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Mean-field techniques provide a rather accurate description of single-chain conformations in spatially inhomogeneous polymer systems containing interfaces or surfaces. Intermolecular correlations, however, are not described by the…

Soft Condensed Matter · Physics 2009-11-13 Martin Hömberg , Marcus Müller

The contact values $g(\sigma,\sigma')$ of the radial distribution functions of a fluid of (additive) hard spheres with a given size distribution $f(\sigma)$ are considered. A ``universality'' assumption is introduced, according to which, at…

Statistical Mechanics · Physics 2007-05-23 A. Santos , S. B. Yuste , M. Lopez de Haro

We compare the steady state velocity distributions from our three-dimensional inelastic hard sphere molecular dynamics simulation for homogeneously heated granular media, with the predictions of a mean field-type Enskog-Boltzmann equation…

Soft Condensed Matter · Physics 2009-11-07 Sung Joon Moon , M. D. Shattuck , J. B. Swift

We simulate, using nonperturbative methods, the real-time dynamics of small bubbles of "false vacuum" in a quantum spin chain near criticality, where the low-energy physics is described by a relativistic (1+1)-dimensional quantum field…

Quantum Physics · Physics 2024-09-19 Ashley Milsted , Junyu Liu , John Preskill , Guifre Vidal

Polymer networks formed by cross linking flexible polymer chains are ubiquitous in many natural and synthetic soft-matter systems. Current micromechanics models generally do not account for excluded volume interactions except, for instance,…

Soft Condensed Matter · Physics 2023-06-05 Pratik Khandagale , Timothy Breitzman , Carmel Majidi , Kaushik Dayal

Analytical treatments of polymer dynamics have mostly been restricted to linear response theory around some steady state obtained via perturbative field theory. Here, I derive an analytical framework that yields unified access to the…

Soft Condensed Matter · Physics 2026-04-03 Andriy Goychuk

A diagrammatic kinetic theory of density fluctuations in simple dense liquids at long times, described in the preceding paper, is applied to a high density Lennard-Jones liquid to calculate various equilibrium time correlation functions.…

Statistical Mechanics · Physics 2015-06-18 Kevin R. Pilkiewicz , Hans C. Andersen

The effect of non-Boltzmann energy distributions on the free propagation of shock waves through a monoatomic gas is investigated via theory and simulation. First, the non-Boltzmann heat capacity ratio $\gamma$, as a key property for…

Fluid Dynamics · Physics 2023-05-18 Malte Döntgen

We present a Generalized Langevin Equation for the dynamics of interacting semiflexible polymer chains, undergoing slow cooperative dynamics. The calculated Gaussian intermolecular center-of-mass and monomer potentials, wich enter the GLE,…

Statistical Mechanics · Physics 2009-11-07 M. Guenza

A fundamental step in the rational design of vascular targeted particles is the firm adhesion at the blood vessel walls. Here, a combined Lattice Boltzmann Immersed Boundary model is presented for predicting the near wall dynamics of…

Fluid Dynamics · Physics 2018-08-07 A. Coclite , H. Mollica , S. Ranaldo , G. Pascazio , M. D. De Tullio , P. Decuzzi

The statistical "monomer-based" segment length $b$ and the Kuhn length $l_k$ are central to polymer physics, yet the minimal size required for a truly statistical segment - Gaussian, uncorrelated, and valid as an entropic spring - is not…

Soft Condensed Matter · Physics 2026-03-13 José A. Martins

We investigate diffusion-limited reactions between a diffusing particle and a target site on a semiflexible polymer, a key factor determining the kinetics of DNA-protein binding and polymerization of cytoskeletal filaments. Our theory…

Soft Condensed Matter · Physics 2010-12-08 Yann von Hansen , Roland R. Netz , Michael Hinczewski

We present computer simulations of a simple bead-spring model for polymer melts with intramolecular barriers. By systematically tuning the strength of the barriers, we investigate their role on the glass transition. Dynamic observables are…

Soft Condensed Matter · Physics 2015-05-14 Marco Bernabei , Angel J. Moreno , Juan Colmenero

We discuss theoretically and numerically the intramolecular form factor $F(q)$ in dense polymer systems. Following Flory's ideality hypothesis, chains in the melt adopt Gaussian configurations and their form factor is supposed to be given…

Soft Condensed Matter · Physics 2009-11-13 P. Beckrich , A. Johner , A. N. Semenov , S. P. Obukhov , H. Benoit , J. P. Wittmer

Small angle X-ray scattering (SAXS) studies in poly[2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV) with varying conjugation, and polyethylene dioxythiophene complexed with polystyrene sulfonate (PEDOT-PSS) in different…

Soft Condensed Matter · Physics 2010-11-11 Paramita Kar Choudhury , Debjani Bagchi , C. S. Suchand Sangeeth , Reghu Menon

We revisit a model of semiflexible Gaussian chains proposed by Winkler \textit{et al}, solve the dynamics of the discrete description of the model and derive exact algebraic expressions for some of the most relevant dynamical observables,…

Soft Condensed Matter · Physics 2022-11-02 Andres R. Tejedor , Jaime R. Tejedor , Jorge Ramirez

Parallel-tempering MD results for a CH$_3$(CH$_2$-O-CH$_2$)$_m$CH$_3$ chain in water are exploited as a data-base for analysis of collective structural characteristics of the PEO globule with a goal of defining models permitting statistical…

Chemical Physics · Physics 2014-04-29 M. I. Chaudhari , L. R. Pratt , M. E. Paulaitis

The dynamics of loop formation by linear polymer chains has been a topic of several theoretical/experimental studies. Formation of loops and their opening are key processes in many important biological processes. Loop formation in flexible…

Soft Condensed Matter · Physics 2015-05-14 K. P. Santo , K. L. Sebastian

We analyzed extensively the dynamics of polymer chains in solutions simulated with dissipative particle dynamics (DPD), with a special focus on the potential influence of a low Schmidt number of a typical DPD fluid on the simulated polymer…

Soft Condensed Matter · Physics 2009-11-11 W. Jiang , J. Huang , Y. Wang , M. Laradji

In this work, an improved methodology for studying interactions of proteins in solution by small-angle scattering, is presented. Unlike the most common approach, where the protein-protein correlation functions $g_{ij}(r)$ are approximated…

Statistical Mechanics · Physics 2009-11-07 Francesco Spinozzi , Domenico Gazzillo , Achille Giacometti , Paolo Mariani , Flavio Carsughi
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