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The structure and the dielectric properties of Pb(Zn1/3Nb2/3)O3 (PZN) crystal have been investigated by means of high-resolution synchrotron x-ray diffraction (with an x-ray energy of 32 keV) and dielectric spectroscopy (in the frequency…

Materials Science · Physics 2009-11-10 Y. -H. Bing , A. A. Bokov , Z. -G. Ye , B. Noheda , G. Shirane

We have studied the neutron diffuse scattering in the relaxor PMN. The diffuse scattering appears around the Burns temperature (~620K), indicating its origin from the polar nanoregions (PNR). While the relative diffuse intensities are…

Materials Science · Physics 2009-11-07 K. Hirota , Z. -G. Ye , S. Wakimoto , P. M. Gehring , G. Shirane

Cold neutron scattering experiments have been performed to explore the energy, temperature, and wave-vector dependence of the diffuse scattering and the transverse acoustic (TA) phonons in the relaxor PbMg(1/3)Nb(2/3)O3. We have observed a…

Materials Science · Physics 2009-11-10 H. Hiraka , S. -H. Lee , P. M. Gehring , Guangyong Xu , G. Shirane

We analyze scattering of the transverse optic modes by spherically symmetric Polarized Nano Regions (PNR) in the paraelectric phase of relaxor ferroelectrics. Calculations have done in the frame of mean-field model early supposed by E.Iolin…

Materials Science · Physics 2015-03-17 Eugene Iolin

We have characterized the dynamics of the polar nanoregions in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ (PMN) through high-resolution neutron backscattering and spin-echo measurements of the diffuse scattering cross section. We find that the diffuse…

Materials Science · Physics 2015-05-18 C. Stock , L. Van Eijck , P. Fouquet , M. Maccarini , P. M. Gehring , Guangyong Xu , H. Luo , X. Zhao , J. -F. Li , D. Viehland

Neutron scattering techniques have been used to study the relaxor ferroelectric 0.68PbMg1/3Nb2/3O3-0.32PbTiO3 denoted in this paper as 0.68PMN-0.32PT. On cooling, these relaxor ferroelectrics have a long-range ordered ferroelectric phase…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , B. Roessli , R. A. Cowley , S. Kojima , S. G. Lushnikov

High energy x-ray diffraction measurements on Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$ (PZN) single crystals show that the system does not have a rhombohedral symmetry at room temperature as previously believed. The new phase (X) in the bulk of the…

Strongly Correlated Electrons · Physics 2009-11-07 Guangyong Xu , Z. Zhong , Y. Bing , Z. -G. Ye , C. Stock , G. Shirane

Neutron scattering investigations were carried out in PbMg$_{1/3}$Ta$_{2/3}$O$_3$ and BaMg$_{1/3}$Ta$_{2/3}$O$_3$ complex perovskites. The crystal structure of both compounds does not show any phase transition in the temperature range 1.5…

Materials Science · Physics 2007-05-23 S. N. Gvasaliya , B. Roessli , D. Sheptyakov , S. G. Lushnikov , T. A. Shaplygina

We have used neutron scattering techniques to characterize the diffuse scattering and lattice dynamics in single crystals of the relaxor PMN from 10K to 900K. We observed two distinct types of diffuse scattering. The first is weak,…

Materials Science · Physics 2009-06-11 P. M. Gehring , H. Hiraka , C. Stock , S. -H. Lee , W. Chen , Z. -G. Ye , S. B. Vakhrushev , Z. Chowdhuri

Recently, a new orthorhombic phase has been discovered in the ferroelectric system Pb(Zn1/3Nb2/3)O3-xPbTiO3 (PZN-xPT) for x= 9%, and for x= 8% after the application of an electric field. In the present work, synchrotron x-ray measurements…

Materials Science · Physics 2009-11-07 D. La-Orauttapong , B. Noheda , Z. -G. Ye , P. M. Gehring , J. Toulouse , D. E. Cox , G. Shirane

