Related papers: Kovacs effects in an aging molecular liquid
The Kovacs effect is a remarkable feature of the ageing dynamics of glass forming liquids near the glass transition temperature. It consists in a non-monotonous evolution of the volume/enthalpy after a succession of two abrupt temperature…
In this note we revisit the Kovacs effect, concerning the way in which the volume of a glass-forming liquid, which has been driven out of equilibrium, changes with time while the system evolves towards a metastable state. The theoret- ical…
This paper is an extended version of an article accepted for publication in Physical Review E. Besides its fundamental interest, the model that we investigate in this article is simple enough to be used as a basis for courses or tutorials…
The Kovacs or crossover effect is one of the peculiar behaviours exhibited by glasses and other complex, slowly relaxing systems. Roughly it consists in the non-monotonic relaxation to its equilibrium value of a macroscopic property of a…
The Kovacs protocol, based on the temperature shift experiment originally conceived by A.J. Kovacs for glassy polymers, is implemented in an exactly solvable dynamical model. This model is characterized by interacting fast and slow modes…
We discuss the `memory effect' discovered in the 60's by Kovacs in temperature shift experiments on glassy polymers, where the volume (or energy) displays a non monotonous time behaviour. This effect is generic and is observed on a variety…
We present a thermodynamic theory of the Kovacs effect based on the idea that the configurational degrees of freedom of a glass-forming material are driven out of equilibrium with the heat bath by irreversible thermal contraction and…
The Kovacs protocol, based on the temperature shift experiment originally conceived by A.J. Kovacs and applied on glassy polymers, is implemented in an exactly solvable model with facilitated dynamics. This model is based on interacting…
Volume and enthalpy relaxation of glasses after a sudden temperature change has been extensively studied since Kovacs seminal work. One observes an asymmetric approach to equilibrium upon cooling versus heating and, more…
We report a molecular dynamics simulation study of the properties of the potential energy landscape sampled by a system of water molecules during the process of generating a glass by cooling, and during the process of regenerating the…
Memory effect reflects a system's ability to encode, retain and retrieve information about its past. Such effects are essentially an out-of-equilibrium phenomenon providing insight into the complex structural and dynamical behavior of the…
Temperature Modulated calorimetry is widely used but still raises some fundamental questions. In this paper we study a model system as a test sample to address some of them. The model has a nontrivial spectrum of relaxation times. We…
The accuracy of a model to describe the horizontal dynamics of a confined quasi-two-dimensional system of inelastic hard spheres is discussed by comparing its predictions for the relaxation of the temperature in an homogenous system with…
The dynamic behaviour of glassy materials displays strong nonequilibrium effects, such as ageing in simple protocols, memory, rejuvenation and Kovacs effects in more elaborated experiments. We show that this phenomenology may be easily…
We apply the Kovacs experimental protocol to classical and quantum p-spin models. We show that these models have memory effects as those observed experimentally in super-cooled polymer melts. We discuss our results in connection to other…
Industrial polymeric materials often rely on antioxidants to achieve long-term reliability. Previous studies have frequently discussed the stabilization effect in the presence of macroscopic additive migration. However, the micro- to…
While memory effects have been reported for dense enough disordered systems such as glasses, we show here by a combination of analytical and simulation techniques that they are also intrinsic to the dynamics of dilute granular gases. By…
Strong and fragile glass relaxation behaviours are obtained simply changing the constraints of the kinetically constrained Ising chain from symmetric to purely asymmetric. We study the out-of-equilibrium dynamics of those two models…
We present a comprehensive study of non-equilibrium phenomena in the low temperature phase of the Edwards-Anderson Gaussian spin glass in 3 and 4 spatial dimensions. Many effects can be understood in terms of a time dependent coherence…
We investigate the Kovacs (or crossover) effect in facilitated $f$-spin models of glassy dynamics. Although the Kovacs hump shows a behavior qualitatively similar for all cases we have examined (irrespective of the facilitation parameter…