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The idealized mode coupling theory (MCT) is applied to colloidal systems interacting via short-range attractive interactions of Yukawa form. At low temperatures MCT predicts a slowing down of the local dynamics and ergodicity breaking…

Soft Condensed Matter · Physics 2009-10-31 J. Bergenholtz , M. Fuchs

Within the framework of the mode coupling theory (MCT) of structural relaxation, mechanisms and properties of non-ergodicity transitions in rather dilute suspensions of colloidal particles characterized by strong short-ranged attractions…

Soft Condensed Matter · Physics 2009-10-31 J. Bergenholtz , M. Fuchs , Th. Voigtmann

Mode coupling theory (MCT) appears to explain several, though not all, aspects of the glass transition in colloids (particularly when short-range attractions are present). Developments of MCT, from rational foundations in statistical…

Soft Condensed Matter · Physics 2007-05-23 M. E. Cates , C. B. Holmes , M. Fuchs , O. Henrich

We present some recent theory and simulation results addressing the phenomena of colloidal gelation at both high and low volume fractions, in the presence of short-range attractive interactions. We discuss the ability of mode-coupling…

Soft Condensed Matter · Physics 2009-11-10 M. E. Cates , M. Fuchs , K. Kroy , W. C. K. Poon , A. M. Puertas

I review recent progress in understanding the arrest and flow behaviour of colloidal glasses, based on mode coupling theory (MCT) and related approaches. MCT has had notable recent successes in predicting the re-entrant arrest behaviour of…

Soft Condensed Matter · Physics 2009-11-07 M. E. Cates

The colloidal gel and glass transitions are investigated using the idealized mode coupling theory (MCT) for model systems characterized by short-range attractive interactions. Results are presented for the adhesive hard sphere and hard core…

Soft Condensed Matter · Physics 2009-10-31 J. Bergenholtz , M. Fuchs

We present mode-coupling equations for the description of the slow dynamics observed in supercooled molecular liquids close to the glass transition. The mode-coupling theory (MCT) originally formulated to study the slow relaxation in simple…

Soft Condensed Matter · Physics 2009-10-31 L. Fabbian , A. Latz , R. Schilling , F. Sciortino , P. Tartaglia , C. Theis

Computer simulations were used to study the gel transition occurring in colloidal systems with short range attractions. A colloid-polymer mixture was modelled and the results were compared with mode coupling theory expectations and with the…

Soft Condensed Matter · Physics 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

We present simulation results addressing the dynamics of a colloidal system with attractive interactions close to gelation. Our interaction also has a soft, long range repulsive barrier which suppresses liquid-gas type phase separation at…

Soft Condensed Matter · Physics 2007-05-23 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

We extend Mode-Coupling Theory (MCT) to inhomogeneous situations, relevant for supercooled liquid in pores, close to a surface, or in an external field. We compute the response of the dynamical structure factor to a static inhomogeneous…

Statistical Mechanics · Physics 2009-11-11 Giulio Biroli , Jean-Philippe Bouchaud , Kunimasa Miyazaki , David R. Reichman

We present further evidence that gelation is an arrested phase separation in attractive colloid-polymer mixtures, based on a method combining confocal microscopy experiments with numerical simulations recently established in {\bf Nature…

Soft Condensed Matter · Physics 2009-11-13 Emanuela Zaccarelli , Peter J. Lu , Fabio Ciulla , David. A. Weitz , Francesco Sciortino

We study the dynamics of a one-component liquid constrained on a spherical substrate, a 2-sphere, and investigate how the mode-coupling theory (MCT) can describe the new features brought by the presence of curvature. To this end we have…

Soft Condensed Matter · Physics 2015-09-30 Julien-Piera Vest , Gilles Tarjus , Pascal Viot

We describe experimentally observed collective dynamics in colloidal suspensions of model hard-sphere particles using a modified mode coupling theory (MCT). This rescaled MCT is capable to describe quantitatively the wave-vector and…

Soft Condensed Matter · Physics 2024-03-08 Joel Diaz Maier , Joachim Wagner

The kinetic glass transition in short-range attractive colloids is theoretically studied by time-convolutionless mode-coupling theory (TMCT). By numerical calculations, TMCT is shown to recover all the remarkable features predicted by the…

Disordered Systems and Neural Networks · Physics 2017-03-15 Takayuki Narumi , Michio Tokuyama

For over 30 years, mode-coupling theory (MCT) has been the de facto theoretic description of dense fluids and the liquid-glass transition. MCT, however, is limited by its ad hoc construction and lacks a mechanism to institute corrections.…

Soft Condensed Matter · Physics 2015-08-12 David D. McCowan

Within the framework of the mode-coupling theory of super-cooled liquids, we investigate new phenomena in colloidal systems on approach to their glass transitions. When the inter-particle potential contains an attractive part, besides the…

Soft Condensed Matter · Physics 2009-11-07 K. A. Dawson , G. Foffi , F. Sciortino , P. Tartaglia , E. Zaccarelli

Understanding the physics of glass formation remains one of the major unsolved challenges of condensed matter science. As a material solidifies into a glass, it exhibits a spectacular slowdown of the dynamics upon cooling or compression,…

Statistical Mechanics · Physics 2018-10-03 Liesbeth M. C. Janssen

In this Rapid Communication we demonstrate the applicability of an augmented Gibbs ensemble Monte Carlo approach for the phase behavior determination of model colloidal systems with short-ranged depletion attraction and long-ranged…

Soft Condensed Matter · Physics 2007-05-23 P. Charbonneau , D. R. Reichman

Mode-coupling theory (MCT) is conjectured to be a mean-field description of dynamics of the structural glass transition and the replica theory to be its thermodynamic counterpart. However, the relationship between the two theories remains…

Soft Condensed Matter · Physics 2015-05-18 Atsushi Ikeda , Kunimasa Miyazaki

We present an approximation scheme to the master kinetic equations for aggregation and gelation with thermal breakup in colloidal systems with variable attraction energy. With the cluster fractal dimension $d_{f}$ as the only…

Soft Condensed Matter · Physics 2013-04-05 Alessio Zaccone , Jerome J. Crassous , Matthias Ballauff
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