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Biological systems use energy to maintain non-equilibrium distributions for long times, e.g. of chemical concentrations or protein conformations. What are the fundamental limits of the power used to "hold" a stochastic system in a desired…

Statistical Mechanics · Physics 2019-07-04 Dmitri S. Pavlichin , Yihui Quek , Tsachy Weissman

Measuring entropy production of a system directly from the experimental data is highly desirable since it gives a quantifiable measure of the time-irreversibility for non-equilibrium systems and can be used as a cost function to optimize…

Statistical Mechanics · Physics 2024-07-16 Prashant Singh , Karel Proesmans

The viscous drag on a colloidal particle pulled through solution by an optical trap is large enough that on experimentally relavant time scales the mechanical force exerted by the trap is equal and op- posite the viscous drag force. The…

Statistical Mechanics · Physics 2007-05-23 R. Dean Astumian

We show that the system entropy change for the transitions between non-equilibrium steady states arbitrarily far from equilibrium for any constituting process is given by the relative entropy of the distributions of these steady states.…

Statistical Mechanics · Physics 2012-05-29 G. Baris Bagci , Ugur Tirnakli , Juergen Kurths

In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This…

Mathematical Physics · Physics 2015-06-19 Elliott H. Lieb , Jakob Yngvason

The transition from a non-equilibrium state to an equilibrium state is characterized not only by the disappearance of the entropy production, but mainly by the disappearance of the organized currents, due to the gradients present in a…

Statistical Mechanics · Physics 2013-08-15 E. G. D. Cohen , R. L. Merlino

How is it that entropy derivatives almost in their own are characterizing the state of a system close to equilibrium, and what happens further away from it? We explain within the framework of Markov jump processes why fluctuation theory can…

Statistical Mechanics · Physics 2009-08-24 Christian Maes , Karel Netočný , Bram Wynants

We define the entropy operator as the negative of the logarithm of the density matrix, give a prescription for extracting its thermodynamically measurable part, and discuss its dynamics. For an isolated system we derive the first, second…

Statistical Mechanics · Physics 2016-07-06 E. Solano-Carrillo , A. J. Millis

Entropy is a very useful concept from physics that tries to explain how a system behaves from a point of view of the thermodynamics. However, there are two ways to explain entropy, and it depends on if we are studying a microsystem or a…

General Finance · Quantitative Finance 2024-07-02 Martin Pomares Calero

Micro- and nano-scale systems driven by rapid changes in control parameters (control protocols) dissipate significant energy. In the fast-protocol limit, we find that protocols that minimize dissipation at fixed duration are universally…

Statistical Mechanics · Physics 2021-08-11 Steven Blaber , Miranda D. Louwerse , David A. Sivak

A complete mathematical theory of nonequilibrium thermodynamics of stochastic systems in terms of master equations is presented. As generalizations of isothermal entropy and free energy, two functions of states play central roles: the Gibbs…

Statistical Mechanics · Physics 2010-05-28 Hao Ge , Hong Qian

Extremal principles are fundamental in our interpretation of phenomena in nature. One of the best known examples is the second law of thermodynamics, governing most physical and chemical systems and stating the continuous increase of…

Statistical Mechanics · Physics 2007-05-23 Dirk Helbing , Tamas Vicsek

In this contribution we prove that the entropy of an N-body isolated system can not decrease and the entropy production should be non-negative provided the system possesses an equilibrium state. We define the entropy as a functional of the…

Statistical Mechanics · Physics 2007-05-23 A. Perez-Madrid

In a wide class of physical systems, diffeomorphisms in the state space leave the amount of entropy produced per unit time inside the bulk of the system unaffected [M. Polettini et al., 12th Joint European Thermodynamics Conference,…

Plasma Physics · Physics 2017-01-20 Andrea Di Vita

This paper investigates the relations between three different properties, which are of importance in optimal control problems: dissipativity of the underlying dynamics with respect to a specific supply rate, optimal operation at steady…

Systems and Control · Computer Science 2017-07-18 Timm Faulwasser , Milan Korda , Colin N. Jones , Dominique Bonvin

Different notions of entropy play a fundamental role in the classical theory of dynamical systems. Unlike many other concepts used to analyze autonomous dynamics, both measure-theoretic and topological entropy can be extended quite…

Dynamical Systems · Mathematics 2017-08-03 Christoph Kawan

In this paper we prove a version of the maximum principle, in the sense of Pontryagin, for the optimal control of a finite dimensional stochastic differential equation, driven by a multidimensional Wiener process. We drop the usual…

Optimization and Control · Mathematics 2017-03-14 Carlo Orrieri

It is a great challenge of nonequilibrium statistical mechanics to calculate entropy production within a microscopic theory. In the framework of linear irreversible thermodynamics, we combine the Mori-Zwanzig-Forster projection operator…

Statistical Mechanics · Physics 2014-01-28 Raphael Wittkowski , Hartmut Löwen , Helmut R. Brand

Chater and MacKay [CM] derived an entropy function of state for exchange economies satisfying a list of axioms, and showed that a change of state of a system of such economies is possible if and only if their total entropy does not…

Mathematical Physics · Physics 2025-10-03 Robert S MacKay

We give a proof of transient fluctuation relations for the entropy production (dissipation function) in nonequilibrium systems, which is valid for most time reversible dynamics. We then consider the conditions under which a transient…

Statistical Mechanics · Physics 2009-11-13 Debra J. Searles , Lamberto Rondoni , Denis J. Evans