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The large, temperature-independent, low-frequency dielectric constant recently observed in single-crystal CaCu{3}Ti{4}O{12} is most plausibly interpreted as arising from spatial inhomogenities of its local dielectric response. Probable…

Materials Science · Physics 2009-11-10 Morrel H. Cohen , J. B. Neaton , Lixin He , David Vanderbilt

In the present work the authors report results of broadband dielectric spectroscopy on various samples of CaCu3Ti4O12, including so far only rarely investigated single crystalline material. The measurements extend up to 1.3 GHz, covering…

Materials Science · Physics 2008-09-03 S. Krohns , P. Lunkenheimer , S. G. Ebbinghaus , A. Loidl

The temperature dependence of experimental charge carrier mobility is commonly used as a predictor of the dominant carrier scattering mechanism in semiconductors, particularly in thermoelectric applications. In this work, we critically…

Materials Science · Physics 2022-10-05 Alex M. Ganose , Junsoo Park , Anubhav Jain

The dielectric constant of CaCu3Ti4O12 is measured with a different electrode geometry than previous measurements. Similar colossal values are obtained showing that they are "intrinsic" to the material. We show that in braced structures…

Condensed Matter · Physics 2007-05-23 A. P. Ramirez , G. Lawes , V. Butko , M. A. Subramanian , C. M. Varma

Inelastic neutron scattering is used to investigate the temperature dependence of spin correlations in the 3-dimensional XY antiferromagnet Ni(Cl$_{1-x}$Br$_x$)$_2$$\cdot$4SC(NH$_2$)$_2$, $ x = 0.14(1)$, tuned close to the…

Strongly Correlated Electrons · Physics 2020-12-08 L. Facheris , D. Blosser , K. Yu. Povarov , R. Bewley , S. Gvasaliya , A. Zheludev

The local atomic structure and lattice dynamics of two isostructural layered transition metal dichalcogenides (TMDs), 1T-TiSe$_2$ and 1T-VSe$_2$, were studied using temperature-dependent X-ray absorption spectroscopy at the Ti, V, and Se…

Materials Science · Physics 2024-01-30 Inga Pudza , Boris Polyakov , Kaspars Pudzs , Edmund Welter , Alexei Kuzmin

Understanding and predicting the dominant diffusion processes in Cr2O3 is essential to its optimization for anti-corrosion coatings, spintronics, and other applications. Despite significant theoretical effort in modeling defect mediated…

Lithium doped sodium niobate is an ecofriendly piezoelectric material that exhibits a variety of structural phase transitions with composition and temperature. We have investigated the phase stabilities of an important composition…

The dielectric properties of CaCu3Ti4O12, a material showing colossal values of the dielectric constant, were investigated in a broad temperature and frequency range extending up to 1.3 GHz. A detailed equivalent circuit analysis of the…

Materials Science · Physics 2009-11-10 P. Lunkenheimer , R. Fichtl , S. G. Ebbinghaus , A. Loidl

Time-of-flight neutron powder diffraction and specific heat measurements were used to study the nature of thermal expansion in rhenium trioxide, an electrically conducting oxide with cubic symmetry. The temperature evolution of the lattice…

The classification of structural phase transitions as displacive or order-disorder in character is usually based on spectroscopic data above the transition. We use single crystal x-ray diffraction to investigate structural correlations in…

Neutron diffraction measurements of a high quality single crystal of CaFe2As2 are reported. A sharp transition was observed between the high temperature tetragonal and low temperature orthorhombic structures at TS = 172.5K (on cooling) and…

We have performed thermal expansion and compressibility measurements on the recently discovered superconducting material NaxCoO2*4xD2O (x=1/3) using neutron powder diffraction over the temperature range 10-295 K and the pressure range 0-0.6…

Superconductivity · Physics 2009-11-11 J. D. Jorgensen , M. Avdeev , D. G. Hinks , P. W. Barnes , S. Short

Spin defects in silicon carbide (SiC) have attracted increasing interest due to their excellent optical and spin properties, which are useful in quantum information processing. In this paper, we systematically investigate the temperature…

We have investigated experimentally how properties of NdFeAsO0.8F0.2 superconductor affected due to the substitution of the calcium by the neodymium. We have synthesized polycrystalline Nd1-xCaxFeAsO0.8F0.2 samples with x=0, 0.01, 0.025,…

Superconductivity · Physics 2019-01-31 F. Shahbaz Tehrani , V. Daadmehr

We study the temperature dependence of the conductivity of the 2D electronic solid. In realistic samples, a domain structure forms in the solid and each domain randomly orients in the absence of the in-plane field. At higher temperature,…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Shi-Jie Yang , Yue Yu

By means of molecular-dynamics simulations, temperature driven diffusionless structural phase transitions in equi- and nearly equiatomic ordered nickel-titanium alloys were investigated. For this purpose, a model potential from the…

Materials Science · Physics 2022-01-04 Daniel Mutter , Peter Nielaba

In accordance with a relation between the lattice parameter c and the concentration of holes p, which has been found earlier for the YBa2Cu3O6+d compound, we obtain the p parameter in the same manner for the solid solution Nd1.2Ba1.8Cu3O6+d…

Materials Science · Physics 2018-01-03 A. V. Fetisov , S. Kh. Estemirova

Temperature dependent electrical resistivity, crystal structure and heat capacity measurements reveal a resistivity drop and metal to semiconductor transition corresponding to first order structural phase transition near 400 K in Ca3Co4O9.…

Materials Science · Physics 2012-04-17 Tao Wu , Trevor A. Tyson , Haiyan Chen , Jianming Bai , Hsin Wang , Cherno Jaye

The temperature dependence of optical constants of titanium nitride thin film is investigated using spectroscopic ellipsometry between 1.4 to 5 eV in the temperature range 300 K to 650 K in steps of 50 K. The real and imaginary parts of the…

Materials Science · Physics 2016-11-26 S. Tripura Sundari , R. Ramaseshan , Feby Jose , S. Dash , A. K. Tyagi