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We used the exact eigenvectors of the generalized Hubbard Hamiltonian solution to predict the transition intensities of the well known $GR1$ and $ND1$ transitions at the neutral and charged vacancies in diamond. In addition to using exact…

Materials Science · Physics 2007-05-23 Mehdi Heidari Saani , Mohammad Ali Vesaghi , Keivan Esfarjani

Using a recently developed quantum embedding theory, we present first principles calculations of strongly correlated states of spin defects in diamond. Within this theory, effective Hamiltonians are constructed, which can be solved by…

Materials Science · Physics 2020-12-30 He Ma , Nan Sheng , Marco Govoni , Giulia Galli

Diamond is a solid-state platform to develop quantum technologies, but it has been a long-standing problem that the current understanding of quantum states in diamond is mostly limited to single-electron pictures. Here, we combine the full…

Chemical Physics · Physics 2023-07-19 Yilin Chen , Tonghuan Jiang , Haoxiang Chen , Erxun Han , Ali Alavi , Kuang Yu , En-Ge Wang , Ji Chen

Hubbard-like Hamiltonians are widely used to describe on-site Coulomb interactions in magnetic and strongly-correlated solids, but there is much confusion in the literature about the form these Hamiltonians should take for shells of p and d…

Strongly Correlated Electrons · Physics 2016-02-10 M. E. A. Coury , S. L. Dudarev , W. M. C. Foulkes , A. P. Horsfield , Pui-Wai Ma , J. S. Spencer

We construct exact ground states of interacting electrons on triangle and diamond Hubbard chains. The construction requires (i) a rewriting of the Hamiltonian into positive semidefinite form, (ii) the construction of a many-electron ground…

Strongly Correlated Electrons · Physics 2015-05-13 Zsolt Gulacsi , Arno Kampf , Dieter Vollhardt

Elucidation of the mechanism for optical spin initialization of point defects in solids in the context of quantum applications requires an accurate description of the excited electronic states involved. While variational density functional…

Materials Science · Physics 2023-07-14 Aleksei V. Ivanov , Yorick L. A. Schmerwitz , Gianluca Levi , Hannes Jónsson

Based on the standard many-fermion field theory, the authors construct models describing ultracold fermions in a 1D optical lattices by implementing a mode expansion of the fermionic field operator where modes, in addition to space…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Francesco Massel , Vittorio Penna

We discuss how to construct a tight binding model Hamiltonan for the simplest possible solid, composed of hydrogen-like atoms. A single orbital per atom is not sufficient because the on-site electron-electron repulsion mixes in higher…

Strongly Correlated Electrons · Physics 2014-09-09 J. E. Hirsch

We consider a model Hamiltonian for a dimer including all the electronic one- and two-body terms consistent with a single orbital per site, a free Einstein phonon term, and an electron-phonon coupling of the Holstein type. The bare…

Strongly Correlated Electrons · Physics 2009-10-31 M. Acquarone , J. R. Iglesias , M. A. Gusmao , C. Noce , A. Romano

We present a statistical mechanics description to study the ground state of quantum systems. In this approach, averages for the complete system are calculated over the non-interacting energy levels. Taking different interaction parameter,…

Statistical Mechanics · Physics 2015-05-20 Andre M. C. Souza

We construct a class of exact ground states for correlated electrons on pentagon chains in the high density region and discuss their physical properties. In this procedure the Hamiltonian is first cast in a positive semidefinite form using…

Strongly Correlated Electrons · Physics 2013-05-27 Zsolt Gulacsi

The quantum mechanical motion of the atomic nuclei is considered over a single- or a multi-dimensional subspace of electronic states which is separated by a gap from the rest of the electronic spectrum over the relevant range of nuclear…

Chemical Physics · Physics 2019-07-24 Edit Matyus , Stefan Teufel

The five-band Hubbard model for a $d$ band with one electron per site is a model which has very interesting properties when the relevant ions are located at sites with high (e. g. cubic) symmetry. In that case, if the crystal field…

Strongly Correlated Electrons · Physics 2009-11-10 A. B. Harris , T. Yildirim , A. Aharony , O. Entin-Wohlman , I. Ya. Korenblit

Group-IV -- Vacancy color centers in diamond are fast emerging qubits that can be harnessed in quantum communication and sensor applications. There is an immediate quest for understanding their magneto-optical properties, in order to select…

Quantum Physics · Physics 2018-06-20 Gergő Thiering , Adam Gali

Nitrogen-vacancy center in diamond is a solid state defect qubit with favorable coherence time up to room temperature which could be harnessed in several quantum enhanced sensor and quantum communication applications, and has a potential in…

Quantum Physics · Physics 2019-09-20 Adam Gali

We derive an electron-vibration model Hamiltonian in a quantum chemical framework, and explore the extent to which such a Hamiltonian can capture key effects of nonadiabatic dynamics. The model Hamiltonian is a simple two-body operator, and…

Chemical Physics · Physics 2021-02-03 Thomas Dresselhaus , Callum B. A. Bungey , Peter J. Knowles , Frederick R. Manby

We present calculations of the ground and excited state energies of spin defects in solids carried out on a quantum computer, using a hybrid classical/quantum protocol. We focus on the negatively charged nitrogen vacancy center in diamond…

Quantum Physics · Physics 2025-07-01 Benchen Huang , Marco Govoni , Giulia Galli

Due to interest in both solid state based quantum computing architectures and the application of quantum mechanical systems to nanomagnetometry, there has been considerable recent attention focused on understanding the microscopic dynamics…

Mesoscale and Nanoscale Physics · Physics 2013-09-30 Liam T. Hall , Jared H. Cole , Lloyd C. L. Hollenberg

We present a model intended for rapid sampling of ground and excited state potential energy surfaces for first-row transition metal active sites. The method is computationally inexpensive and is suited for dynamics simulations where (1)…

Chemical Physics · Physics 2009-11-10 M. X. LaBute , R. G. Endres , D. L. Cox

We introduce a Hubbard model as the simple quantum generalization of the classical capacitance circuit model to study semiconductor quantum-dot spin qubits. We prove theoretically that our model is equivalent to the usual capacitance…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Shuo Yang , Xin Wang , S. Das Sarma
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