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Related papers: A self-interaction corrected pseudopotential schem…

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We propose a simplified version of self-interaction corrected local spin-density (SIC-LSD) approximation, based on multiple scattering theory, which implements self-interaction correction locally, within the KKR method. The multiple…

Strongly Correlated Electrons · Physics 2016-08-16 M. Lüders , A. Ernst , M. Däne , Z. Szotek , A. Svane , D. Ködderitzsch , W. Hergert , B. L. Györffy , W. M. Temmerman

We extend some of the well established self-interaction correction (SIC) schemes of density-functional theory to the case of systems with noncollinear magnetism. Our proposed SIC schemes are tested on a set of molecules and metallic…

Chemical Physics · Physics 2023-10-31 Nicolas Tancogne-Dejean , Martin Lüders , Carsten A. Ullrich

Standard spin-density functionals for the exchange-correlation energy of a many-electron ground state make serious self-interaction errors which can be corrected by the Perdew-Zunger self-interaction correction (SIC). We propose a…

Materials Science · Physics 2014-01-28 Mark R Pederson , Adrienn Ruzsinszky , John P. Perdew

By combining the Self-Interaction Correction (SIC) with pseudopotential perturbation theory, the role of self-interaction errors inherent to the Local Density Approximation (LDA) to Density Functional Theory is estimated in the…

mtrl-th · Physics 2009-10-28 Jorge M. Pacheco , Walter Ekardt , Wolf-Dieter Schoene

We describe the behavior of the Perdew-Zunger self-interaction-corrected local density approximation (SIC-LDA) functional when implemented in a plane-wave pseudopotential formalism with Wannier functions. Prototypical semiconductors and…

Other Condensed Matter · Physics 2011-03-03 Massimiliano Stengel , Nicola A. Spaldin

Accurate prediction of spin-state energy difference is crucial for understanding the spin crossover (SCO) phenomena and is very challenging for the density functional approximations, especially for the local and semi-local approximations,…

Chemical Physics · Physics 2023-02-22 Selim Romero , Tunna Baruah , Rajendra R. Zope

We present a fully variational locally scaled self-interaction corrected (SIC) energy functional using complex optimal orbitals. This represents an important milestone for fully variational SIC energy functionals, which have been shown to…

The electronic structures of several actinide solid systems are calculated using the self-interaction corrected local spin density approximation. Within this scheme the $5f$ electron manifold is considered to consist of both localized and…

Strongly Correlated Electrons · Physics 2007-05-23 L. Petit , A. Svane , Z. Szotek , W. M. Temmerman

The Perdew-Zunger self-interaction correction(PZ-SIC) improves the performance of density functional approximations(DFAs) for the properties that involve significant self-interaction error(SIE), as in stretched bond situations, but…

Semilocal density-functional approximations (DFAs), including the state-of-the-art SCAN functional, are plagued by the self-interaction error (SIE). While this error is explicitly defined only for one-electron systems, it has inspired the…

Materials Science · Physics 2024-01-23 Sheng Bi , Christian Carbogno , Igor Ying Zhang , Matthias Scheffler

Recently proposed local self-interaction correction (LSIC) method [Zope, R. R. et al., J. Chem. Phys. 151, 214108 (2019)] is a one-electron self-interaction-correction (SIC) method that uses an iso-orbital indicator to apply the SIC at each…

Chemical Physics · Physics 2023-02-22 Yoh Yamamoto , Tunna Baruah , Po-Hao Chang , Selim Romero , Rajendra R. Zope

We calculate the electronic structure of several atoms and small molecules by direct minimization of the Self-Interaction Corrected Local Density Approximation (SIC-LDA) functional. To do this we first derive an expression for the gradient…

Condensed Matter · Physics 2009-10-28 S. Goedecker , C. J. Umrigar

Density functional theory (DFT) and beyond-DFT methods are often used in combination with photoelectron spectroscopy to obtain physical insights into the electronic structure of molecules and solids. The Kohn-Sham eigenvalues are not…

We present applications of the recently introduced ``Generalized SIC-Slater'' scheme which provides a simple Self-Interaction Correction approximation in the framework of the Optimized Effective Potential. We focus on the computation of…

Quantum Physics · Physics 2015-05-13 J. Messud , Z. Wang , P. M. Dinh , P. -G. Reinhard , E. Suraud

Semi-local approximations to the density functional for the exchange-correlation energy of a many-electron system necessarily fail for lobed one-electron densities, including not only the familiar stretched densities but also the less…

We propose a computational method that simplifies drastically the inclusion of spin-orbit interaction in density functional theory implemented on localised atomic orbital basis sets. Our method is based on a well-known procedure for…

Materials Science · Physics 2009-11-11 Lucas Fernandez-Seivane , Miguel A. Oliveira , Stefano Sanvito , Jaime Ferrer

Self-interaction (SI) error, which results when exchange-correlation contributions to the total energy are approximated, limits the reliability of many density functional approximations. The Perdew-Zunger SI correction (PZSIC), when applied…

A self-consistent projection operator method for single-particle excitations is developed. It describes the nonlocal correlations on the basis of a projection technique to the retarded Green function and the off-diagonal effective medium.…

Strongly Correlated Electrons · Physics 2015-05-14 Yoshiro Kakehashi , Tetsuro Nakamura , Peter Fulde

A self-consistent calculation scheme for correlated electron systems is created based on the density-functional theory (DFT). Our scheme is a multi-reference DFT (MR-DFT) calculation in which the electron charge density is reproduced by an…

Strongly Correlated Electrons · Physics 2009-11-13 Koichi Kusakabe , Naoshi Suzuki , Shusuke Yamanaka , Kizashi Yamaguchi

We present an atomic orbital based approximate scheme for self-interaction correction (SIC) to the local density approximation of density functional theory. The method, based on the idea of Filippetti and Spaldin [Phys. Rev. B 67, 125109…

Strongly Correlated Electrons · Physics 2013-05-29 C. D. Pemmaraju , T. Archer , D. Sanchez-Portal , S. Sanvito
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