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The results of ac and dc magnetization and heat capacity measurements on the oxides, Ca$_3$Co$_{1+x}$Mn$_{1-x}$O$_6$, forming in a K$_4$CdCl$_6$-derived rhombohedral quasi-one-dimensional crystal structure, are reported. As far as…

Strongly Correlated Electrons · Physics 2009-11-10 S. Rayaprol , Kausik Sengupta , E. V. Sampathkumaran

A quasi one-dimensional compound, Ca3CuRuO6, has been synthesized by solid-state reaction method and studied using magnetization (M) and heat capacity (C) measurements. This compound undergoes magnetic ordering (T_o) around 40 K, as…

Strongly Correlated Electrons · Physics 2016-08-31 S. Rayaprol , E. V. Sampathkumaran

Heat-capacity behavior in the presence of externally applied magnetic field (H) up to 140 kOe is investigated (2-35 K) for the quasi-1-dimensional compound, Ca3Co2O6, believed to order magnetically with the so-called partially disordered…

Strongly Correlated Electrons · Physics 2009-11-10 E. V. Sampathkumaran , Z. Hiroi , S. Rayaprol , Y. Uwatoko

We present a detailed powder and single crystal neutron diffraction study of the spin chain compound Ca3Co2O6. Below 25 K, the system orders magnetically with a modulated partially disordered antiferromagnetic structure. We give a…

Strongly Correlated Electrons · Physics 2008-09-17 S. Agrestini , L. C. Chapon , A. Daoud-Aladine , J. Schefer , A. Gukasov , C. Mazzoli , M. R. Lees , O. A. Petrenko

The spin-chain compounds, Ca3CuIrO6 and Ca3CuRhO6, crystallizing in a K4CdCl6-derived monoclinic structure, are investigated by ac and dc magnetization, isothermal remnant magnetization as well as heat capacity measurements. The results…

Strongly Correlated Electrons · Physics 2009-11-10 S. Rayaprol , E. V. Sampathkumaran

We report the results of ac and dc magnetization (M) and heat-capacity (C) measurements on the solid solution, Sr$_3$Cu$_{1-x}$Zn$_x$IrO$_6$. While the Zn end member is known to form in a rhombohedral pseudo one-dimensional K$_4$CdCl$_6$…

Strongly Correlated Electrons · Physics 2009-11-07 Asad Niazi , E. V. Sampathkumaran , P. L. Paulose , D. Eckert , A. Handstein , K. -H. Müller

To study the relationship between the properties of low-dimensional spin systems with weakly coupled Cu-triangles and their crystal structure, single crystals of $Cs_3Cu_3Cl_8OH$ (1) and the new $Cs_3Cu_3Cl_{7.6}Br_{0.4}OH$ (2) were grown.…

The chain-like system Ba_{3}Cu_{3}Sc_4O_{12} has potentially interesting magnetic properties due to the presence of Cu^{2+} and a structure-suggested low-dimensionality. We present magnetization M versus magnetic field H and temperature T,…

Strongly Correlated Electrons · Physics 2012-11-16 B. Koteswararao , A. V. Mahajan , F. Bert , P. Mendels , J. Chakraborty , V. Singh , I. Dasgupta , S. Rayaprol , V. Siruguri , A. Hoser , S. D. Kaushik

Using powder neutron diffraction we have discovered an unusual magnetic order-order transition in the Ising spin chain compound Ca3Co2O6. On lowering the temperature an antiferromagnetic phase with propagation vector k=(0.5,-0.5,1) emerges…

Strongly Correlated Electrons · Physics 2011-05-17 S. Agrestini , C. L. Fleck , L. C. Chapon , C. Mazzoli , A. Bombardi , M. R. Lees , O. A. Petrenko

Heat-capacity (C) and ac susceptibility measurements have been performed on the spin-chain compounds, Sr3ZnRhO6 and Ca3NiMnO6, to establish their magnetic behavior and to explore whether there are magnetic frustration effects due to…

