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The cornerstone of Boltzmann-Gibbs ($BG$) statistical mechanics is the Boltzmann-Gibbs-Jaynes-Shannon entropy $S_{BG} \equiv -k\int dx f(x)\ln f(x)$, where $k$ is a positive constant and $f(x)$ a probability density function. This theory…

Physics and Society · Physics 2009-11-11 Silvio M. Duarte Queiros , Celia Anteneodo , Constantino Tsallis

Clausius introduced, in the 1860s, a thermodynamical quantity which he named {\it entropy} $S$. This thermodynamically crucial quantity was proposed to be {\it extensive}, i.e., in contemporary terms, $S(N) \propto N$ in the thermodynamic…

Statistical Mechanics · Physics 2011-06-21 Constantino Tsallis

The general formalism for the nonextensive statistics based on the Landsberg-Vedral entropy was derived. The formula for the first law of thermodynamics and the exact relations of the thermodynamic quantities to their ensemble averages were…

Statistical Mechanics · Physics 2019-04-08 A. S. Parvan

This chapter deals with our recent attempt to extend the notion of equilibrium (EQ) entropy to nonequilibrium (NEQ) systems so that it can also capture memory effects. This is done by enlarging the equilibrium state space by introducing…

Statistical Mechanics · Physics 2022-01-03 P. D. Gujrati

Entropy maximization procedure has been a general practice in many diverse fields of science to obtain the concomitant probability distributions. The consistent use of the maximization procedure on the other hand requires the probability…

Statistical Mechanics · Physics 2018-10-17 Thomas Oikonomou , G. Baris Bagci

Within its range of applicability, the Boltzmann equation seems unique in its capacity to accurately describe the transition from almost any initial state to a self-equilibrated thermal state. Using information-theoretic methods to rephrase…

Statistical Mechanics · Physics 2025-10-07 Jürgen T. Stockburger

In this paper, we show that 1) additive energy is not appropriate for discussing the validity of Tsallis or R\'enyi statistics for nonextensive systems at meta-equilibrium; 2) $N$-body systems with nonadditive energy or entropy should be…

Statistical Mechanics · Physics 2007-05-23 Q. A. Wang , L. Nivanen , M. Pezeril , A. Le Méhauté

A proof of the relativistic $H$-theorem by including nonextensive effects is given. As it happens in the nonrelativistic limit, the molecular chaos hypothesis advanced by Boltzmann does not remain valid, and the second law of thermodynamics…

Statistical Mechanics · Physics 2009-11-11 R. Silva , J. A. S. Lima

Non-extensive thermodynamics was criticized among others by stating that the Zeroth Law cannot be satisfied with non-additive composition rules. In this paper we determine the general functional form of those non-additive composition rules…

General Physics · Physics 2011-07-06 T. S. Biró , P. Ván

Certain fluctuations in particle number at fixed total energy lead exactly to a cut-power law distribution in the one-particle energy, via the induced fluctuations in the phase-space volume ratio. The temperature parameter is expressed…

Statistical Mechanics · Physics 2014-12-10 Tamas Sandor Biro , Peter Van , Gergely Gabor Barnafoldi , Karoly Urmossy

We formulate a convenient generalization of the q-expectation value, based on the analogy of the symmetric quantum groups and q-calculus, and show that the q->q^{-1} symmetric nonextensive entropy preserves all of the mathematical structure…

Statistical Mechanics · Physics 2009-10-31 A. Lavagno , P. Narayana Swamy

Different quantities that go by the name of entropy are used in variational principles to infer probability distributions from limited data. Shore and Johnson showed that maximizing the Boltzmann- Gibbs form of the entropy ensures that…

Statistical Mechanics · Physics 2015-06-18 Steve Pressé , Kingshuk Ghosh , Julian Lee , Ken A. Dill

Starting from the basic-exponential, a q-deformed version of the exponential function established in the framework of the basic-hypergeometric series, we present a possible formulation of a generalized statistical mechanics. In a…

Statistical Mechanics · Physics 2008-11-26 A. Lavagno , A. M. Scarfone , P. Narayana Swamy

We review with a tutorial scope the information theory foundations of quantum statistical physics. Only a small proportion of the variables that characterize a system at the microscopic scale can be controlled, for both practical and…

Statistical Mechanics · Physics 2007-05-23 R. Balian

Through the generalization of Khinchin's classical axiomatic foundation, a basis is developed for nonadditive information theory. The classical nonadditive conditional entropy indexed by the positive parameter q is introduced and then…

Quantum Physics · Physics 2009-11-07 Sumiyoshi Abe

We consider an isolated system in an arbitrary state and provide a general formulation using first principles for an additive and non-negative statistical quantity that is shown to reproduce the equilibrium thermodynamic entropy of the…

Chemical Physics · Physics 2013-04-18 P. D. Gujrati

Shannon and Khinchin showed that assuming four information theoretic axioms the entropy must be of Boltzmann-Gibbs type, $S=-\sum_i p_i \log p_i$. Here we note that in physical systems one of these axioms may be violated. For non-ergodic…

Statistical Mechanics · Physics 2015-03-19 Stefan Thurner , Rudolf Hanel

In the case of a system with an unbounded hamiltonian the entropic index q of non-extensive thermodynamics has an upperbound q_c>1 beyond which the formalism becomes meaningless. The expression 1/(q_c-1) is the dimension of the state space…

Statistical Mechanics · Physics 2007-05-23 Jan Naudts

We show that the conservation and the non-additivity of the information, together with the additivity of the entropy make the entropy increase in an isolated system. The collapse of the entangled quantum state offers an example of the…

Quantum Physics · Physics 2009-11-13 Qi-Ren Zhang

The original canonical ensemble formalism for the nonextensive entropy thermostatistics is reconsidered. It is shown that the unambiguous connection of the statistical mechanics with the equilibrium thermodynamics is provided if the…

Statistical Mechanics · Physics 2009-11-11 A. S. Parvan