. Drissi , A. Rios , C. Barbieri
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