Related papers: Electric Field Effects Near Critical Points
The effect of the external field on the weakly-discontinuous first-order phase transition is analyzed in the frame of the Landau theory. The transformation of the free energy expansion as a power series in the order parameter is suggested…
We report the observation of sum-frequency signals that depend linearly on an applied electrostatic field and that change sign with the handedness of an optically active solution. This recently predicted chiral electro-optic effect exists…
Magnetic field usually leads to a polarization of electron spins. It is shown that in a system of {\em strongly interacting} particles applying magnetic field may lead to an opposite effect -- depolarization of electron spins. Results of…
In a recent paper [S.El Boustani, P.R.Buenzli, and Ph.A.Martin, Phys.Rev. E 73, 036113 (2006) cond-mat/0511537], about quantum charges in equilibrium with radiation, among other things the asymptotic form of the electric-field correlation…
We review recent theoretical advances on controlling the fluid-fluid phase transition with electric fields. Using a mean-field approach, we compare the effects of uniform versus non-uniform electric fields, and show how non-uniform fields…
A Landau-Ginzburg functional of two order parameters (charge-density $\phi$ and mass-density deviation $\eta$) is developed in order to yield a field theory relevant to ionic lattice gases as well as a family of off-lattice models of ionic…
We consider the influence of electric field gradients on the phase behavior of nonpolar binary mixtures. Small fields give rise to smooth composition profiles, whereas large enough fields lead to a phase-separation transition. The critical…
Can we avoid molecular dynamics simulations to estimate the electrostatic interaction between charged objects separated by a nanometric distance in water? To answer this question, we develop a continuous model for the dielectric properties…
Several experiments have reported that ferroelectric nanoparticles have drastic effects on nematic liquid crystals--increasing the isotropic-nematic transition temperature by about 5 K, and greatly increasing the sensitivity to applied…
Expressions are obtained for force and couple densities and stress tensors in macroscopic models for nematic liquid crystals subjected to electric fields. The coupling between the liquid crystal orientational properties and the electric…
We discuss the effect of an external electric field on the wetting of a solid surface by liquid. To this end, we use a model of the two-level-atom fluid for which the changes in interatomic interactions due to the presence of the field can…
Statistical theory of the dielectric susceptibility of polar liquid crystals is proposed. The molecules are calamitic or bent-core but the permanent dipole moment is perpendicular to the molecule long axis. The ordering of the phase is…
A boundary condition for the Ginzburg-Landau wave function at surfaces biased by a strong electric field is derived within the de Gennes approach. This condition provides a simple theory of the field effect on the critical temperature of…
The driving of vibrational motion by external electric fields is a topic of continued interest, due to the possibility of assessing new or metastable material phases with desirable properties. Here, we combine ab initio molecular dynamics…
We study the thermodynamic behavior of nonpolar liquid mixtures in the vicinity of curved charged objects, such as electrodes or charged colloids. For small enough charge on the object, or equivalently, small potential, the…
When immiscible liquids are subject to electric fields interfacial forces arise due to a difference in the permittivity or the conductance of the liquids, and these forces lead to shape change in droplets or to interfacial instabilities. In…
We formulate the statistical mechanical description of liquid systems for both polarizable and polar systems in an electric field in the $\mathbf{E}$-ensemble, which is the pendant to the thermodynamic description in terms of the free…
We look at the influence of external fields on systems described by generic free energy functional of the order parameter. The external force may have arbitrary spatial dependence, and the order parameter coupling may be nonlinear. The…
Ionic liquids are solvent-free electrolytes, some of which possess an intriguing self-assembly property. Using a mean-field framework (based on Onsager's relations) we show that bulk nano-structures arise via type-I and II phase transitions…
We show that development of polar order may spontaneously destroy the lamellar structure of a liquid crystal. This results in an unusual sequence of phases with the ferroelectric nematic phase appearing below a non-polar smectic phase. The…