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We derive a formulation of the First Law of nonequilibrium thermodynamics for biological information-processing systems by partitioning entropy in the Second Law into microscopic and mesoscopic components and by assuming that natural…

Statistical Mechanics · Physics 2025-11-03 Roger D. Jones , Achille Giacometti , Alan M. Jones

The example of macroscopic thermodynamical system violating the Clausius inequality is presented.

General Physics · Physics 2007-05-23 A. V. Gavrilov

A scheme for treating the Second Law of thermodynamics as a constraint and accounting for the approximate nature of constitutive assumptions in continuum thermomechanics is discussed. An unconstrained, concave, variational principle is…

Classical Physics · Physics 2024-12-31 Amit Acharya

Second law of thermodynamics is applied to a few electronic processes. It is seen that the second law of thermodynamics holds good for all except one mentioned here. The classical approach, based on exact equivalence of emission and…

General Physics · Physics 2007-05-23 R. C. Gupta , Ruchi Gupta , Sanjay Gupta

A review is given on the thermodynamical structure of bipartite entanglement. By comparing it to the axiomatic formulation of thermodynamics presented by Giles it is shown that for finite dimensional systems the two theories are formally…

Quantum Physics · Physics 2016-04-11 Nikolaos K. Kollas

It exists a large class of systems for which the traditional notion of extensivity breaks down. From experimental examples we induce two general hypothesis concerning such systems. In the first the existence of an internal coordinate system…

Statistical Mechanics · Physics 2015-03-09 J-P. Badiali , A. El Kaabouchi

This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

We use the work done on and the heat removed from a system to maintain it in a nonequilibrium steady state for a thermodynamic-like description of such a system as well as of its fluctuations. Based on a generalized Onsager-Machlup theory…

Statistical Mechanics · Physics 2008-02-10 Tooru Taniguchi , E. G. D. Cohen

After presenting possible motives for fighting against the second law of thermodynamics, several attempts to beat this law are analyzed. The second law wins, but an interesting interpretation of it emerges. This interpretation uses the…

adap-org · Physics 2015-06-30 Jorge Berger

Recently, there has been a considerable progress on the issue of the thermodynamic second law, which is known as the law of entropy increase or irreversibility. In particular, a novel symmetry known as the Gallavotti-Cohen symmetry is found…

Statistical Mechanics · Physics 2018-08-01 Hyunggyu Park

We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function…

Statistical Mechanics · Physics 2015-05-13 H. -H. Hasegawa , J. Ishikawa , K. Takara , D. J. Driebe

Aspects of the modern dynamical systems approach to thermodynamics of stationary states out of equilibrium with attention to the original conceptions which arose at the beginnings of Statistical Mechanics

Statistical Mechanics · Physics 2019-01-28 Giovanni Gallavotti

It has long been known that, fundamentally different from a large body of rarefied gas, when a Knudsen gas is immersed in a thermal bath, it may never reach thermal equilibrium. The root cause is nonchaoticity: as the particle-particle…

Statistical Mechanics · Physics 2024-11-15 Yu Qiao , Zhaoru Shang

Path thermodynamic formulation of non-equilibrium reactive systems is considered. It is shown through simple practical examples that this approach can lead to results that contradict well established thermodynamic properties of such…

Mathematical Physics · Physics 2020-05-27 M. Malek Mansour , Alejandro L. Garcia

The thermodynamics is studied with the thermodynamic parameter of the lifetime, first-passage time, generalizing the equilibrium thermodynamics. Various ways of describing several stationary nonequilibrium states in the system are…

Statistical Mechanics · Physics 2019-10-21 V. V. Ryazanov

Noncommutativity of observables is a central feature of quantum physics. It plays a fundamental role in the formulation of the uncertainty principle for complementary variables and strongly affects the laws of thermodynamics for systems…

Quantum Physics · Physics 2025-10-07 Franklin L. S. Rodrigues , Eric Lutz

Several comments are given to previous proofs of the generalised second law of thermodynamics: black hole entropy plus ordinary matter entropy never decreases for a thermally closed system. Arguments in favour of its truism are given in the…

General Relativity and Quantum Cosmology · Physics 2007-05-23 S. -T. Sung

We use rigorous non-equilibrium thermodynamic arguments to prove (i) the residual entropy of any system is bounded below by the experimentally (calorimetrically) determined absolute temperature entropy, which itself is bounded below by the…

Statistical Mechanics · Physics 2011-06-13 P. D. Gujrati

The purpose of this work is to discuss recent progress in deriving the fundamental laws of thermodynamics (0th, 1st and 2nd-law) from nonequilibrium quantum statistical mechanics. Basic thermodynamic notions are clarified and different…

Mathematical Physics · Physics 2007-05-23 Walid K. Abou Salem

Nonequilibrium thermodynamics has shown its applicability in a wide variety of different situations pertaining to fields such as physics, chemistry, biology, and engineering. As successful as it is, however, its current formulation…

Condensed Matter · Physics 2009-11-07 J. M. G. Vilar , J. M. Rubi