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Configurational fluctuations of conducting polymers in solution can bring into proximity monomers which are distant from each other along the backbone. Electrons can hop between these monomers across the "bridges" so formed. We show how…

Soft Condensed Matter · Physics 2009-10-31 Daniel W. Hone , Henri Orland

Electron transport properties of C$_{20}$ molecules suspended between gold electrodes are investigated using first-principles calculations. Our study reveals that the conductances are quite sensitive to the number of C$_{20}$ molecules…

Condensed Matter · Physics 2009-11-10 Megumi Otani , Tomoya Ono , Kikuji Hirose

This tutorial outlines the basic theoretical concepts and tools which underpin the fundamentals of phase-coherent electron transport through single molecules. The key quantity of interest is the transmission coefficient T(E), which yields…

Mesoscale and Nanoscale Physics · Physics 2016-01-05 C J Lambert

Collective transport through channels shows surprising properties under one-dimensional confinement: particles in a single file exhibit sub-diffusive behavior, while liquid confinement causes distance-independent correlations between the…

Soft Condensed Matter · Physics 2019-06-05 Karolis Misiunas , Ulrich F. Keyser

Achieving highly transmitting molecular junctions through resonant transport at low bias is key to the next-generation low-power molecular devices. Although, resonant transport in molecular junctions was observed by connecting a molecule…

Mesoscale and Nanoscale Physics · Physics 2023-08-09 Biswajit Pabi , Štepán Marek , Adwitiya Pal , Puja Kumari , Soumya Jyoti Ray , Arunabha Thakur , Richard Korytár , Atindra Nath Pal

This thesis investigates the mechanically controlled break junctions, with a particular emphasis on elucidating the behaviour of molecular currents at room temperature. The core of this experimental investigation involves a detailed…

Mesoscale and Nanoscale Physics · Physics 2024-09-17 Giovanna Angelis Schmidt

Non-equilibrium Green's functions (NEGF) formalism combined with extended Huckel (EHT) and charging model are used to study electrical conduction through single-molecule junctions. Analyzed molecular complex is composed of asymmetric…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Kamil Walczak , Sergey Edward Lyshevski

We present first-principles calculations of the dI/dV characteristics of an H2 molecule sandwiched between Au and Pt electrodes in the presence of electron-phonon interactions. The conductance is found to decrease by a few percentage at…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 I. S. Kristensen , M. Paulsson , K. S. Thygesen , K. W. Jacobsen

Recently, Song et al [Nature 462, 1039 (2009)] employed transition-voltage spectroscopy to demonstrate that the energy $\varepsilon_H$ of the highest occupied molecular orbital (HOMO) of single-molecule transistors can be controlled by a…

Mesoscale and Nanoscale Physics · Physics 2010-07-29 Ioan Baldea

The single-molecule conductance of a 3-ring, conjugated azomethine was studied using the mechanically controlled breakjunction technique. Charge transport properties are found to be comparable to vinyl-based analogues; findings are…

Mesoscale and Nanoscale Physics · Physics 2016-08-18 Max Koole , Riccardo Frisenda , Michiel L. Petrus , Mickael L. Perrin , Herre S. J. van der Zant , Theo J. Dingemans

Coherent electron transport through a quantum channel in the presence of a general extended scattering potential is investigated using a T-matrix Lippmann-Schwinger approach. The formalism is applied to a quantum wire with Gaussian type…

Using first-principles calculations, we systematically study the potential energy surfaces and dissociation processes of the hydrogen molecule on the Mg(0001) surface. It is found that during the dissociative adsorption process with the…

Materials Science · Physics 2015-05-13 Yanfang Li , Yu Yang , Bo Sun , Hong-Zhou Song , Yinghui Wei , Ping Zhang

Electronic transport properties for single-molecule junctions have been widely measured by several techniques, including mechanically controllable break junctions, electromigration break junctions or by means of scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2020-07-22 Ferdinand Evers , Richard Korytár , Sumit Tewari , Jan M. van Ruitenbeek

Electronic transport characteristics through a single phenalenyl molecule sandwiched between two metallic electrodes are investigated by the use of Green's function technique. A parametric approach, based on the tight-binding model, is used…

Mesoscale and Nanoscale Physics · Physics 2009-11-06 Santanu K. Maiti

We have determined the transmission coefficients of atomic-sized Zn contacts using a new type of breakjunction which contains a whisker as a central bridge. We find that in the last conductance plateau the transport is unexpectedly…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 M. Häfner , P. Konrad , F. Pauly , J. C. Cuevas , E. Scheer

Ion channels are protein structures that facilitate the selective passage of ions across the membrane cells of living organisms. They are known for their high conductance and high selectivity. The precise mechanism between these two…

Biological Physics · Physics 2025-02-12 Mateusz Polakowski , Miłosz Panfil

The ability to control the conductance of single molecules will have a major impact in nanoscale electronics. Azobenzene, a molecule that changes conformation as a result of a trans/cis transition when exposed to radiation, could form the…

Mesoscale and Nanoscale Physics · Physics 2008-11-26 Miriam del Valle , Rafael Gutierrez , Carlos Tejedor , Gianaurelio Cuniberti

The realization of single-molecule thermal conductance measurements has driven the need for theoretical tools to describe conduction processes that occur over atomistic length scales. In macroscale systems, the principle that is typically…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Galen T. Craven , Abraham Nitzan

We investigate the electronic transport through a molecule in the Kondo regime. The tunneling between the electrode and the molecule is asymmetrically modulated by the oscillations of the molecule, i.e., if the molecule gets closer to one…

Mesoscale and Nanoscale Physics · Physics 2008-12-09 J. Mravlje , A. Ramsak

In this work, we have investigated conduction through an artificial molecule comprising two coupled quantum dots. The question addressed is the role of inter-dot coupling on electronic transport. We find that the current through the…

Mesoscale and Nanoscale Physics · Physics 2011-09-22 M. Imran , B. Tariq , M. Tahir , K. Sabeeh