Related papers: Potential energy landscape-based extended van der …
Depth, number, and shape of the basins of the potential energy landscape are the key ingredients of the inherent structure thermodynamic formalism introduced by Stillinger and Weber [F. H. Stillinger and T. A. Weber, Phys. Rev. A 25, 978…
Using the inherent structure formalism originally proposed by Stillinger and Weber [Phys. Rev. A 25, 978 (1982)], we generalize the thermodynamics of an energy landscape that has an ideal glass transition and derive the consequences for its…
A recently suggested equation of state with the induced surface tension is generalized to the case of quantum gases with mean-field interaction. The self-consistency conditions of such a model and the necessary one to obey the Third Law of…
Features and parameters of \boiling" liquid layer, which arises under conditions of isentropic expansion of warm dense matter (WDM), are stud- ied with the use of simplest van der Waals equation of state (EOS). Advan- tage of this EOS is…
Molecular dynamics simulations are used to generate an ensemble of saddles of the potential energy of a Lennard-Jones liquid. Classifying all extrema by their potential energy u and number of unstable directions k, a well defined relation…
There is a long-standing question of whether it is possible to extend the formalism of equilibrium thermodynamics to the case of non-equilibrium systems in steady states. We have made such an extension for an ideal gas in a heat flow…
Inspired by the recent developments in the study of the thermodynamics of van der Waals fluids via the theory of nonlinear conservation laws and the description of phase transitions in terms of classical (dissipative) shock waves, we…
The van der Waals (VDW) equation of state is a simple and popular model to describe the pressure function in equilibrium systems of particles with both repulsive and attractive interactions. This equation predicts an existence of a…
The van der Waals (vdW) theory of fluids is the first and simplest theory that takes into account interactions between the particles of a system that result in a phase transition versus temperature. Combined with Maxwell's construction,…
In this paper, we modify the VDW equation of state by adding a temperature factor to it. As a result, we give out a good phase diagram and the correlation of the reduced pressure and the reduced temperature when a balanced liquid-gas…
Numerical simulations of systems at coexistence are known to yield unstable fields in some regions of the density parameters, as well as inequivalence of ensembles. The Van der Waals-like loops are attributed to effects of the interface…
Within the frame of macroscopic quantum electrodynamics in causal media, the van der Waals interaction between an atomic system and an arbitrary arrangement of dispersing and absorbing dielectric bodies including metals is studied. It is…
The repulsive term of Van der Waals equation of state has been deduced and improved in this work using a probabilistic description of the configurational entropy. The aim is to find out whether its physical basis is suitable for the study…
This contribution briefly reviews some recent work demonstrating the partial breakdown of the colloidal fluid <--> atomic fluid analogy. The success of liquid state theory for atomic fluids stems in part from the van der Waals picture,…
In principle, density functional theory yields the correct ground-state densities and energies of electronic systems under the action of a static external potential. However, traditional approximations fail to include Van der Waals energies…
By means of molecular dynamics simulations, we study the stationary points of the potential energy in a Lennard-Jones liquid, giving a purely geometric characterization of the energy landscape of the system. We find a linear relation…
We carefully investigate the two fundamental assumptions in the Stillinger-Weber analysis of the inherent structures (IS's) in the energy landscape and come to conclude that they cannot be validated. This explains some of the conflicting…
Pecularities of isentropic expansion of warm dense matter (WDM) created by intense energy fluxes are under discussion in situation when thermodynamic trajectory of such expansion crosses binodal of liquid-gas phase transition and expansion…
We analyze the properties of a Lennard-Jones system at the level of the potential energy landscape. After an exhaustive investigation of the topological features of the landscape of the systems, obtained studying small size sample, we…
The current attempt is aimed to honor the first centennial of Johannes Diderik van der Waals (VDW) awarding Nobel Prize in Physics. The VDW theory of ordinary fluids is reviewed in the first part of the paper, where special effort is…