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We use the thread model for linear chains of interacting monomers, and the ``polymer reference interaction site model'' (PRISM) formalism to determine the monomer-monomer pair correlation function $h_{mm}(r)$ for dilute and semi-dilute…

Soft Condensed Matter · Physics 2007-05-23 V. Krakoviack , B. Rotenberg , J. -P. Hansen

We calculate the two, three, four, and five-body (state independent) effective potentials between the centers of mass (CM) of self avoiding walk polymers by Monte-Carlo simulations. For full overlap, these coarse-grained n-body interactions…

Soft Condensed Matter · Physics 2009-11-07 P. G. Bolhuis , A. A. Louis , J. P. Hansen

A coarse-graining strategy for dilute and semi-dilute solutions of interacting polymers, and of colloid polymer mixtures is briefly described. Monomer degrees of freedom are traced out to derive an effective, state dependent pair potential…

Soft Condensed Matter · Physics 2009-11-11 J. -P. Hansen , C. I. Addison , A. A. Louis

We map dilute or semi-dilute solutions of non-intersecting polymer chains onto a fluid of ``soft'' particles interacting via a concentration dependent effective pair potential, by inverting the pair distribution function of the centers of…

Soft Condensed Matter · Physics 2009-10-31 A. A. Louis , P. G. Bolhuis , J. P. Hansen , E. J. Meijer

Dilute or semi-dilute solutions of non-intersecting self-avoiding walk (SAW) polymer chains are mapped onto a fluid of ``soft'' particles interacting via an effective pair potential between their centers of mass. This mapping is achieved by…

Soft Condensed Matter · Physics 2009-10-31 P. G. Bolhuis , A. A. Louis , J. P. Hansen , E. J. Meijer

We derive and introduce anisotropic effective pair potentials to coarse-grain solutions of semiflexible rings polymers of various lengths. The system has been recently investigated by means of full monomer-resolved computer simulations,…

Soft Condensed Matter · Physics 2015-07-21 Peter Poier , Christos N. Likos , Angel J. Moreno , Ronald Blaak

We systematically studied the validity and transferability of effective, coarse-grained, pair potentials in ultrasoft colloidal systems. We focused on amphiphilic dendrimers, macromolecules which can aggregate into clusters of overlapping…

Soft Condensed Matter · Physics 2018-02-01 Marta Montes-Saralegui , Gerhard Kahl , Arash Nikoubashman

We show how to coarse grain polymers in a good solvent as single particles, interacting with density-independent or density-dependent interactions. These interactions can be between the centres of mass, the mid-points or end-points of the…

Soft Condensed Matter · Physics 2009-11-07 A. A. Louis , P. G. Bolhuis , R. Finken , V. Krakoviack , E. J. Meijer , J. P. Hansen

A coarse-graining strategy, previously developed for polymer solutions, is extended here to mixtures of linear polymers and hard-sphere colloids. In this approach groups of monomers are mapped onto a single pseudoatom (a blob) and the…

Soft Condensed Matter · Physics 2015-01-07 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni

Soft nanocomposites represent both a theoretical and an experimental challenge due to the high number of the microscopic constituents that strongly influence the behaviour of the systems. An effective theoretical description of such systems…

Soft Condensed Matter · Physics 2016-12-14 Emanuele Locatelli , Barbara Capone , Christos N. Likos

Polymer chains in colloid-polymer mixtures can be coarse-grained by replacing them with single soft particles interacting via effective polymer-polymer and polymer-colloid pair potentials. Here we describe in detail how Ornstein-Zernike…

Soft Condensed Matter · Physics 2007-05-23 P. G. Bolhuis , A. A. Louis

We discuss the reliability of integral-equation methods based on several commonly used closure relations in determining the phase diagram of coarse-grained models of soft-matter systems characterized by mutually interacting soft and…

Soft Condensed Matter · Physics 2015-10-28 Roberto Menichetti , Andrea Pelissetto , Giuseppe D'Adamo , Carlo Pierleoni

A brief review of modeling and simulation methods for a study of polymers at interfaces is provided. When studying truly multiscale problems as provided by realistic polymer systems, coarse graining is practically unavoidable. In this…

Soft Condensed Matter · Physics 2009-10-19 Fathollah Varnik , Kurt Binder

Theoretical aspects of polymers in mixed solvents are considered using the Edwards Hamiltonian formalism. Thermodynamic and structural properties are investigated and some predictions are made when the mixed solvent approaches criticality.…

Soft Condensed Matter · Physics 2007-05-23 A. Negadi , A. Sans-Penninckx , M. Bemouna , T. A. Vilgis

We present a promising coarse-graining strategy for linking micro- and mesoscales of soft matter systems. The approach is based on effective pairwise interaction potentials obtained from detailed atomistic molecular dynamics (MD)…

Soft Condensed Matter · Physics 2007-05-23 A. P. Lyubartsev , M. Karttunen , I. Vattulainen , A. Laaksonen

We present a coarse-grained model for linear polymers with a tunable number of effective atoms (blobs) per chain interacting by intra- and inter-molecular potentials obtained at zero density. We show how this model is able to accurately…

Soft Condensed Matter · Physics 2012-07-17 Giuseppe D'Adamo , Andrea Pelissetto , Carlo Pierleoni

An analytical description of polymer melts and their mixtures as liquids of interacting soft colloidal particles is obtained from liquid-state theory. The derived center-of-mass pair correlation functions with no adjustable parameters…

Soft Condensed Matter · Physics 2009-11-10 G. Yatsenko , E. J. Sambriski , M. A. Nemirovskaya , M. Guenza

We study the effect of a gradient of solvent quality on the coil-globule transition for a polymer in a narrow pore. A simple self-attracting self-avoiding walk model of a polymer in solution shows that the variation in the strength of…

Soft Condensed Matter · Physics 2015-06-17 S Nath , D P Foster , D Giri , S Kumar

To study the cooling behavior and the glass transition of polymer melts in bulk and with free surfaces a coarse-grained weakly semi-flexible polymer model is developed. Based on a standard bead spring model with purely repulsive…

Soft Condensed Matter · Physics 2019-09-09 Hsiao-Ping Hsu , Kurt Kremer

We study numerically the effective pair potential between star polymers with equal arm lengths and equal number $f$ of arms. The simulations were done for the soft core Domb-Joyce model on the simple cubic lattice, to minimize corrections…

Soft Condensed Matter · Physics 2009-11-10 Hsiao-Ping Hsu , Peter Grassberger
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