We report neutron inelastic scattering experiments on single crystal PbMg$_{1/3}$Nb$_{2/3}$O$_{3}$ doped with 32\% PbTiO$_{3}$, a relaxor ferroelectric that lies close to the morphotropic phase boundary. When cooled under an electric field…

Materials Science · Physics 2016-01-06 John A. Schneeloch , Zhijun Xu , B. Winn , C. Stock , P. M. Gehring , R. J. Birgeneau , Guangyong Xu

High energy (67 keV) x-ray diffuse scattering measurements were performed on single crystals of Pb(Zn$_{1/3}$Nb$_{2/3}$)O$_3$-$x$PbTiO$_3$ (PZN-$x$PT). A novel technique was developed to map out the diffuse scattering distribution in all…

Materials Science · Physics 2007-05-23 Guangyong Xu , Z. Zhong , H. Hiraka , G. Shirane

High-energy x-ray diffraction experiments peformed on rhombohedral (1-x)Pb(Zn1/3Nb2/3)O3-xPbTiO3(PZN-xPT) crystals with x= 4.5 and 8% show that an electric field applied along the [001] direction induces the tetragonal phase, as proposed by…

Materials Science · Physics 2009-11-07 B. Noheda , Z. Zhong , D. E. Cox , G. Shirane , S-E. Park , P. Rehring

Ferroelectric phase transition in the semiconductor Sn2P2S6 single crystal has been studied by means of neutron scattering in the pressure-temperature range adjacent to the anticipated tricritical Lifshitz point (p=0.18GPa, T=296K). The…

We report a neutron scattering study of a ferroelectric phase transition in Sr$_{0.61}$Ba$_{0.39}$Nb$_2$O$_6$ (SBN-61). The ferroelectric polarization is along the crystallographic $c$-axis but the transverse acoustic branch propagating…

Materials Science · Physics 2014-02-10 S. N. Gvasaliya , R. A. Cowley , L. I. Ivleva , S. G. Lushnikov , B. Roessli , A. Zheludev

Relaxor behavior and lattice dynamics have been studied for a single crystal of K$_{1-x}$Li$_x$TaO$_3$ $(x=0.05)$, where a small amount of a Ca impurity ($\sim 15$~ppm) was incorporated. The dielectric measurements revealed Debye-like…

Materials Science · Physics 2009-11-11 S. Wakimoto , G. A. Samara , R. K. Grubbs , E. L. Venturini , L. A. Boatner , G. Xu , G. Shirane , S. -H. Lee

Spatially resolved neutron diffraction as a function of crystal depth in Pb(Mg$_{1/3}$Nb$_{2/3}$)O$_{3}$ reveals the presence of a distinct near-surface region. A dramatic change in both the lattice constant and the Bragg peak intensity as…

Materials Science · Physics 2009-11-10 K. Conlon , H. Luo , D. Viehland , J. F. Li , T. Whan , J. H. Fox , C. Stock , G. Shirane

We report neutron inelastic scattering measurements of the lowest-energy transverse optic (TO) phonon branch in the relaxor Pb(Mg_1/3Nb_2/3)O_3 from 400 to 1100 K. Far above the Burns temperature T_d ~ 620 K we observe well-defined…

Materials Science · Physics 2009-11-07 P. M. Gehring , S. Wakimoto , Z. -G. Ye , G. Shirane

We review results obtained from recent neutron scattering studies of the lead-oxide class of perovskite relaxors PMN and PZN. A ferroelectric soft mode has been identified in PMN at 1100 K that becomes overdamped near 620 K. This is the…

Materials Science · Physics 2009-11-07 P. M. Gehring , S. Wakimoto , Z. -G. Ye , G. Shirane

Neutron inelastic scattering measurements of the polar TO phonon mode dispersion in the cubic relaxor Pb(Zn_1/3Nb_2/3)_0.92Ti_0.08O_3 at 500K reveal anomalous behavior in which the optic branch appears to drop precipitously into the…

Materials Science · Physics 2009-10-31 P. M. Gehring , S. E. Park , G. Shirane