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In solution-processing of thin films, the material layer is deposited from a solution composed of several solutes and solvents. The final morphology and hence the properties of the film often depend on the time needed for the evaporation of…

The free energy of the solid and fluid phases of the Girifalco C60 model are determined through extensive Monte Carlo simulations. In this model the molecules interact through a spherical pair potential, characterized by a narrow and…

Soft Condensed Matter · Physics 2009-11-07 D. Costa , G. Pellicane , M. C. Abramo , C. Caccamo

The alternative approach to the displacement of gas/liquid equilibrium is developed on the basis of the Clapeyron equation. The phase transition in the system with well-established properties is taken as a reference process to search for…

Chemical Physics · Physics 2010-06-15 Vladimir Kh. Dobruskin

The equation of state of a hard sphere fluid at high density should exhibit a simple pole at the random close packing limit. Here we show that trying to obtain a compact semi-empirical equation of state simultaneously compatible with that…

Soft Condensed Matter · Physics 2019-08-14 Richard Bonneville

We investigate polydispersity effects on the average structure factor of colloidal suspensions of neutral particles with surface adhesion. A sticky hard sphere model alternative to Baxter's one is considered. The choice of factorizable…

Statistical Mechanics · Physics 2009-11-07 Domenico Gazzillo , Achille Giacometti

We derive a phase diagram for amorphous solids and liquid supercooled water and explain why the amorphous solids of water exist in several different forms. Application of large-deviation theory allows us to prepare such phases in computer…

Statistical Mechanics · Physics 2015-06-16 David T Limmer , David Chandler

Theory is presented for the phase stability of mixtures containing nanospheres and non-adsorbing reversible supramolecular polymers. This was made possible by incorporating the depletion thickness and osmotic pressure of reversible…

Soft Condensed Matter · Physics 2011-06-09 Remco Tuinier

Recent analyses of multifragmentation in terms of Fisher's model and the related construction of a phase diagram brings forth the problem of the true existence of the vapor phase and the meaning of its associated pressure. Our analysis…

Nuclear Experiment · Physics 2007-05-23 L. G. Moretto , J. B. Elliott , L. Phair , G. J. Wozniak

Motility and nonreciprocity are two primary mechanisms for self-organization in active matter. In a recent study [Phys. Rev. Lett. 131, 148301 (2023)], we explored their joint influence in a minimal model of two-species quorum-sensing…

Soft Condensed Matter · Physics 2025-04-15 Yu Duan , Jaime Agudo-Canalejo , Ramin Golestanian , Benoît Mahault

We propose a method of describing a phase transition in a cell fluid model with pair interaction potential that includes repulsive and attractive parts. An exact representation of the grand partition function of this model is obtained in…

Statistical Mechanics · Physics 2017-06-23 M. P. Kozlovskii , O. A. Dobush

Recent studies of the phase diagram for spherical, purely repulsive, active particles established the existence of a transition from a liquid-like to a solid-like phase analogous to the one observed in colloidal systems at thermal…

Statistical Mechanics · Physics 2020-04-30 Lorenzo Caprini , Claudio Maggi , Umberto Marini Bettolo Marconi , Matteo Paoluzzi , Andrea Puglisi

We study the crossover between liquid and solid electron phases in a two-dimensional harmonic trap as the density is progressively diluted. We infer the formation of geometrically ordered phases from charge distributions and pair…

Strongly Correlated Electrons · Physics 2007-05-23 Massimo Rontani , Carlo Cavazzoni , Guido Goldoni

Various biological and chemical processes lead to the nucleation and growth of non-wetting fluid bubbles within the pore space of a granular medium, such as the formation of gas bubbles in liquid-saturated lake-bed sediments. In…

Soft Condensed Matter · Physics 2022-05-13 Oliver W. Paulin , Liam C. Morrow , Matthew G. Hennessy , Christopher W. MacMinn

The phase behavior of hard superballs is examined using molecular dynamics within a deformable periodic simulation box. A superball's interior is defined by the inequality $|x|^{2q} + |y|^{2q} + |z|^{2q} \leq 1$, which provides a versatile…

Statistical Mechanics · Physics 2015-05-18 Robert D. Batten , Frank H. Stillinger , Salvatore Torquato

The phase behavior of binary fluid mixtures of hard hyperspheres in four and five dimensions is investigated. Spinodal instability is found by using a recent and accurate prescription for the equation of state of the mixture that requires…

Statistical Mechanics · Physics 2016-08-15 S. B. Yuste , A. Santos , M. López de Haro

We evidence via a computation in the reciprocal space the asymptotic behaviour of the high order virial coefficients for a hard sphere system. These coefficients, if their order is high enough, are those of a geometric series. We thus are…

Statistical Mechanics · Physics 2015-03-23 Richard Bonneville

We consider a ternary mixture of hard colloidal spheres, ideal polymer spheres, and rigid vanishingly thin needles, which model stretched polymers or colloidal rods. For this model we develop a geometry-based density functional theory,…

Soft Condensed Matter · Physics 2009-11-07 Matthias Schmidt , Alan R. Denton

The mass and size distributions are the key characteristics of any astrophysical objects, including the densest clumps comprising the cold phase of multiphase environments. In our recent papers, we showed how individual clouds of various…

Astrophysics of Galaxies · Physics 2019-05-01 Tim Waters , Daniel Proga

We present a new method for studying equilibrium properties of interacting fluids in an arbitrary external field. The fluid is composed of monodisperse spherical particles with hard-core repulsion and additional interactions of arbitrary…

Soft Condensed Matter · Physics 2021-03-09 Benaoumeur Bakhti , Gerhard Müller

The collision dynamics of hard spheres and cylindrical pores is solved exactly, which is the minimal model for a regularly porous membrane. Nonequilibrium event-driven molecular dynamics simulations are used to show that the permeability…

Soft Condensed Matter · Physics 2021-04-23 Yue Yu , Kai Zhang