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We extend the canonical Gibbs distribution, originally formulated for systems at equilibrium, to systems driven out of equilibrium. The stochastic dynamics of a small system are described by a probability distribution over discrete energy…

Statistical Mechanics · Physics 2026-03-31 Jean-Luc Garden

We consider conservative quantum evolutions possibly interrupted by macroscopic measurements. When started in a nonequilibrium state, the resulting path-space measure is not time-reversal invariant and the weight of time-reversal breaking…

Statistical Mechanics · Physics 2007-05-23 I. Callens , W. De Roeck , T. Jacobs , C. Maes , K. Netocny

The information shared among observables representing processes of interest is traditionally evaluated in terms of macroscale measures characterizing aggregate properties of the underlying processes and their interactions. Traditional…

Information Theory · Computer Science 2018-01-31 Rui A. P. Perdigão

We propose a new approximation-technique to deal with the exact macroscopic integro-differential evolution equations of statistical systems which self-consistently accounts for dissipative effects. Concentrating on one and two point…

High Energy Physics - Phenomenology · Physics 2007-05-23 Herbert Nachbagauer

We obtain the large deviation function for entropy production of the medium and its distribution function for two-site totally asymmetric simple exclusion process(TASEP) and three-state unicyclic network. Since such systems are described…

Statistical Mechanics · Physics 2016-01-29 Bappa Saha , Sutapa Mukherji

We derive a formula for the nonequilibrium entropy of a classical stochastic field in terms of correlation functions of this field. The formalism is then applied to define the entropy of gravitational perturbations (both gravitational waves…

General Relativity and Quantum Cosmology · Physics 2009-10-22 R. Brandenberger , T. Prokopec , V. Mukhanov

Given a thermodynamic process which carries a system from one equilibrium state to another, we construct a quantity whose average, over an ensemble of microscopic realizations of the process, depends only on these end states, even if at…

Statistical Mechanics · Physics 2015-06-25 C. Jarzynski

Using information entropy formalism, we consider a one-dimensional system with heat flux and extend the meaning of equilibrium variables to non equilibrium scenarios when classical local equilibrium approach is not applicable; this is…

Statistical Mechanics · Physics 2019-09-10 Sergey Sobolev

We analyze the dynamics of a simple but nontrivial classical Hamiltonian system of infinitely many coupled rotators. We assume that this infinite system is driven out of thermal equilibrium either because energy is injected by an external…

Statistical Mechanics · Physics 2015-06-25 David Ruelle

On a fine grained scale the Gibbs entropy of an isolated system remains constant throughout its dynamical evolution. This is a consequence of Liouville's theorem for Hamiltonian systems and appears to contradict the second law of…

Statistical Mechanics · Physics 2017-07-05 Renato Pakter , Yan Levin

After the justification of the maximum entropy approach for equilibrium thermodynamic system, and of a maximum path entropy algorithm for nonequilibrium thermodynamic systems by virtue of the principle of virtual work, we present in this…

Statistical Mechanics · Physics 2007-12-18 Qiuping A. Wang

Many measurements on soft condensed matter (e.g., biological and materials) systems track low-dimensional observables projected from the full system phase space as a function of time. Examples are dynamic structure factors, spectroscopic…

Statistical Mechanics · Physics 2021-02-03 Alessio Lapolla , Jeremy C. Smith , Aljaž Godec

According to the second law of thermodynamics, the arrow of time points to an ever increasing entropy of the Universe. However, exactly how the entropy evolves with time and what drives the growth remain largely unknown. Here, for the first…

Cosmology and Nongalactic Astrophysics · Physics 2012-11-09 Xinghai Zhao , Yuexing Li , Qirong Zhu , Derek Fox

The concept of entropy in statistical physics is related to the existence of irreversible macroscopic processes. In this work, we explore a recently introduced entropy formula for a class of stochastic processes with more than one absorbing…

Populations and Evolution · Quantitative Biology 2022-10-21 Diogo Costa-Cabanas , Fabio A. C. C. Chalub , Max O. Souza

Given the evolution of an arbitrary open quantum system, we formulate a general and unambiguous method to separate the internal energy change of the system into an entropy-related contribution and a part causing no entropy change,…

Quantum Physics · Physics 2022-10-26 S. Alipour , A. T. Rezakhani , A. Chenu , A. del Campo , T. Ala-Nissila

Configurational entropy is an important factor in the free energy change of many macromolecular recognition and binding processes, and has been intensively studied. Despite great progresses that have been made, the global sampling remains…

Biological Physics · Physics 2012-12-04 Wenzhao Li , Kai Wang , Suyan Tian , Pu Tian

Nonequilibrium phase transitions can be typified in a similar way to equilibrium systems, for instance, by the use of the order parameter. However, this characterization hides the irreversible character of the dynamics as well as its…

Statistical Mechanics · Physics 2019-07-10 C. E. Fernández Noa , Pedro E. Harunari , M. J. de Oliveira , C. E. Fiore

Estimating the dissipation, or the entropy production rate (EPR), can provide insights into the underlying mechanisms of nonequilibrium driven processes. Experimentally, however, only partial information can be accessed, and the ability to…

Statistical Mechanics · Physics 2022-12-29 Uri Kapustin , Aishani Ghosal , Gili Bisker

Time-asymmetric behavior as embodied in the second law of thermodynamics is observed in {\it individual macroscopic} systems. It can be understood as arising naturally from time-symmetric microscopic laws when account is taken of a) the…

Statistical Mechanics · Physics 2007-09-06 Joel L. Lebowitz

Development of thermodynamic induction up to second order gives a dynamical bifurcation for thermodynamic variables and allows for the prediction and detailed explanation of nonequilibrium phase transitions with associated spontaneous…

Statistical Mechanics · Physics 2021-10-07 S. N. Patitsas