Related papers: Extended Generic Nature of Surface Entropy
The contact angle of a liquid droplet on a solid surface is a direct measure of fundamental atomic-scale forces acting between liquid molecules and the solid surface. In this work, the validity is assessed of a simple equation, which…
In this paper we propose an analytic expression for surface tension of organic compounds. This new expression, originally derived from the statistical-mechanics is shown to represent the experimental surface tension data of 94 different…
In work [1] ("Temperature dependence of ultracold neutron loss rates" E.Korobkina et al., PRB 70,035409) results of measurement of temperature dependence of losses of ultracold neutrons (UCN) in a range from 4 K to 300 K at UCN storage in a…
This work addresses a longstanding theoretical discrepancy using Density Functional Theory (DFT) with experimental observations of CO binding trends on electrocatalytically relevant metals for the CO2 reduction reaction (CO2RR). By…
Using a recently developed formalism, we present an in-depth analysis of how the thermodynamics of the climate system varies with CO2 concentration by performing experiments with a simplified yet Earth-like climate model. We find that, in…
The contact angle of a liquid drop on a rigid surface is determined by the classical theory of Young-Laplace. For chemically homogeneous surfaces, this angle is a constant. We study the minimal-energy configurations of liquid drops on rough…
The problem of surface effects at a fluid boundary created by the force field of finite value is investigated. A classical simple fluid with a locally introduced field imitating a permeable solid is considered. The cases of micro- and…
The dramatic slowdown of glass-forming liquids has been variously linked to increasing dynamic and static correlation lengths. Yet, empirical evidence is insufficient to decide among competing theories. The random first order theory (RFOT)…
I compute the leading contribution to the ground state Renyi entropy $S_{\alpha}$ for a region of linear size $L$ in a Fermi liquid. The result contains a universal boundary law violating term simply related the more familiar entanglement…
In a recent paper [Franzosi, Physica A {\bf 494}, 302 (2018)], we have suggested to use of the surface entropy, namely the logarithm of the area of a hypersurface of constant energy in the phase space, as an expression for the thermodynamic…
The line tension of an electrolyte wetting a non-polar substrate is computed analytically and numerically. The results show that, depending on the value of the apparent contact angle, positive or negative line tension values may be…
Twenty years ago Poole et al. (Nature 360, 324, 1992) suggested that the anomalous properties of supercooled water may be caused by a critical point that terminates a line of liquid-liquid separation of lower-density and higher-density…
Relations between the thermodynamics and dynamics of supercooled liquids approaching a glass transition have been proposed over many years. The potential energy surface of model liquids has been increasingly studied since it provides a…
Starting out with an entropy identity, the entropy flux, the entropy production and the corresponding Gibbs and Gibbs-Duhem equations of general-covariant conti\-nuum thermodynamics are established. Non-dissipative materials and equilibria…
We develop a geometric foundation of microcanonical thermodynamics in which entropy and its derivatives are determined from the geometry of phase space, rather than being introduced through an a priori ensemble postulate. Once the minimal…
The essence of the second law of classical thermodynamics is the `entropy principle' which asserts the existence of an additive and extensive entropy function, S, that is defined for all equilibrium states of thermodynamic systems and whose…
We investigate connections between the continuum and atomistic descriptions of deformable crystals, using certain interesting results from number theory. The energy of a deformed crystal is calculated in the context of a lattice model with…
The thermodynamic definition of entropy can be extended to nonequilibrium systems based on its relation to information. To apply this definition in practice requires access to the physical system's microstates, which may be prohibitively…
The total entropy production fluctuations are studied in some exactly solvable models. For these systems, the detailed fluctuation theorem holds even in the transient state, provided initially the system is prepared in thermal equilibrium.…
We derive a universal thermodynamic bound constraining directional transport in both discrete and continuous nonequilibrium systems. For continuous-time Markov jump processes and overdamped diffusions governed by Fokker--Planck equations,…