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The structure of flexible polymers endgrafted in cylindrical pores of diameter D is studied as a function of chain length N and grafting density \sigma, assuming good solvent conditions. A phenomenological scaling theory, describing the…

Soft Condensed Matter · Physics 2009-11-11 D. I. Dimitrov , A. Milchev , K. Binder

A simple application of classical density functional theory is derived and applied to a system of polymers grafted to a plane. The system is assumed to have symmetry in directions parallel to the grafting plane hence it being a…

Soft Condensed Matter · Physics 2016-12-02 Luke Kristopher Davis

Non equilibrium coarse grained, dissipative particle dynamics simulations of complex fluids, made up of polymer brushes tethered to planar surfaces immersed in a solvent yield non monotonic behavior of the friction coefficient as a function…

Soft Condensed Matter · Physics 2017-02-01 E. Mayoral , J. Klapp , A. Gama Goicochea

Recently, Castellano and Pastor-Satorras [1] utilized the finite size scaling (FSS) theory to analyze simulation data for the contact process (CP) on scale-free networks (SFNs) and claimed that its absorbing critical behavior is not…

Statistical Mechanics · Physics 2015-06-25 Meesoon Ha , Hyunsuk Hong , Hyunggyu Park

A brief review of modeling and simulation methods for a study of polymers at interfaces is provided. When studying truly multiscale problems as provided by realistic polymer systems, coarse graining is practically unavoidable. In this…

Soft Condensed Matter · Physics 2009-10-19 Fathollah Varnik , Kurt Binder

We consider edge effects in grafted polymer layers under compression. For a semi-infinite brush, the penetration depth of edge effects $\xi\propto h_0(h_0/h)^{1/2}$ is larger than the natural height $h_0$ and the actual height $h$. For a…

Soft Condensed Matter · Physics 2017-09-13 T. A. Vilgis , A. Johner , J. F. Joanny

We study the interface representation of the contact process (CP) at its directed-percolation critical point, where the scaling properties of the interface can be related to those of the original particle model. Interestingly, such a…

Statistical Mechanics · Physics 2024-09-30 B. G. Barreales , J. J. Meléndez , R. Cuerno , J. J. Ruiz-Lorenzo

The behavior of a strongly charged polymer adsorbed on an oppositely charged surface of low-dielectric constant is formulated by the functional integral method. By separating the translational, conformational, and fluctuational degrees of…

Soft Condensed Matter · Physics 2007-05-23 Chi-Ho Cheng , Pik-Yin Lai

The process of adsorption on a planar repulsive, "marginal" and attractive wall of long-flexible polymer chains with excluded volume interactions is investigated. The performed scaling analysis is based on formal analogy between the polymer…

Soft Condensed Matter · Physics 2009-10-08 Z. Usatenko

Variational (Rayleigh-Ritz) methods are applied to local quantum field theory. For scalar theories the wave functional is parametrized in the form of a superposition of Gaussians and the expectation value of the Hamiltonian is expressed in…

High Energy Physics - Theory · Physics 2016-08-25 George Tiktopoulos

Bottle brushes are polymeric macromolecules made of a linear polymeric backbone grafted with side chains. The choice of the grafting density {\sigma}g, the length ns the grafted side chains and their chemical nature fully determines the…

Soft Condensed Matter · Physics 2019-08-09 P. Corsi , E. Roma , T. Gasperi , F. Bruni , B. Capone

Within mean-field theory we determine the universal scaling function for the effective force acting on a single colloid located near the interface between two coexisting liquid phases of a binary liquid mixture close to its critical…

Soft Condensed Matter · Physics 2015-06-22 Adam D. Law , Ludger Harnau , Matthias Troendle , Siegfried Dietrich

Wave packet propagation in the basis of interpolating scaling functions (ISF) is studied. The ISF are well known in the multiresolution analysis based on spline biorthogonal wavelets. The ISF form a cardinal basis set corresponding to an…

Atomic Physics · Physics 2015-06-26 Andrei G. Borisov , Sergei V. Shabanov

Because physical phenomena on Earth's surface occur on many different length scales, it makes sense when seeking an efficient approximation to start with a crude global approximation, and then make a sequence of corrections on finer and…

Numerical Analysis · Mathematics 2014-06-06 Quoc Thong Le Gia , Ian H Sloan , Holger Wendland

We consider a semiflexible polymer in $\mathbb Z^d$ which is a random interface model with a mixed gradient and Laplacian interaction. The strength of the two operators is governed by two parameters called lateral tension and bending…

Probability · Mathematics 2020-06-24 Alessandra Cipriani , Biltu Dan , Rajat Subhra Hazra

We develop a scaling theory of the unjamming transition of soft frictionless disks in two dimensions by defining local areas, which can be uniquely assigned to each contact. These serve to define local order parameters, whose distribution…

Disordered Systems and Neural Networks · Physics 2017-03-29 Kabir Ramola , Bulbul Chakraborty

We develop a variational method for interacting surface systems with higher-form global symmetries. As a natural extension of the conventional second-quantized Hamiltonian of interacting bosons, we explicitly construct a second-quantized…

Statistical Mechanics · Physics 2026-02-10 Kiyoharu Kawana

We studied polyelectrolyte adsorption on a repulsive charged surface by scaling analysis. At low ionic strength and low surface charge density in which a single polyelectrolyte is able to be adsorbed onto the surface, different regimes in…

Soft Condensed Matter · Physics 2016-08-31 Chi-Ho Cheng , Pik-Yin Lai

A Brownian dynamics algorithm is used to describe the static behaviour of associative polymer solutions. Predictions for the fractions of stickers bound by intra-chain and inter-chain association, as a function of system parameters, such as…

Soft Condensed Matter · Physics 2021-07-16 Aritra Santra , B. Dünweg , J. Ravi Prakash

Via computer simulations, we demonstrate how a densely grafted layer of polymers, a {\it brush}, could be turned into an efficient switch through chemical modification of some of its end-monomers. In this way, a surface coating with…

Soft Condensed Matter · Physics 2009-11-13 Holger Merlitz , Gui-Li He , Chen-Xu Wu , Jens-Uwe Sommer
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