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A class of bistable "stator-rotor" molecules is proposed, where a stationary bridge (stator) connects the two electrodes and facilitates electron transport between them. The rotor part, which has a large dipole moment, is attached to an…

Soft Condensed Matter · Physics 2009-11-07 P. E. Kornilovitch , A. M. Bratkovsky , R. S. Williams

The energy dependent thermoelectric response of a single molecule contains valuable information about its transmission function and its excited states. However, measuring it requires devices that can efficiently heat up one side of the…

Transport properties of metal-molecule-metal junctions containing monolayer of conjugated and saturated molecules with characteristic dimensions in the range of 30-300 nm are correlated with microscopic topography, stress and chemical…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Nikolai B. Zhitenev , Weirong Jiang , Artur Erbe , Zhenan Bao , Eric Garfunkel , Donald M. Tennant , Raymond A. Cirelli

We present a theoretical study of the electronic transport through single-molecule junctions incorporating a Pt6 metal cluster bound within an organic framework. We show that the insertion of this molecule between a pair of electrodes leads…

Mesoscale and Nanoscale Physics · Physics 2013-02-27 Linda A. Zotti , Edmund Leary , Maria Soriano , Juan Carlos Cuevas , Juan Jose Palacios

Using molecular dynamics simulation, we investigate transport properties of a classical two-dimensional electron system confined in a microchannel with a narrow constriction. As a function of the confinement strength of the constriction,…

Mesoscale and Nanoscale Physics · Physics 2012-10-18 Moto Araki , Hisao Hayakawa

Analytic results for the conductance of a molecular wire attached to mesoscopic tubule leads are obtained. They permit to study linear transport in presence of low dimensional leads in the whole range of parameters. In particular contact…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Cuniberti , G. Fagas , K. Richter

Notwithstanding the discreteness of metallic constrictions, it is shown that the finite elasticity of stable, single-atom gold constrictions allows for a continuous and reversible change in conductance, thereby enabling observation of…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Jason N. Armstrong , R. M. Schaub , Susan Z. Hua , Harsh Deep Chopra

The possibility of using single molecule junctions as electron pumps for energy conversion and storage is considered. It is argued that the small dimensions of these systems enable to make use of unique intra-molecular quantum coherences in…

Quantum Physics · Physics 2015-05-20 Roie Volkovich , Uri Peskin

Transport of molecules across membrane channels is investigated theoretically using exactly solvable discrete stochastic site-binding models. It is shown that the interaction potential between molecules and the channel has a strong effect…

Soft Condensed Matter · Physics 2009-11-11 Anatoly B. Kolomeisky

Conductance switching has been reported in many molecular junction devices, but in most cases has not been convincingly explained. We investigate conductance switching in Pt/stearic acid monolayer/Ti devices using pressure-modulated…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Feng Miao , Douglas Ohlberg , Duncan Stewart , R. Stanley Williams , Chun Ning Lau*

The hydrogen phase diagram has a number of unusual features which are generally well reproduced by density functional calculations. Unfortunately, these calculations fail to provide good physical insights into why those features occur. In…

Materials Science · Physics 2020-10-28 Hongxiang Zong , Heather Wiebe , Graeme J. Ackland

Molecular electronics offers unique scientific and technological possibilities, resulting from both the nanometre scale of the devices and their reproducible chemical complexity. Two fundamental yet different effects, with no classical…

Mesoscale and Nanoscale Physics · Physics 2017-05-12 Andrew K. Mitchell , Kim G. L. Pedersen , Per Hedegaard , Jens Paaske

We study linear electron transport through a molecular wire sandwiched between nanotube leads. We show that the presence of such electrodes strongly influences the calculated conductance. We find that depending on the quality and geometry…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 G. Cuniberti , G. Fagas , K. Richter

Measurements of the thermal conductance of single-molecule junctions have recently been reported for the first time. It is presently unclear, how much the heat transport can be controlled through molecule-internal effects. The search for…

Mesoscale and Nanoscale Physics · Physics 2025-10-01 Matthias Blaschke , Fabian Pauly

The structural and electronic properties of a single pentacene molecule and a pentacene molecular crystal, an organic semiconductor, are examined by a first-principles method based on the generalized gradient approximation of density…

Materials Science · Physics 2007-05-23 R. G. Endres , C. Y. Fong , L. H. Yang , G. Witte , Ch. Woll

We obtain the conductance of a system of electrons connected to leads, within time-dependent density-functional theory, using a direct relation between the conductance and the density response function. Corrections to the non-interacting…

Materials Science · Physics 2007-10-04 P. Bokes , J. Jung , R. W. Godby

We consider transport through a one-dimensional conductor subject to an external periodic potential and connected to non-interacting leads (a "Mott quantum wire"). For the case of a strong periodic potential, the conductance is shown to…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 Oleg A. Starykh , Dmitrii L. Maslov

Understanding of charge transport mechanisms in nanoscale structures is essential for the development of molecular electronic devices. Charge transport through 1D molecular systems connected between two contacts is influenced by several…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Daijiro Nozaki , Horacio M. Pastawski , Gianaurelio Cuniberti

The interplay between electron correlation and nuclear quantum effects makes our understanding of elemental hydrogen a formidable challenge. Here, we present the phase diagram of hydrogen and deuterium at low temperatures and high-pressure…

Materials Science · Physics 2023-06-28 Lorenzo Monacelli , Michele Casula , Kosuke Nakano , Sandro Sorella , Francesco Mauri

The equilibrium states of one-dimensional proton conductors in the systems with hydrogen bonds are investigated. Our extended hard-core boson lattice model includes short-range interactions between hydrogen ions, their transfer along the…

Statistical Mechanics · Physics 2021-06-28 R. Ya. Stetsiv
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