Strongly Correlated Electrons · Physics 2009-11-10 S. Rayaprol , Kausik Sengupta , E. V. Sampathkumaran , Y. Matsushita

We have investigated the structural and magnetic transitions in CsCoO$_2$ using calorimetric measurements, neutron powder diffraction (NPD), density functional theory (DFT) calculations and muon-spin relaxation ($\mu$SR) measurements.…

Strongly Correlated Electrons · Physics 2015-06-23 N. Z. Ali , R. C. Williams , F. Xiao , S. J. Clark , T. Lancaster , S. J. Blundell , D. V. Sheptyakov , M. Jansen

We have performed a resonant x-ray scattering study at the Co pre-K edge on a single crystal of Ca3Co2O6. The measurements reveal an abrupt transition to a magnetically ordered state immediately below T_N = 25 K, with a magnetic correlation…

Other Condensed Matter · Physics 2008-05-10 S. Agrestini , C. Mazzoli , A. Bombardi , M. R. Lees

The temperature dependent ac and dc magnetization and heat capacity data of Ca$_3$CoIrO$_6$, a spin-chain compound crystallizing in a K$_4$CdCl$_6$-derived rhombohedral structure, show the features due to magnetic ordering of a…

Strongly Correlated Electrons · Physics 2009-11-10 S. Rayaprol , Kausik Sengupta , E. V. Sampathkumaran

Sr_4Cr_3O_9 is the n = 2 member of a family of quasi-one-dimensional compounds A_{n+2}T_{n+1}O_{3n+3} (A = Ca, Sr, or Ba, T = transition metal, and n = 1 to \infty) having a crystal structure which consists of chains of n TO_6 octahedra…

Strongly Correlated Electrons · Physics 2008-08-26 Yogesh Singh , D. C. johnston

We report a comprehensive experimental and theoretical study of the quasi-one-dimensional quantum magnet CuNCN. Based on magnetization measurements above room temperature as well as muon spin rotation and electron spin resonance…

We report the results of neutron powder diffraction studies on the spin-chain compound Ca3CoRhO6 in the temperature range 3 to 293 K. Bragg peaks due to magnetic ordering start appearing below about 100 K. The most interesting observation…

Condensed Matter · Physics 2009-11-10 M. Loewenhaupt , W. Schaefer , A. Niazi , E. V. Sampathkumaran

By means of muon spin rotation and relaxation ($\mu^+$SR) techniques, we have investigated the magnetism of quasi one-dimensional (1D) cobalt oxides $AE_{n+2}$Co$_{n+1}$O$_{3n+3}$ ($AE$=Ca, Sr and Ba, $n$=1, 2, 3, 5 and $\infty$), in which…

Strongly Correlated Electrons · Physics 2009-11-11 J. Sugiyama , H. Nozaki , J. H. Brewer , E. J. Ansaldo , T. Takami , H. Ikuta , U. Mizutani

We present the results of magnetic measurements on Nd6Co(1.67)Si3, a compound recently reported to crystallize in a hexagonal structure (space group P6_3/m) and to undergo long range magnetic ordering below 84 K. The results reveal that the…

Strongly Correlated Electrons · Physics 2009-11-13 Niharika Mohapatra , S. Narayana Jammalamadaka , Sitikantha D. Das , E. V. Sampathkumaran

We present a combined experimental and theoretical study of the spin-1/2 compound CuP$_2$O$_6$ that features a network of two-dimensional (2D) antiferromagnetic (AFM) square planes, interconnected via one-dimensional (1D) AFM spin chains.…

Two magnetic ordering transitions are found in InMnO3, the paramagnetic to antiferromagnetic transition near ~118 K and a lower possible spin rotation transition near ~42 K. Multiple length scale structural measurements reveal enhanced…

Materials Science · Physics 2015-06-22 T. Yu , T. A. Tyson , P. Gao , T. Wu , X. Hong , S. Ghose , Y. -S. Chen
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