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Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the $N-$body phase space with the given total energy. Due to Boltzmann's principle,…

Statistical Mechanics · Physics 2009-04-28 D. H. E. Gross

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble. Classically this is the manifold of all points in the N-body phase space with the given total energy. Due to Boltzmann-Planck's principle,…

Statistical Mechanics · Physics 2009-11-10 D. H. E. Gross

Boltzmann's principle S(E,N,V)=k*ln W(E,N,V) relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…

Statistical Mechanics · Physics 2015-06-24 D. H. E. Gross

The most complicated phenomena of equilibrium statistics, phase separations and transitions of various order and critical phenomena, can clearly and sharply be seen even for small systems in the topology of the curvature of the…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Traditionally, phase transitions are defined in the thermodynamic limit only. We propose a new formulation of equilibrium thermo-dynamics that is based entirely on mechanics and reflects just the {\em geometry and topology} of the N-body…

Statistical Mechanics · Physics 2009-10-31 D. H. E. Gross

Boltzmann's principle S(E,N,V...)=ln W(E,N,V...) allows the interpretation of Statistical Mechanics of a closed system as Pseudo-Riemannian geometry in the space of the conserved parameters E,N,V... (the conserved mechanical parameters in…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Non-extensive systems do not allow to go to the thermodynamic limit. Therefore we have to reformulate statistical mechanics without invoking the thermodynamical limit. I.e. we have to go back to Pre-Gibbsian times. We show that Boltzmann's…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Boltzmann's principle S(E,N,V)=k\ln W relates the entropy to the geometric area e^{S(E,N,V)} of the manifold of constant energy in the N-body phase space. From the principle all thermodynamics and especially all phenomena of phase…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Equilibrium statistics of finite Hamiltonian systems is fundamentally described by the microcanonical ensemble (ME). Canonical, or grand-canonical partition functions are deduced from this by Laplace transform. Only in the thermodynamic…

Nuclear Theory · Physics 2008-11-26 D. H. E. Gross

We develop a generalized theory of (meta)equilibrium statistical mechanics in the thermodynamic limit valid for both smooth and fractal phase spaces. In the former case, our approach leads naturally to Boltzmann-Gibbs standard…

Statistical Mechanics · Physics 2009-11-11 V. Garcia-Morales , J. Pellicer

Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. (Only in this case this is equivalent to the fundamental microcanonical ensemble.) However, some 170 years ago the original motivation of…

Astrophysics · Physics 2009-11-13 D. H. E. Gross

Depending on the exact experimental conditions, the thermodynamic properties of physical systems can be related to one or more thermostatistical ensembles. Here, we survey the notion of thermodynamic temperature in different statistical…

Statistical Mechanics · Physics 2016-05-05 Peter Hänggi , Stefan Hilbert , Jörn Dunkel

The critique against using Boltzmann's microcanonical entropy, an "ensemble measure", as foundation of statistics is rebuffed. The confusion of the microcanonical distribution with the exponential Boltzmann-Gibbs (``BG'') distribution is…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 150 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…

Statistical Mechanics · Physics 2009-11-10 D. H. E. Gross

Introduced by Boltzmann under the name "monode," the microcanonical ensemble serves as the fundamental representation of equilibrium thermodynamics in statistical mechanics by counting all possible realizations of a system's states.…

Statistical Mechanics · Physics 2026-01-27 Roman Belousov , Jenna Elliott , Florian Berger , Lamberto Rondoni , Anna Erzberger

Equilibrium statistics of Hamiltonian systems is correctly described by the microcanonical ensemble, whereas canonical ones fail in the most interesting, mostly inhomogeneous, situations like phase separations or away from the thermodynamic…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

The mean-field thermodynamic limit is studied for a class of isolated Newtonian N-body systems whose Hamiltonian admits several invariants of motion. It is shown that the macrostates of individual members of a statistical equilibrium…

Mathematical Physics · Physics 2009-11-13 Michael K. -H. Kiessling

Thermodynamics makes definite predictions about the thermal behavior of macroscopic systems in and out of equilibrium. Statistical mechanics aims to derive this behavior from the dynamics and statistics of the atoms and molecules making up…

Statistical Mechanics · Physics 2018-03-28 Sheldon Goldstein , David A. Huse , Joel L. Lebowitz , Pablo Sartori

Phase transitions in nuclei, small atomic clusters and self-gravitating systems demand the extension of thermo-statistics to ``Small'' systems. The main obstacle is the thermodynamic limit. It is shown how the original definition of the…

Statistical Mechanics · Physics 2017-08-23 D. H. E. Gross
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